scholarly journals Investigation of Hg 1-X Cdx te epitaxial vapor phase growth under isothermal conditions

1999 ◽  
Vol 64 (7-8) ◽  
pp. 463-470 ◽  
Author(s):  
Vesna Jovic ◽  
Zoran Djinovic

The Hg 1. x Cd x Te layers were grown by vapor phase epitaxy on Cd-terminated {111} CdTe single crystal substrates from a HgTe solid source under isothermal conditions in a semi-closed system with controlled Hg vapor pressure. The growth kinetics were investigated in the temperature region from 420?C to 550?C with different source to substrate spacings, varying from 1 to 11 mm. It was found that the dependence of the growth rate on temperature could be well described by an Arrhenius type equation with an activation energy of 80 kJ/mol in the investigated temperature interval. The activation energies for the crystallization were the same for all the investigated source to substrate spacing.This activation energy value points to the importance of a solid-state diffusion process in the Hg 1-x Cdx Te/CdTe epitaxial couple obtained by isothermal growth under the given experimental conditions.

1987 ◽  
Vol 66 (12) ◽  
pp. 1717-1720 ◽  
Author(s):  
F. Moya ◽  
J. Payan ◽  
J. Bernardini ◽  
E.G. Moya

A radiotracer technique was used to study silver and gold diffusion into dental porcelain under experimental conditions close to the real conditions in prosthetic laboratories for porcelain bakes. It was clearly shown that these non-oxidizable elements were able to diffuse into the ceramic as well as oxidizable ones. The penetration depth varied widely according to the element. The ratio DAg/DA u was about 103 around 850°C. In contrast to gold, the silver diffusion rate was high enough to allow silver, from the metallic alloy, to be present at the external ceramic surface after diffusion into the ceramic. Hence, the greening of dental porcelains baked on silver-rich alloys could be explained mainly by a solid-state diffusion mechanism.


2020 ◽  
Vol 28 ◽  
pp. 26-30
Author(s):  
Artur Mishevich Bagov ◽  
Anatoliy Amishevich Akhkubekov ◽  
Svetlana Nanievna Akhkubekova ◽  
Tanziliya Zhagafarovna Kumukova

The effect of Li and Sr impurities on the kinetics and structure formation of alloys in the Sn - Pb, In - Zn, Sn - Zn systems used in the soldering of instrument nodes in electronics has been investigated. The XPS method showed that under the given experimental conditions and the indicated concentrations of lithium impurities in lead and strontium in zinc, there are no prerequisites for the formation of chemical compounds, which is explained by an insignificant impurity content, although a significant amount of chemical compounds is formed according to state diagrams. It was also established that impurities affect the kinetics of phase growth in the junction zone.


Langmuir ◽  
2011 ◽  
Vol 27 (10) ◽  
pp. 6409-6417 ◽  
Author(s):  
Davide Barreca ◽  
Giorgio Carraro ◽  
Alberto Gasparotto ◽  
Chiara Maccato ◽  
Oleg I. Lebedev ◽  
...  

2008 ◽  
Vol 44 (1) ◽  
pp. 67-69 ◽  
Author(s):  
V. V. Bakovets ◽  
T. M. Levashova ◽  
I. Yu. Filatova ◽  
E. A. Maksimovskii ◽  
A. E. Kupcha

2002 ◽  
Vol 17 (1) ◽  
pp. 52-59 ◽  
Author(s):  
N.F. Gao ◽  
Y. Miyamoto

The joining of a Ti3SiC2 ceramic with a Ti–6Al–4V alloy was carried out at the temperature range of 1200–1400 °C for 15 min to 4 h in a vacuum. The total diffusion path of joining was determined to be Ti3SiC2/Ti5Si3Cx/Ti5Si3Cx + TiCx/TiCx/Ti. The reaction was rate controlled by the solid-state diffusion below 1350 °C and turned to the liquid-state diffusion controlled with a dramatic increase of parabolic rate constant Kp when the temperature exceeded 1350 °C. The TiCx tended to grow at the boundarywith the Ti–6Al–4V alloy at a higher temperature and longer holding time. TheTi3SiC2/Ti–6Al–4V joint is expected to be applied to implant materials.


2016 ◽  
Vol 686 ◽  
pp. 794-802 ◽  
Author(s):  
Yuan Yuan ◽  
Dajian Li ◽  
Yuanyuan Guan ◽  
Hans J. Seifert ◽  
Nele Moelans

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