scholarly journals Effects of Additions of Silver Chloride, Silver Bromide and Silver Iodide on the Characteristics of Electrical Contacts of Silver, Silver-Nickel and Silver-Carbon Contact Materials

1972 ◽  
Vol 36 (7) ◽  
pp. 638-642
Author(s):  
Mitsunori Sato ◽  
Masayuki Hijikata ◽  
Ichiro Morimoto
1975 ◽  
Vol 28 (8) ◽  
pp. 1657 ◽  
Author(s):  
UN Dash ◽  
B Nayak

From the e.m.f. measurements of the buffered cells of the type ��������������������� Pt, H2|HOAc(m1), KOAc(m2), KX(m3)|AgX-Ag the standard potentials of the Ag-AgX electrodes have been determined, in formamide, at nine different temperatures in the range 5-45�. The standard potentials of the Ag-AgX electrodes obtained at 25� are in good agreement with those obtained from the study of the cells ������������������ Ag-AgX|KX(m3), KOAc(m2), HOAc(m1), QH2-Q|Pt at 25�, where X is Br or I. The cell �������������������������Pt,H2|HBr(m)|AgBr-Ag has been further studied in this solvent at 25� with a view to having an independent check on these buffered cells for the standard potential of the Ag-AgBr electrode. The standard thermodynamic quantities (ΔG�, ΔH�, and ΔS�) for the corresponding cell reactions have been calculated from the e.m.f. data over the range, 5-45�.


1968 ◽  
Vol 23 (12) ◽  
pp. 2073-2076
Author(s):  
Cesare Sinistri ◽  
Giorgio Flor ◽  
Paolo Ferloni

Molten mixtures of AgCl, AgBr and AgI with alkali molibdates have been investigated. The silver chloride presents stratification phenomena only with Li2MoO4, the silver bromide demixes with Li2MoO4 and Na2MoO4 while the silver iodide demixes with Li2MoO4, Na2MoO4 and K2MoO4. The ability of demixing, for mixtures containing the same halide, increases as the radius of the alkali cation diminishes (or the polarizing power of the same increases).Moreover the whole composition square of the ternary reciprocal system Ag, Na/Br, MoO4 has been investigated.


2014 ◽  
Vol 631 ◽  
pp. 384-389 ◽  
Author(s):  
Daina Kalnina ◽  
Karlis Agris Gross ◽  
Pavels Onufrijevs ◽  
Edvins Dauksta ◽  
Vizma Nikolajeva ◽  
...  

Silver halides represent a yet unexplored avenue for imparting antimicrobial activity in calcium phosphates. Silver halide colloids were added to calcium phosphate. Concurrent melting of silver halides and crystallization of carbonated apatite was achieved by heating to increase the silver halide surface area available to bacteria.Pseudomonas aeruginosa were more sensitive to silver iodide and silver bromide than Staphylococcus aureus. Silver iodide demonstrated greater activity than silver bromide. Silver chloride did not produce an antibacterial response. Both amorphous calcium phosphate and carbonated apatite displayed similar antibacterial activity when accompanied by silver halides. It is thought that amorphous calcium phosphate dissolves more readily and increases the bioavailability of the silver halide particles. Silver iodide displays a greater antibacterial response of all silver halides, with a response that is improved in a more resorbable matrix.


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