scholarly journals Synthesis, Fluorescence and Nonlinear Optical Properties of Phthalocyanine Derivatives in the Continuous-wave and Pulsed Excitation Regimes-=SUP=-*-=/SUP=-

2021 ◽  
Vol 129 (5) ◽  
pp. 626
Author(s):  
Hacene Manaa ◽  
Devrim Attila ◽  
Ayse Gul Gurek ◽  
Sughra Mohamed ◽  
Fadheela A. Alawainati ◽  
...  
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Continuous Wave ◽  
Pulsed Laser ◽  
Optical Limiting ◽  
Nonlinear Optical Properties ◽  
Visible Range ◽  
Third Order ◽  
Nonlinear Properties ◽  
532 Nm

In this work, the photo-physical properties of seven different phthalocyanine derivatives are studied, with a focus on their transparency spectral range. Two compounds among them are recently synthesised. The investigations include synthesis, photoluminescence, absorptive and refractive nonlinear properties, and optical limiting performances. The compounds are found to be emitting interesting broad fluorescence bands in the visible range. The nonlinear optical properties are investigated with the help of Z-scan technique, with both a continuous laser at 488, 514.5 and 632.8 nm, and with a pulsed laser at 532 nm. The sign and the magnitude of the nonlinear refractive index, third-order susceptibility, and nonlinear absorption coefficient have been evaluated in the seven compounds. The optical limiting performance of each compound was also evaluated in the continuous and pulsed laser excitation regimes. Keywords:

scholarly journals Wavelength-dependent nonlinear optical properties of 8-(4-methoxyphenyl)-6-oxo-3-p-tolyl-6H-pyrido[1,2-b][1,2,4]triazine-7,9-dicarbonitrile

2018 ◽  
Vol 96 (12) ◽  
pp. 1288-1294 ◽  
Author(s):  
M. Khanzadeh ◽  
M. Dehghanipour ◽  
A. Darehkordi ◽  
F. Rahmani
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Continuous Wave ◽  
Nonlinear Optical Properties ◽  
Saturable Absorption ◽  
Reverse Saturable Absorption ◽  
Third Order ◽  
Incident Intensity ◽  
532 Nm ◽  
Order Susceptibility

In this study, 8-(4-methoxyphenyl)-6-oxo-3-p-tolyl-6H-pyrido[1,2-b][1,2,4]triazine-7,9-dicarbonitrile (A) was prepared and then the nonlinear optical properties of this compound, including nonlinear refractive index (n2) and nonlinear absorption coefficient (β) were measured using Z-scan technique by continuous wave laser diode at wavelengths of 405 and 532 nm. At wavelength of 532 nm, by increasing the incident intensity a switch over from saturable absorption (SA) to reverse saturable absorption (RSA) was observed. The results showed that the nonlinear optical properties of this compound depend on the wavelength. It was also observed that with decreasing incident intensity, the thermal nonlinear refractive coefficient increased accordingly, while its thermo-optic coefficient decreased. In addition, the third-order susceptibility of this compound in wavelength of 532 nm was obtained higher than 405 nm.

Nonlinear optical properties of colloidal carbon nanoparticles: nanodiamonds and carbon dots

RSC Advances ◽  
2014 ◽  
Vol 4 (76) ◽  
pp. 40152-40160 ◽  
Author(s):  
Irene Papagiannouli ◽  
Athanasios B. Bourlinos ◽  
Aristides Bakandritsos ◽  
Stelios Couris
Keyword(s):  
Optical Properties ◽  
Carbon Dots ◽  
Carbon Nanoparticles ◽  
Nonlinear Optical ◽  
Laser Excitation ◽  
Optical Limiting ◽  
Nonlinear Optical Properties ◽  
Nlo Response ◽  
Colloidal Carbon ◽  
532 Nm

Nanodiamonds (NDs) and carbon-dots (CDs) suspensions exhibit significant NLO response under both ps and ns laser excitation. NDs exhibit important optical limiting action under nanosecond visible (532 nm) and infrared (1064 nm) laser excitation.

Glass Structures and Linea/Nonlinear Optical Properties of Ag2O-Doped TeO2 Glasses

2014 ◽  
Vol 617 ◽  
pp. 141-144 ◽  
Author(s):  
Yusuke Kasuya ◽  
Toshiki Suhara ◽  
Tomokatsu Hayakawa ◽  
Philippe Thomas ◽  
Masayuki Nogami
Keyword(s):  
Optical Properties ◽  
Absorption Edge ◽  
Photoelectron Spectroscopy ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Nonlinear Susceptibility ◽  
Third Order ◽  
Nonlinear Properties ◽  
Nonlinear Optical Devices ◽  
Third Order Nonlinear Susceptibility

A family of TeO2-based glasses is known to have high third-order nonlinear properties and expected as nonlinear optical devices. In the present study, we fabricated Ag2O-TeO2 and Ag2O-Nb2O5-TeO2 glasses, and estimated their structures and linear/nonlinear optical properties. The main results showed that the absorption-edge of the glasses was shifted to longer wavelength side with increasing Ag2O content. By Raman spectroscopy, it was found that an increase in Ag2O content promoted to change TeO4 to TeO3/TeO3+1 units. X-ray photoelectron spectroscopy (XPS) revealed the presence of an electronic state of Ag2+ ions, which was supposed to have a large influence on the absorption-edge wavelength. In Ag2O-Nb2O5-TeO2 glass system, the third-order nonlinear susceptibility χ(3) increased with increasing Ag2O content at the expense of Nb2O5 content.

