scholarly journals Процессы захвата и диссоциативного захвата одного электрона при взаимодействии двухзарядных ионов с молекулами CO

2019 ◽  
Vol 89 (8) ◽  
pp. 1164
Author(s):  
А.А. Басалаев ◽  
В.В. Кузьмичев ◽  
М.Н. Панов ◽  
О.В. Смирнов

AbstractThe absolute cross sections of single-electron capture and single-electron capture with dissociation in the interaction between incident He^2+, C^2+, N^2+, and O^2+ ions with energies from 6.4 to 36.4 keV and СО molecules were measured. It is demonstrated that the cross section of dissociative capture is much larger than the cross section of single-electron capture for O^2+ projectile ions. A qualitative explanation for this effect is provided.

2002 ◽  
Vol 11 (06) ◽  
pp. 567-572 ◽  
Author(s):  
A. T. HASAN ◽  
T. J. GRAY

Absolute total cross sections for single-electron-capture are measured for [Formula: see text] and N+ ions traversing N2 molecular gas of collision energies in the range of 0.60 to 1.5 keV. These cross sections are found to be in the range of 3.97 - 6.25 Å2 for [Formula: see text] ions, and in the range of 0.46 - 1.67 Å2 for N+ ions. A comparison is made between the present measurements of the total cross sections of the N+ + N2 system and all the experimental results, which are represented by B. G. Lindsay et al.,1 for the O+ + N2 system. The present measurements of the total cross section of the N+ + N2 system are in partial agreement with measurements of B. G. Lindsay et al.,1 and in an excellent agreement with the measurements of Moran et al.,2 The present measurements of the total cross sections of the [Formula: see text] system are compared to the theoretical calculations and the experimental results of the same system.23 The results are in disagreement with each other.


1977 ◽  
Vol 55 (18) ◽  
pp. 1594-1600 ◽  
Author(s):  
H. C. Suk ◽  
A. Guilbaud ◽  
B. Hird

Measurements of single electron capture cross sections by Ar2+ ions in thin targets of neon, argon, and krypton have been made with an absolute accuracy of about 5%. The detection system was constructed so as to have a uniform efficiency over the range of angles and energies at which the singly charged Ar+ ions were produced in the charge exchange. Discrepancies with the extrapolated absolute values of previous measurements were found, but the energy variations of the cross section are in much better agreement. It seems possible to account for the energy variation of the cross sections with the two state theory when it is assumed that the ions of both the initial and the final states are all in their ground states.


1968 ◽  
Vol 46 (21) ◽  
pp. 2339-2345 ◽  
Author(s):  
J. F. Williams

The ionization probability curves of argon and krypton atoms within 1 eV of threshold have been studied for electron impact with an average electron energy distribution of 0.035 eV (FWHM). In krypton, changes in the slope of the ionization probability curves occur at electron energies close to the spectroscopically observed autoionization levels between the 2P3/2 and 2P1/2 levels. Ions which have been formed in such a manner are then used as primary ions in charge-transfer reactions. Total single electron capture cross sections have been measured for 2P3/2 and 2P1/2 state argon and krypton ions incident upon argon and krypton atoms, respectively. Upon the presumption of the applicability of the adiabatic hypothesis, it appears, for single electron capture reactions of krypton ions upon krypton atoms over the relative energy range 500–1500 eV, that (a) the reaction 2P3/2 → 2P3/2 is dominant over the reaction 2P3/2 → 2P1/2, (b) the cross section for the 2P3/2 → 2P3/2 reaction is greater than the 2P1/2 → 2P1/2 reaction cross section, and (c) little information can be deduced for the relative values of the forward and reverse [Formula: see text] reaction cross sections.


1977 ◽  
Vol 32 (6) ◽  
pp. 555-557 ◽  
Author(s):  
A. Müller ◽  
E. Salzborn

AbstractCross sections for single electron capture by CO22+ ions as well as total collision cross sections σi,tot (i=1, 2) for CO21+ and CO22+ ions in He, Ne, Ar, Kr, Xe, H2, O2, N2, CH4 and CO2 gases have been measured at 10 keV impact energy. σ2,1 varies between 4.5·10-17cm2 for the He and 1.8·10·15cm2 for the CO, target. On the average, σ2,1,tot is 1.6 times larger than σ1,tot and shows a nearly linear dependence on the gaskinetic hard sphere cross section of the target particle. The largest observed value of σ2,tot is 9.4·10-15cm2 for the CO2 target.


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