scholarly journals Surface characterization of catalytically active metal, alloy, and compound films. Progress report, September 1, 1978--August 31, 1979. [Ag--Cu, Pd--Cu, Pt--Au]

1979 ◽  
Author(s):  
R.W. Vook

Author(s):  
L. Tröger ◽  
H. Hünnefeld ◽  
S. Nunes ◽  
M. Oehring ◽  
D. Fritsch


1997 ◽  
Vol 40 (1-4) ◽  
pp. 81-83 ◽  
Author(s):  
L. Tröger ◽  
H. Hünnefeld ◽  
S. Nunes ◽  
M. Oehring ◽  
D. Fritsch


2009 ◽  
Vol 42 (14) ◽  
pp. 4937-4940 ◽  
Author(s):  
Matthieu F. Dumont ◽  
Sandy Moisan ◽  
Cyril Aymonier ◽  
Jean-Daniel Marty ◽  
C. Mingotaud




ChemInform ◽  
2010 ◽  
Vol 28 (22) ◽  
pp. no-no
Author(s):  
L. TROEGER ◽  
H. HUENNEFELD ◽  
S. NUNES ◽  
M. OEHRING ◽  
D. FRITSCH


Catalysts ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 17 ◽  
Author(s):  
Krisztina Orosz ◽  
Gábor Papp ◽  
Ágnes Kathó ◽  
Ferenc Joó ◽  
Henrietta Horváth

The synthesis and characterization of the new Ir(I)-complexes [IrCl(cod)(Bnmim)], [Ir(cod)(emim)(PPh3)]Cl and [Ir(cod)(Bnmim)(mtppms)] are reported. The zwitterionic complexes [Ir(cod)(NHC)(mtppms)] and Na2[Ir(cod)(NHC)(mtppts)] (NHC = emim, bmim or Bnmim; mtppms-Na and mtppts-Na3 = sodium salts of mono- and trisulfonated triphenylphosphine, respectively) were found to be effective precatalysts for transfer hydrogenation of aromatic and aliphatic ketones in basic 2-propanol-water mixtures with initial turnover frequencies up to 510 h−1 at 80 °C, and their catalytic performances were compared to those of [IrCl(cod)(NHC)] complexes (NHC = emim, bmim, Bnmim, IMes) and [Ir(cod)(emim)(PPh3)]Cl. Three of the catalysts were characterized by single-crystal X-ray diffraction. The reaction rates of the transfer hydrogenation of acetophenone and benzophenone showed strong dependence on the water concentration of the solvent, indicating preferential solvation of the catalytically active metal complexes.



1997 ◽  
Vol 101 (8) ◽  
pp. 1279-1291 ◽  
Author(s):  
L. Tröger ◽  
H. Hünnefeld ◽  
S. Nunes ◽  
M. Oehring ◽  
D. Fritsch


Author(s):  
R. E. Herfert

Studies of the nature of a surface, either metallic or nonmetallic, in the past, have been limited to the instrumentation available for these measurements. In the past, optical microscopy, replica transmission electron microscopy, electron or X-ray diffraction and optical or X-ray spectroscopy have provided the means of surface characterization. Actually, some of these techniques are not purely surface; the depth of penetration may be a few thousands of an inch. Within the last five years, instrumentation has been made available which now makes it practical for use to study the outer few 100A of layers and characterize it completely from a chemical, physical, and crystallographic standpoint. The scanning electron microscope (SEM) provides a means of viewing the surface of a material in situ to magnifications as high as 250,000X.



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