Treatment of Different Wastewaters from Pulp and Paper Industry in Methane Reactors

1985 ◽  
Vol 17 (1) ◽  
pp. 223-230 ◽  
Author(s):  
P K Latola

A wastewater from an integrated paper mill with a COD of 1200 mg/dm3 was anaerobically treated in a multi-stage reactor. The BOD7 removal efficiencies of 60-75 % were achieved at maximal loading rates of 5-6 kg COD/m3d and HRT of 4-6 hours due to the granular sludge. Industrial sulphite evaporator condensates from Ca- and Na-processes were treated in anaerobic filters containing light gravel, plastic foam and power plant slag as filter media. The BOD7 removals of 78 % on average were achieved at loading rates of 1.8-3.3 kg COD/m3d with Ca-process evaporator condensates and 80 % BOD7 removals were achieved with Na-process condensates at loading rates of 3.5-4.1 kg COD/m3d.

1990 ◽  
Vol 22 (9) ◽  
pp. 199-206
Author(s):  
J. Junna ◽  
J. Rintala

Since 1984, when the first activated sludge treatment plant (ASTP) was built to treat pulp and paper industry wastewaters in Finland, twenty more plants have been introduced by 1989. An evaluation was undertaken to find out the actual performance of the ASTPs in BOD7, CODc r and phosphorus removal. The evaluation included all the 12 ASTPs in operation in the pulp and paper industry at the beginning of 1987. The highest average BOD7 removals were about 90 % at pulp mills as well as paper and board mills. CODc r removal was generally higher at paper and board mills (about 40-70 %) than at pulp mills (about 25-55 %). Phosphorus was added to wastewater in most plants. In some ASTPs, phosphorus concentrations were lowered by 20-40 % compared with wastewater from the mill. In some plants phosphorus load on the recipient was higher than the load coming from the mill. In treated wastewater, correlations between suspended solids and BOD7, CODc r, phosphorus and nitrogen were significant in most plants. This indicated that low removal efficiencies resulted from poor suspended solids removal in the secondary clarification. Volumetric and sludge CODc r loading rates could not explain removal efficiencies when all plants were included in the comparison. In plants treating chemical pulping effluents, higher removal efficiencies were normally achieved with lower loading rates. When the plants were studied separately, the influence of loading rate was generally significant.


2019 ◽  
Vol 98 (12) ◽  
pp. 1392-1401
Author(s):  
V. V. Yurchenko ◽  
Faina I. Ingel ◽  
N. A. Urtseva ◽  
E. K. Krivtsova ◽  
L. V. Akhaltseva

Introduction. Analysis of literature has shown genotoxicants (mutagens and carcinogens) to be present in the atmospheric emissions of pulp and paper industry (PPI). Moreover, among PPI workers from different countries, there was identified an additional risk of cancer, which suggests its high probability among residents of the cities where the PPI is located. The recognized index of genotoxic effects is an increased level of genome instability, which is determined, in particular, in the micronucleus test. The scope of the study - the comparative analysis of the effects of genomic instability in the two tissues - blood lymphocytes cultured with Cytochalasin B, and buccal epithelial cells in the second grade school children (8-9 years old, boys and girls), whose schools were located at different distances from the pulp and paper mill. Material and methods. The study was carried out in the city of Koryazhma, the Arkhangelsk Region (42000 citizens), where the pulp and paper plant as the city-forming industry was located. For the analysis, we subdivided the territories on which the schools were located, into 3 groups according to their distance from the pulp and paper mill. The effects of genomic instability were determined by cytome analysis in the micronucleus test. Results. Cytome analysis of cultivated lymphocytes demonstrated that levels of genome instability indices (including cell frequencies with micronuclei and nucleoplasm bridges, apoptosis, as well as changes in the spectrum of cell populations) to decrease along with the rising the distance between the pulp and paper mill and schools where the children go. In buccal epithelial cells, the manifestations of genomic instability effects were less systematic, which did not allow making a definitive conclusion. At the same time, in both tests, gender differences in the results of cytome analysis were revealed (for example, the alteration of frequency of lymphocytes with genetic damage dependence on the distance between schools and the PPI was more pronounced among boys). Conclusion. According to the results of this study and taking into consideration the data of literature, we hypothesized that the discovering of gender dimorphism in the effects of genome instability may indicate the presence of toxic and/or genotoxic compounds in an environment.


2007 ◽  
Vol 55 (6) ◽  
pp. 117-123 ◽  
Author(s):  
C.R. Oliveira ◽  
C.M. Silva ◽  
A.F. Milanez

In the pulp and paper industry, the water use minimization is a constant target. One way to reduce water use is to recycle the effluent in a closed-cycle concept. In paper mills, the main source of liquid effluent is the so-called whitewater, which is the excess water, originated from pulp stock dewatering and other fibre contaminated water. This research studied the reuse of paper mill whitewater after membrane ultrafiltration (UF) in the paper machine and in the pulp bleach plant of an integrated mill. Contaminant removal and flux behaviour of the UF system were evaluated. The treatment by ultrafiltration was technically feasible and the treated whitewater had good potential to be reused in some processes in the paper machine. The reuse of ultrafiltered whitewater in the bleaching plant was not recommended because of the high level of soluble calcium present in this stream. Therefore, a combined treatment of the whitewater using the principle of precipitation and ultrafiltration was proposed showing good results and enabling the use of the treated whitewater in the bleach plant.