New Self-Focusing Materials: Synthesis, Structures and Nonlinear Optical Properties of Butterfly Shaped Clusters

1994 ◽  
Vol 374 ◽  
Author(s):  
S. Shi ◽  
X. Q. Xin
Keyword(s):  
Optical Properties ◽  
Nonlinear Absorption ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Acetonitrile Solution ◽  
Materials Synthesis ◽  
Third Order ◽  
Nlo Property ◽  
Self Focusing ◽  
532 Nm

AbstractCompounds WCu2OS3(PPh3)4 (I) and MoCu2OS3(PPh3)3 (II) were synthesized by reactions of (NH4)2MO2S2 (M = W, Mo), Cu2S and PPh3 in solid state for nonlinear optical studies. A wide transparent window (λ = 400 - 1000 nm) was observed for both clusters, which makes them attractive for nonlinear optical (NLO) applications. NLO properties of the clusters were studied with a 7-ns pulsed laser at 532 nm. Cluster I exhibits mainly optical self-focusing (n2 = 8 × 10-18 m2 W-1, as measured with an 1.2 × 10-4 M acetonitrile solution) with negligibly small nonlinear absorption. Cluster II exhibits both optical self-focusing (n2 = 5 × 10-17 m2 W-1, as measured with a 7.4 × 10-5 M acetonitrile solution) and nonlinear absorption (α2 = 2.6 × 10-10 m W-1). The third-order NLO susceptibilities (χ(3)) of the two clusters at the above-mentioned concentrations are 2 × 10-11 esu for I and 1.2 × 10-10 esu for II respectively. These nonlinear optical properties of the clusters were compared with those of cubic cage shaped and nest shaped clusters to reveal a qualitative structure/NLO property correlation.

Third order nonlinear optical properties and optical limiting in donor/acceptor substituted 4′-methoxy chalcone derivatives

2007 ◽  
Vol 88 (1) ◽  
pp. 105-110 ◽  
Author(s):  
H.J. Ravindra ◽  
A. John Kiran ◽  
K. Chandrasekharan ◽  
H.D. Shashikala ◽  
S.M. Dharmaprakash
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Optical Limiting ◽  
Nonlinear Optical Properties ◽  
Third Order ◽  
Chalcone Derivatives ◽  
Donor Acceptor

scholarly journals Synthesis and investigation of nonlinear optical properties of Para Red: Z-scan technique and quantum mechanical calculations

2018 ◽  
Vol 36 (3) ◽  
pp. 445-451 ◽  
Author(s):  
Fatemeh Mostaghni ◽  
Yasaman Abed
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Nonlinear Susceptibility ◽  
Quantum Mechanical ◽  
Dipole Polarizability ◽  
Quantum Mechanical Calculations ◽  
Quantum Chemical Analysis ◽  
Third Order ◽  
532 Nm

AbstractIn this study, we present a systematic study of linear and nonlinear optical properties of Para Red with the aim of Z-scan technique and quantum mechanical calculations. The Z-scan experiments were performed using a 532 nm Nd: YAG (SHG) CW laser beam. Para Red exhibited a strong nonlinear refractive index, nonlinear absorption coefficient and third-order nonlinear susceptibility 3.487 × 10−6 cm2/W, 2.341 × 10−1cm/W and 2.157 × 10−4 esu, respectively. Also, quantum chemical analysis was used for the calculation of the dipole moment μ, dipole polarizability α, anisotropy of polarizability Δα and molecular hyperpolarizabilities (β,γ). The results revealed that Para Red has large first and second hyperpolarizabilities. However, from the obtained results, it was found that Para Red can be a promising material for applications in the development of non-linear optical materials.

Third-order nonlinear optical properties of three chlorinated thienyl chalcones derivatives: synthesis, structural determination and Hirshfeld surface analysis

2019 ◽  
Vol 234 (10) ◽  
pp. 685-696 ◽  
Author(s):  
Weng Zhun Ng ◽  
Qin Ai Wong ◽  
Tze Shyang Chia ◽  
C. S. Chidan Kumar ◽  
Huey Chong Kwong ◽  
...  
Keyword(s):  
Optical Properties ◽  
Surface Analysis ◽  
Nonlinear Optical ◽  
Continuous Wave ◽  
Hirshfeld Surface ◽  
Nonlinear Optical Properties ◽  
Hirshfeld Surface Analysis ◽  
Nonlinear Susceptibility ◽  
Third Order ◽  
Chalcone Derivatives

Abstract Three chlorinated theinyl chalcone derivatives, namely (E)-1-(5-chlorothiophen-2-yl)-3-(4-(methylthio)phenyl)prop-2-en-1-one (I), (E)-1-(5-chlorothiophen-2-yl)-3-(4-(dimethylamino)phenyl)prop-2-en-1-one (II) and (E)-1-(5-chlorothiophen-2-yl)-3-(2,3-dihydrobenzofuran-5-yl)prop-2-en-1-one (III), were synthesized and their crystal structures were determined by single-crystal X-ray diffraction analysis. Compounds I, II and III crystallize in the monoclinic space groups P 21/c (centrosymmetric), P 21/n (centrosymmetric) and Pc (non-centrosymmetric), respectively. In all three compounds, the molecules are in a relatively planar conformation and adopt a trans configuration with respect to the C=C double bond. The crystal packings are stabilized by weak hydrogen-bonds, π · · · π, C–H · · · π and C–Cl · · · π interactions. The intermolecular contacts and lattice energies were further analyzed by Hirshfeld surface analysis. The third-order nonlinear optical properties of these chalcone derivatives were investigated using the single beam Z-scan technique with a 5 mW continuous wave diode laser operating at 635 nm, where compound I showed the highest potential for optical application with its exclusive nonlinear refractive index and nonlinear susceptibility.

Sign in / Sign up

Export Citation Format

Share Document