scholarly journals The synthesis, structure and photoluminescence property of a novel 3D supramolecular compound based on mixed ligands of 8-hydroxy-quionline-5-sulfonate and ethylenediamine

2011 ◽  
Vol 76 (11) ◽  
pp. 1497-1504 ◽  
Author(s):  
Ying Wang ◽  
Changfu Zhuang ◽  
Chunhua Wu ◽  
Jiayan Zhang ◽  
Wang Li ◽  
...  
Keyword(s):  
Room Temperature ◽  
Three Dimensional ◽  
Photoluminescence Property ◽  
Supramolecular Network ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mixed Ligands ◽  
Structure Solution ◽  
Hydroxy Quinoline ◽  
Hybrid Coordination

A new organic-inorganic hybrid coordination compound ZnQS (en)?2H2O (1) in which two different organic ligands, ethylenediamine (en) and 8-hydroxy-quinoline-5-sulfonic acid (H2QS) coordinate with zinc ions, has been synthesized via the evaporation method and characterized by single crystal X-ray diffraction analysis, IR spectroscopy and thermogravimetric analysis (TGA). The structure solution showed that compound 1 displays a three-dimensional supramolecular network by synergic linkage of hydrogen and coordinated bonds. Moreover, compound 1 exhibits intense photoluminescence at 513 nm excited at 396 nm in the solid state at room temperature.

A Silver(I) Coordination Polymer Based on a Schiff Base Ligand: Synthesis, Crystal Structure and Luminescence Properties

2013 ◽  
Vol 68 (3) ◽  
pp. 284-288 ◽  
Author(s):  
Lin Yu Jin ◽  
Meng Meng Li ◽  
Dong Bin Dang ◽  
Yan Bai ◽  
Yan Ning Zheng
Keyword(s):  
Coordination Polymer ◽  
Room Temperature ◽  
Three Dimensional ◽  
Chain Structure ◽  
Luminescence Properties ◽  
Tridentate Ligand ◽  
Supramolecular Network ◽  
Zigzag Chain ◽  
X Ray Diffraction ◽  
X Ray

A new Ag(I) coordination polymer [AgL(NO3)]n 1 (L=4-(pyridine-2-yl)methyleneamino-1,2,4- trizaole) has been synthesized and characterized by IR spectroscopy, elemental analysis, powder and single-crystal X-ray diffraction. The Ag(I) atom has a seesaw environment with an N3O donor set from three N atoms of two ligands and one O atom of one NO-3 anion. Each twisted tridentate ligand is bound to two silver centers, and each silver atom is coordinated by two ligands thereby generating a zigzag chain structure. The chains interact with each other featuring a three-dimensional supramolecular network through multiple weak C-H···π interactions and C-H···O hydrogen bonds. The luminescence properties of the polymer 1 were investigated in the solid state at room temperature.

scholarly journals Synthesis, Crystal Structure, and Properties of a New Coordination Polymer Built from N/O-Donor Mixed Ligands

Crystals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 372
Author(s):  
Mei-An Zhu ◽  
Shuai-Shuai Han ◽  
Feng Deng ◽  
Jia-Le Li ◽  
Shui-Sheng Chen
Keyword(s):  
Coordination Polymer ◽  
Weak Interactions ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Tridentate Ligand ◽  
Supramolecular Polymer ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mixed Ligands ◽  
Benzenedicarboxylic Acid

The coordination polymer, namely, [Cd(H2L)(nobda)]n (1) was prepared by the reaction of Cd(NO3)2·4H2O with 4-amino-1,2-benzenedicarboxylic acid (H2nobda) and 1,4-di(1H-imidazol-4-yl)benzene (H2L), and characterized by single-crystal X-ray diffraction, elemental analysis, infrared (IR) spectroscopy, thermogravimetric analysis, and powder X-ray diffraction (PXRD). The carboxylic acid of H2nobda ligands was completely deprotonated to be nobda2− anions, which act as tridentate ligand to connect the Cd2+ to form two-dimensional (2D) network, while the neutral H2L ligands serve as a linear didentate bridge to connect two adjacent Cd2+ ions upper and down the 2D layer. The adjacent 2D layers were further linked into the three-dimensional (3D) supramolecular polymer by the weak interactions such as hydrogen bonds and π−π stacking interactions. The ultraviolet-visible (UV-vis) absorption spectra and luminescent properties in the solid state at room temperature have been investigated.