1991 ◽  
Vol 24 (3-4) ◽  
pp. 411-415 ◽  
Author(s):  
J. Wartiovaara ◽  
P. Heinonen

During recent years the BOD-loading of pulp and paper mill wastewaters has decreased dramatically, due to more effective circulation of water in the processes, and the new activated sludge biological treatment plants. This traditional threat to the environment has been forgotten by the scientists who nowadays are more interested in the role of chlorine compounds discharged from bleaching processes. However, eutrophication due to nutrient loading is still present in many recipients of pulp and paper industry. The BOD-reduction has often been carried out on the cost of adding nutrients, pnosphorus and nitrogen to the purification processes. The biological treatment has also decreased the inhibitive effect of wastewater on the biological production of the recipient water body. Therefore, the eutrophication arises immediatly. The authors worry about the research of nutrients; loadings, development trends and eutrophication effects.


1988 ◽  
Vol 20 (1) ◽  
pp. 251-262 ◽  
Author(s):  
R. Hakulinen

Biological systems have been employed successfully for manv years in the treatment of pulp and paper mill waste water. Previously, not very much was known about enzymes and their possibilities in pulp and paper industry wastewater treatment. There is currently a lot of research activity in the enzymology of lignin degradation. Ligninase, cellulase, peroxidase, etc. are the most important enzymes, especially peroxidase, which is used for color removal in bleaching effluents. It is also possible to mix enzymes together with special microbes, which normally do not have high enzvme activity, and remove recalcitrant and harmless compounds from wastewater. The use of novel enzymes and rDNA technology in sludge and wastewater treatment will also be discussed.


2020 ◽  
Vol 5 (10) ◽  
Author(s):  
Chhotu Ram ◽  
Pushpa Rani ◽  
Kibrom Alebel Gebru ◽  
Mebrhit G Mariam Abrha

AbstractPulp and paper industry is coming under one of the most water polluting industries, and generated wastewater is highly toxic in nature. The paper mill requires huge quantity (~50–60 m3 of water to produce one ton of paper) of water, and accordingly huge quantity of chemical contaminated wastewater is discharged. The paper mill effluents have identified 240–250 chemicals in different stages of paper making. Various chemical constituents such as high chemical oxygen demand, biochemical oxygen demand, AOX, chlorinated compounds, color, suspended materials, lignin and their derivatives are released in the wastewater. The present review study is focused on the paper mill processes, wastewater generation and its effective treatment by microorganisms. The biological treatment has been identified as cost-effective and eco-friendly methods for the degradation of xenobiotic compounds for paper mill wastewater. Various studies have been performed so far to investigate the complex nature of wastewater by the application of bacteria, fungi and their enzymes at industrial scale. Therefore, the article discussed the importance of biological method as an effective technique for the degradation of paper mill wastewater.


2010 ◽  
Vol 62 (7) ◽  
pp. 1676-1681 ◽  
Author(s):  
S. Gupta ◽  
S. K. Chakrabarti ◽  
S. Singh

Aerobic biological treatment with activated sludge is the predominant process all over the world for treatment of pulp and paper industry wastewater. 50–70% of the biodegradable organic material is oxidized to CO2 and the rest is converted to bacterial biomass, typically termed as excess sludge or waste activated sludge (WAS). Handling and disposal of WAS in general and in particular from the pulp and paper industry face different processing difficulties, regulatory stringency due to organochlorine contamination and reluctance of people for reuse. With an objective of reducing the net disposable biomass, ozonation of WAS from a pulp and paper mill and from a laboratory scale batch activated sludge process operated with the wastewater and bacterial seed of the same pulp and paper mill have been carried out. With the mill sludge having predominant filamentous organisms 18% MLSS was reduced at an ozone dosage of 55 mg O3/g dry MLSS solid (DS) resulting in 2.5 times COD increase. With the laboratory sludge which is well structured and flocculating, only 6% MLSS was reduced at an ozone dosage of 55 mg O3/g DS. Ozonation mineralizes 26% and 20% AOX compounds embedded in the secondary sludge in the mill and laboratory sludge respectively at an ozone dosage of 55 mg O3/g DS. During ozonation, absorbed/adsorbed lignin on biomass was released which resulted in increased colour concentration. Ozonation can be a potential oxidative pretreatment process for reducing the WAS and paving the way for cost effective overall treatment of WAS.


2002 ◽  
Vol 45 (12) ◽  
pp. 151-158 ◽  
Author(s):  
E. Tarlan ◽  
Ü. Yetis ◽  
F.B. Dilek

Highly colored and highly polluted pulp and paper industry wastewaters are proposed to be treated by using algae in sequential batch reactors (SBR). Results of batch studies revealed that up to 74% COD; 74% color removal could be attained in about 40 days of incubation. From the preliminary SBR experiments, filling period was found to be a critical step affecting the overall efficiency when mixing and aeration is applied during filling. Therefore, 5 different filling periods (4, 6, 8, 10 and 12 days) were studied with a total SBR cycle of 15 days. For all filling periods; COD, color and AOX removal efficiencies increased with increasing filling time. Maximum removal efficiencies achieved were 60 to 85% for COD, 42 to 75% for color and 82 to 93% for AOX for the filling periods of 4 to 12 days. For 8 days or longer filling periods, no additional reaction time was required. Results showed that, organics in the wastewater were both chlorinated and non-chlorinated; algae removed these mainly by metabolism; and chlorine cleavage from chlorinated organic molecules was more rapid than the degradation of non-chlorinated and colored organics. Adsorbed lignin on algal biomass was found to be varying between 10-20% depending on filling period applied.


Sign in / Sign up

Export Citation Format

Share Document