scholarly journals Geochemistry of Ni in the Cretaceous-Tertiary succession Fiskeler (Fish Clay) at Stevns Klint (Denmark): cheto-smectite of the black marl

2006 ◽  
Vol 71 (6) ◽  
pp. 639-659 ◽  
Author(s):  
Pavle Premovic ◽  
Bratislav Todorovic ◽  
Nikola Nikolic ◽  
Mirjana Pavlovic ◽  
Dragan Djordjevic ◽  
...  

The Cretaceus-Tertiary (KT) boundary at Stevns Klint (the H?jerup succession), Fiskeler, consists of a thin red clay layer overlain by a thick one of black marl. These two layers are made up mainly from cheto-smectite and biogenic calcite. The black marl shows an enhanced concentration of Ni (655 ppm) within its smectite fraction. Additionally, its carbonate fraction also shows an enhanced concentration of Ni (245 ppm). It is reasoned that these enrichments represent a sudden and rapid input of high amounts of Ni into the late Cretaceus seawater at Stevns Klint. The ultimate source of Ni in both the carbonate and smectite fractions of the black marl was probably impact fallout, produced by the KT asteroidal impact, deposited on the nearby soil and leached by the (acid) surface waters. The geochemistry of the Ni supports the hypothesis that the smectite of this marl most likely has a local (marine or terrestrial) provenance and was probably redeposited, after its formation, from the original site to its present location at the KT boundary.

CATENA ◽  
2020 ◽  
Vol 186 ◽  
pp. 104391 ◽  
Author(s):  
Yuan Li ◽  
Chuancheng Fu ◽  
Lin Zeng ◽  
Qian Zhou ◽  
Haibo Zhang ◽  
...  

2006 ◽  
Vol 71 (7) ◽  
pp. 793-806 ◽  
Author(s):  
Pavle Premovic ◽  
Milena Krsmanovic ◽  
Bratislav Todorovic ◽  
Mirjana Pavlovic ◽  
Nikola Nikolic ◽  
...  

Geochemical analyses of trace metals (Ir, Ni and Zn) in the kerogen of the black marl of the Cretaceous-Tertiary boundary succession (Fish Clay) at Stevns Klint (H?jerup Church) were undertaken. The data for this kerogen were in accordance with a previous hypothesis that this (insoluble) geoorganic polymer was derived from humic substances (mainly humic acids) of a nearshore soil. Substantial proportions of Ir, Ni and Zn within the kerogen structure were probably contained in these substances arriving at the sedimentary site. It is proposed that these humics were probably transported by acid surface waters (induced by the KT asteroid impact) into the shallow marine basin of Stevns Klint. It is also suggested that local leaching/weathering of the asteroidal impact fallout on the land near these waters played an important role in providing Ir, Ni and Zn for these substances. Apparently, Ir, Ni and Zn of the kerogen were created by the chondritic component of the impact ejecta fallout.


1985 ◽  
Vol 6 (2) ◽  
pp. 52-58 ◽  
Author(s):  
Susan T. Bagley

AbstractThe genus Klebsiella is seemingly ubiquitous in terms of its habitat associations. Klebsiella is a common opportunistic pathogen for humans and other animals, as well as being resident or transient flora (particularly in the gastrointestinal tract). Other habitats include sewage, drinking water, soils, surface waters, industrial effluents, and vegetation. Until recently, almost all these Klebsiella have been identified as one species, ie, K. pneumoniae. However, phenotypic and genotypic studies have shown that “K. pneumoniae” actually consists of at least four species, all with distinct characteristics and habitats. General habitat associations of Klebsiella species are as follows: K. pneumoniae—humans, animals, sewage, and polluted waters and soils; K. oxytoca—frequent association with most habitats; K. terrigena— unpolluted surface waters and soils, drinking water, and vegetation; K. planticola—sewage, polluted surface waters, soils, and vegetation; and K. ozaenae/K. rhinoscleromatis—infrequently detected (primarily with humans).


Author(s):  
James S. Webber

INTRODUCTION“Acid rain” and “acid deposition” are terms no longer confined to the lexicon of atmospheric scientists and 1imnologists. Public awareness of and concern over this phenomenon, particularly as it affects acid-sensitive regions of North America, have increased dramatically in the last five years. Temperate ecosystems are suffering from decreased pH caused by acid deposition. Human health may be directly affected by respirable sulfates and by the increased solubility of toxic trace metals in acidified waters. Even man's monuments are deteriorating as airborne acids etch metal and stone features.Sulfates account for about two thirds of airborne acids with wet and dry deposition contributing equally to acids reaching surface waters or ground. The industrial Midwest is widely assumed to be the source of most sulfates reaching the acid-sensitive Northeast since S02 emitted as a byproduct of coal combustion in the Midwest dwarfs S02 emitted from all sources in the Northeast.


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