Metal-Controlled Assembly Tuning Coordination Polymers with Flexible 2-(1H-imidazole-1-yl)acetic Acid (Hima)

2006 ◽  
Vol 59 (9) ◽  
pp. 647 ◽  
Author(s):  
Yong-Tao Wang ◽  
Gui-Mei Tang ◽  
Da-Wei Qin
Keyword(s):  
Coordination Polymers ◽  
Weak Interactions ◽  
Critical Role ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Water Medium ◽  
New Materials ◽  
X Ray Diffraction ◽  
X Ray ◽  
Supramolecular Networks

Three new inorganic–organic coordination polymers based on a versatile linking unit 2-(1H-imidazole-1-yl)acetate (Hima) and divalent Mn(ii), Ni(ii), and Cu(ii) ions, exhibiting two kinds of two dimensionalities with different topological structures, have been prepared in water medium and structurally characterized by single-crystal X-ray diffraction analysis. Reaction of MnCl2·4H2O and Ni(NO3)2·6H2O with Hima yielded neutral two-dimensional (2D) coordination polymers [M(ima)2]n, M = Mn(ii) 1, and Ni(ii) 2 with isostructural 2D coordination polymers possessing (3,6) topology structures, which further stack into three-dimensional (3D) supramolecular networks through C–H···O weak interactions. However, when Cu(NO3)2·4H2O was used, a neutral 2D coordination polymer [Cu(ima)2]n 3 consisting of rhombus units was generated, which showed a 3D supramolecular network through C–H···O weak interactions. Among these polymers, the building block ima anion exhibits different coordination modes. These results indicate that the versatile nature of this flexible ligand, together with the coordination preferences of the metal ions, plays a critical role in construction of these novel coordination polymers. Spectral and thermal properties of these new materials have also been investigated.

Synthesis and Crystal Structure of a Cadmium(II) Complex with 2-(4΄-Chlorine-Benzoyl)-Benzoic Acid and 1,10-Phenanthroline

2011 ◽  
Vol 339 ◽  
pp. 313-316
Author(s):  
Xiu Mei Li ◽  
Zhi Tao Wang ◽  
Qing Wei Wang
Keyword(s):  
Benzoic Acid ◽  
Room Temperature ◽  
Supramolecular Network ◽  
X Ray Diffraction ◽  
Organic Complex ◽  
Orthorhombic Space Group ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Metal Organic Complex ◽  
Metal Organic

A new metal-organic complex Cd2(cbba)4(phen)2 (Hcbba = 2-(4΄-chlorine-benzoyl)- benzoic acid, phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The compound crystallizes in orthorhombic, space group Pbcn with a = 12.0976(4), b = 18.0925(6), c = 31.6829(10) Å, V = 6934.6(4) Å3, C80H48Cd2Cl4N4O12, Mr = 1623.82, Dc = 1.555 g/cm3, μ(MoKα) = 0.8365 mm1, F(000) = 3264, Z = 4, the final R = 0.0396 and wR = 0.0960 for 5372 observed reflections (I > 2(I)). It exhibits a 3D supramolecular network through π-π interactions and shows green luminescent property at room temperature.

Two new CdII MOFs of 1,4-bis(1H-benzimidazol-1-yl)butane and flexible dicarboxylate ligands: luminescence sensing towards Fe3+

2020 ◽  
Vol 76 (11) ◽  
pp. 1024-1033
Author(s):  
Fang-Hua Zhao ◽  
Shi-Yao Li ◽  
Wen-Yu Guo ◽  
Zi-Hao Zhao ◽  
Xiao-Wen Guo ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Solid State ◽  
Hydrogen Bonds ◽  
Layer Structure ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Vis Spectroscopy

