Isotopic evolution of planetary crusts by hypervelocity impacts evidenced by Fe in microtektites

Fractionation effects related to evaporation and condensation had a major impact on the current elemental and isotopic composition of the Solar System. Although isotopic fractionation of moderately volatile elements has been observed in tektites due to impact heating, the exact nature of the processes taking place during hypervelocity impacts remains poorly understood. By studying Fe in microtektites, here we show that impact events do not simply lead to melting, melt expulsion and evaporation, but involve a convoluted sequence of processes including condensation, variable degrees of mixing between isotopically distinct reservoirs and ablative evaporation during atmospheric re-entry. Hypervelocity impacts can as such not only generate isotopically heavy, but also isotopically light ejecta, with δ56/54Fe spanning over nearly 5‰ and likely even larger variations for more volatile elements. The mechanisms demonstrated here for terrestrial impact ejecta modify our understanding of the effects of impact processing on the isotopic evolution of planetary crusts.

The formation of impact coesite

Coesite in impact rocks is traditionally considered a retrograde product formed during pressure release by the crystallisation of an amorphous phase (either silica melt or diaplectic glass). Recently, the detailed microscopic and crystallographic study of impact ejecta from Kamil crater and the Australasian tektite strewn field pointed in turn to a different coesite formation pathway, through subsolidus quartz-to-coesite transformation. We report here further evidence documenting the formation of coesite directly from quartz. In Kamil ejecta we found sub-micrometric single-coesite-crystals that represent the first crystallization seeds of coesite. Coesite in Australasian samples show instead well-developed subeuhedral crystals, growing at the expenses of hosting quartz and postdating PDF deformation. Coesite (010) plane is most often parallel to quartz {10–11} plane family, supporting the formation of coesite through a topotactic transformation. Such reaction is facilitated by the presence of pre-existing and shock-induced discontinuities in the target. Shock wave reverberations can provide pressure and time conditions for coesite nucleation and growth. Because discontinuities occur in both porous and non-porous rocks and the coesite formation mechanism appears similar for small and large impacts, we infer that the proposed subsolidus transformation model is valid for all types of quartz-bearing target rocks.

DART and LICIACUBE: Documenting Kinetic Impact

<p>The NASA Double Asteroid Redirection Test (DART) mission will demonstrate asteroid deflection by a kinetic impactor. DART will impact Dimorphos, the secondary member of the (65803) Didymos system, in late September to early October, 2022 in order to change the binary orbit period. DART will carry a 6U CubeSat called LICIACube, contributed by the Italian Space Agency, to document the DART impact and to observe the impact ejecta. LICIACube will be released by DART 10 days prior to Didymos encounter, and LICIACube will fly by Dimorphos at closest approach distance of about 51 km and with a closest approach time delay of about 167 s after the DART impact. LICIACube will observe the structure and evolution of the DART impact ejecta plume and will obtain images of the surfaces of both bodies at best ground sampling about 1.4 m per pixel. LICIACube imaging importantly includes the non-impact hemisphere of the target body, the side not imaged by DART.</p> <p> </p> <p>The LICIACube flyby trajectory, notably the closest approach distance and the time delay of closest approach, are designed to optimize the study of ejecta plume evolution without exposing the satellite to impact hazard. LICIACube imaging will determine the direction of the ejecta plume and the ejection angles, and will further help to determine the ejecta momentum transfer efficiency <em>β</em>. The ejecta plume structure, as it evolves over time, is determined by the amount of ejecta that has reached a given altitude at a given time. The LICIACube plume images enable characterization of the ejecta mass versus velocity distribution, which is strongly dependent on target properties like strength and porosity and is therefore a powerful diagnostic of the DART impact, complementary to measurements of the DART impact crater by the ESA Hera mission which will arrive at Didymos in 2026. Hera will measure crater radius and crater volume to determine the total volume of ejecta, which together with a ejecta mass-velocity distribution gives a full characterization of the DART impact.</p> <p> </p> <p>Models of the ejecta plume evolution as imaged by LICIACube show how LICIACube images can discriminate between different target physical properties (mainly strength and porosity), thereby allowing inferences of the magnitude of the ejecta momentum. Measured ejecta plume optical depth profiles can distinguish between gravity-controlled and strength-controlled impact cases and help determine target physical properties. LICIACube ejecta plume images further provide information on the direction of the ejecta momentum as well as the magnitude, requiring full 2-D simulations of the plume images. We will present new simulation model optical depth profiles across the plume at arbitrary positions.</p> <p><br />We thank NASA for support of the DART project at JHU/APL, under Contract # NNN06AA01C, Task Order # NNN15AA05T. The Italian LICIACube team acknowledges financial support from Agenzia Spaziale Italiana (ASI, contract No. 2019-31-HH.0 CUP<br />F84I190012600).</p>