Two new CdII MOFs, namely, two-dimensional (2D) poly[[[μ2-1,4-bis(1H-benzimidazol-1-yl)butane](μ2-heptanedioato)cadmium(II)] tetrahydrate], {[Cd(C7H10O4)(C18H18N4)]·4H2O} n or {[Cd(Pim)(bbimb)]·4H2O} n (1), and 2D poly[diaqua[μ2-1,4-bis(1H-benzimidazol-1-yl)butane](μ4-decanedioato)(μ2-decanedioato)dicadmium(II)], [Cd2(C10H16O4)2(C18H18N4)(H2O)2] n or [Cd(Seb)(bbimb)0.5(H2O)] n (2), have been synthesized hydrothermally based on the 1,4-bis(1H-benzimidazol-1-yl)butane (bbimb) and pimelate (Pim2−, heptanedioate) or sebacate (Seb2−, decanedioate) ligands. Both MOFs were structurally characterized by single-crystal X-ray diffraction. In 1, the CdII centres are connected by bbimb and Pim2− ligands to generate a 2D sql layer structure with an octameric (H2O)8 water cluster. The 2D layers are further connected by O—H...O hydrogen bonds, resulting in a three-dimensional (3D) supramolecular structure. In 2, the CdII centres are coordinated by Seb2− ligands to form binuclear Cd2 units which are linked by bbimb and Seb2− ligands into a 2D hxl layer. The 2D layers are further connected by O—H...O hydrogen bonds, leading to an 8-connected 3D hex supramolecular network. IR and UV–Vis spectroscopy, thermogravimetric analysis and solid-state photoluminescence analysis were carried out on both MOFs. Luminescence sensing experiments reveal that both MOFs have good selective sensing towards Fe3+ in aqueous solution.

A fourfold interpenetrating diamond-like three-dimensional zinc(II) coordination polymer: synthesis, crystal structure and physical properties

2019 ◽  
Vol 75 (5) ◽  
pp. 504-507 ◽  
Author(s):  
Hui-Ru Chen
Keyword(s):  
Crystal Structure ◽  
Room Temperature ◽  
Three Dimensional ◽  
Fluorescence Emission ◽  
Crystal Structure Analysis ◽  
The Novel ◽  
X Ray Diffraction ◽  
Metal Compounds ◽  
X Ray ◽  
Coordination Framework

Excellent fluorescence properties are exhibited by d 10 metal compounds. The novel three-dimensional ZnII coordination framework, poly[[{μ2-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether-κ2 N 3:N 3′}(μ2-furan-2,5-dicarboxylato-κ2 O 2:O 5)zinc(II)] 1.76-hydrate], {[Zn(C6H2O5)(C20H18N4O)]·1.76H2O} n , has been prepared and characterized using IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal structure analysis revealed that the compound exhibits a novel fourfold interpenetrating diamond-like network. This polymer also displays a strong fluorescence emission in the solid state at room temperature.

A coordination polymer of mercury(II) formed by triazole-based and chloride linkers

2017 ◽  
Vol 72 (8) ◽  
pp. 573-577 ◽  
Author(s):  
Seyed Ghorban Hosseini ◽  
Keyvan Moeini ◽  
Mohammed S.M. Abdelbaky ◽  
Santiago García-Granda
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coordination Numbers ◽  
H Nmr ◽  
Square Planar ◽  
Polymeric Chains ◽  
Ft Ir ◽  
Hybrid Coordination

AbstractIn this work, a coordination polymer formed from 4,5-diamino-3-methyl-4H-1,2,4-triazol-1-ium chloride (DAMT·HCl) and HgCl2 formulated as [Hg5(μ-DAMT)2(μ-Cl)6(μ3-Cl)2Cl2]n has been prepared and characterized by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. X-ray analysis of the complex revealed an organic-inorganic hybrid coordination polymer containing three different mercury atoms with coordination numbers of 4 (HgN(μ-Cl)2(μ3-Cl)), 5 (Hg(μ-Cl)3(μ3-Cl)Cl), and 6 (HgN2(μ-Cl)2(μ3-Cl)2) and seesaw, octahedral, and square pyramidal geometries, respectively. The polymeric chains are extended to a three-dimensional (3D) array by C–H···Cl and N–H···Cl interactions. In addition to these hydrogen bonds, there are Hg···Cl interactions with the mercury atoms with coordination numbers 4 and 5 to complete their pseudo-square planar and -octahedral geometries, respectively.

A new three-dimensional CdIIsupramolecular framework constructed from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand

2015 ◽  
Vol 71 (2) ◽  
pp. 93-96 ◽  
Author(s):  
Qiang Li ◽  
Hui-Ting Wang ◽  
Lin Zhou
Keyword(s):  
Crystal Packing ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Stacking Interactions ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Cl Atoms

A new tetrazole–metal supramolecular compound, di-μ-chlorido-bis(trichlorido{1-[(1H-tetrazol-5-yl-κN2)methyl]-1,4-diazoniabicyclo[2.2.2]octane}cadmium(II)), [Cd2(C8H16N6)2Cl8], has been synthesized and structurally characterized by single-crystal X-ray diffraction. In the structure, each CdIIcation is coordinated by five Cl atoms (two bridging and three terminal) and by one N atom from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand, adopting a slightly distorted octahedral coordination geometry. The bridging bicyclo[2.2.2]octane and chloride ligands link the CdIIcations into one-dimensional ribbon-like N—H...Cl hydrogen-bonded chains along thebaxis. An extensive hydrogen-bonding network formed by N—H...Cl and C—H...Cl hydrogen bonds, and interchain π–π stacking interactions between adjacent tetrazole rings, consolidate the crystal packing, linking the poymeric chains into a three-dimensional supramolecular network.

A three-dimensional CdIIcoordination framework: poly[di-μ2-aqua-{μ2-1,4-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene-κ2N4:N4′}di-μ3-terephthalato-κ3O:O′:O′′-dicadmium(II)]

2014 ◽  
Vol 70 (11) ◽  
pp. 1025-1028
Author(s):  
Hong Shen
Keyword(s):  
Solid State ◽  
Thermogravimetric Analysis ◽  
Room Temperature ◽  
Three Dimensional ◽  
Fluorescence Emission ◽  
Photoluminescence Properties ◽  
X Ray Diffraction ◽  
Strong Fluorescence ◽  
X Ray ◽  
Methyl Benzene

The title CdIIcoordination polymer, [Cd(C10H8O4)(C12H12N6)0.5(H2O)]n, has been obtained by the hydrothermal method and studied by single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, IR spectroscopy and fluorescence spectroscopy. The compound forms a novel three-dimensional framework with 3,8-connected three-dimensional binodal {4.52}2{42.510.612.7.83} topology. An investigation of its photoluminescence properties shows that the compound exhibits a strong fluorescence emission in the solid state at room temperature.

A twofold interpenetrating three-dimensional CdIIcoordination framework: poly[[μ2-1,3-bis(2-methyl-1H-imidazol-1-yl)benzene](μ3-5-nitrobenzene-1,3-dicarboxylato)cadmium(II)]

2014 ◽  
Vol 70 (12) ◽  
pp. 1138-1142 ◽  
Author(s):  
Le Li ◽  
Jian-Qing Tao
Keyword(s):  
Thermal Analysis ◽  
Solid State ◽  
Ir Spectroscopy ◽  
Room Temperature ◽  
Three Dimensional ◽  
Pentagonal Bipyramid ◽  
Asymmetric Unit ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coordination Framework

A twofold interpenetrating three-dimensional CdIIcoordination framework, [Cd(C8H3NO6)(C14H14N4)]n, has been prepared and characterized by IR spectroscopy, elemental analysis, thermal analysis and single-crystal X-ray diffraction. The asymmetric unit consists of a divalent CdIIatom, one 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene (1,3-BMIB) ligand and one fully deprotonated 5-nitrobenzene-1,3-dicarboxylate (NO2-BDC2−) ligand. The coordination sphere of the CdIIatom consists of five O-donor atoms from three different NO2-BDC2−ligands and two imidazole N-donor atoms from two different 1,3-BMIB ligands, forming a distorted {CdN2O5} pentagonal bipyramid. The NO2-BDC ligand links three CdIIatomsviaa μ1-η1:η1chelating mode and a μ2-η2:η1bridging mode. The title compound is a twofold interpenetrating 3,5-connected network with the {42.65.83}{42.6} topology. In addition, the compound exhibits fluorescence emissions in the solid state at room temperature.

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