Shocked quartz in distal ejecta from the Ries impact event (Germany) found at ~ 180 km distance, near Bernhardzell, eastern Switzerland

Impact ejecta formation and emplacement is of great importance when it comes to understanding the process of impact cratering and consequences of impact events in general. Here we present a multidisciplinary investigation of a distal impact ejecta layer, the Blockhorizont, that occurs near Bernhardzell in eastern Switzerland. We provide unambiguous evidence that this layer is impact-related by confirming the presence of shocked quartz grains exhibiting multiple sets of planar deformation features. Average shock pressures recorded by the quartz grains are ~ 19 GPa for the investigated sample. U–Pb dating of zircon grains from bentonites in close stratigraphic context allows us to constrain the depositional age of the Blockhorizont to ~ 14.8 Ma. This age, in combination with geochemical and paleontological analysis of ejecta particles, is consistent with deposition of this material as distal impact ejecta from the Ries impact structure, located ~ 180 km away, in Germany. Our observations are important for constraining models of impact ejecta emplacement as ballistically and non-ballistically transported fragments, derived from vastly different depths in the pre-impact target, occur together within the ejecta layer. These observations make the Ries ejecta one of the most completely preserved ejecta deposit on Earth for an impact structure of that size.

A potential subsurface cavity in the continuous ejecta deposits of the Ziwei crater discovered by the Chang’E-3 mission

In the radargram obtained by the high-frequency lunar penetrating radar onboard the Chang’E-3 mission, we notice a potential subsurface cavity that has a smaller permittivity compared to the surrounding materials. The two-way travel time between the top and bottom boundaries of the potential cavity is ~ 21 ns, and the entire zone is located within the continuous ejecta deposits of the Ziwei crater, which generally have similar physical properties to typical lunar regolith. We carried out numerical simulations for electromagnetic wave propagation to investigate the nature of this low-permittivity zone. Assuming different shapes for this zone, a comprehensive comparison between our model results and the observed radargram suggests that the roof of this zone is convex and slightly inclined to the south. Modeling subsurface materials with different relative permittivities suggests that the low-permittivity zone is most likely formed due to a subsurface cavity. The maximum vertical dimension of this potential cavity is ~ 3.1 m. While the continuous ejecta deposits of Ziwei crater are largely composed of pre-impact regolith, competent mare basalts were also excavated, which is evident by the abundant meter-scale boulders on the wall and rim of Ziwei crater. We infer that the subsurface cavity is supported by excavated large boulders, which were stacked during the energetic emplacement of the continuous ejecta deposits. However, the exact geometry of this cavity (e.g., the width) cannot be constrained using the single two-dimensional radar profile. This discovery indicates that large voids formed during the emplacement of impact ejecta should be abundant on the Moon, which contributes to the high bulk porosity of the lunar shallow crust, as discovered by the GRAIL mission. Our results further suggest that ground penetrating radar is capable of detecting and deciphering subsurface cavities such as lava tubes, which can be applied in future lunar and deep space explorations.

Dendritic reidite from the Chesapeake Bay impact horizon, Ocean Drilling Program Site 1073 (offshore northeastern USA): A fingerprint of distal ejecta?

High-pressure minerals provide records of processes not normally preserved in Earth’s crust. Reidite, a quenchable polymorph of zircon, forms at pressures >20 GPa during shock compression. However, there is no broad consensus among empirical, experimental, and theoretical studies on the nature of the polymorphic transformation. Here we decipher a multistage history of reidite growth recorded in a zircon grain in distal impact ejecta (offshore northeastern United States) from the ca. 35 Ma Chesapeake Bay impact event which, remarkably, experienced near-complete conversion (89%) to reidite. The grain displays two distinctive reidite habits: (1) intersecting sets of planar lamellae that are dark in cathodoluminescence (CL); and (2) dendritic epitaxial overgrowths on the lamellae that are luminescent in CL. While the former is similar to that described in literature, the latter has not been previously reported. A two-stage growth model is proposed for reidite formation at >40 GPa in Chesapeake Bay impact ejecta: formation of lamellar reidite by shearing during shock compression, followed by dendrite growth, also at high pressure, via recrystallization. The dendritic reidite is interpreted to nucleate on lamellae and replace damaged zircon adjacent to lamellae, which may be amorphous ZrSiO4 or possibly an intermediate phase, all before quenching. These results provide new insights on the microstructural evolution of the highpressure polymorphic transformation over the microseconds-long interval of reidite stability during meteorite impact. Given the formation conditions, dendritic reidite may be a unique indicator of distal ejecta.