scholarly journals Crystallization Behavior and Phase Formation in Zr–Al–Cu–Ni Metallic Glass Containing Oxygen

1998 ◽  
Vol 39 (6) ◽  
pp. 623-632 ◽  
Author(s):  
J. Eckert ◽  
N. Mattern ◽  
M. Zinkevitch ◽  
M. Seidel
2007 ◽  
Vol 22 (4) ◽  
pp. 1093-1097 ◽  
Author(s):  
J.B. Qiang ◽  
W. Zhang ◽  
G.Q. Xie ◽  
A. Inoue

The addition of Ti, Nb, or Ta altered the crystallization behavior of the Zr65Al7.5Cu27.5 glass, and a metastable nanoscaled I-phase was obtained on primary crystallization of these quaternary glasses. The complete substitution of Al by Nb also led to the precipitation of I-phase upon crystallization. Negative heats of mixing between the addition metals and the transition metals of the mother alloy were demonstrated to be not a necessary condition for I-phase formation in the present alloy system.


2019 ◽  
Author(s):  
F.X. Bai ◽  
S.J. Zheng ◽  
Y.X. Wang ◽  
J. Pan ◽  
J.H. Yao ◽  
...  

2021 ◽  
Vol 565 ◽  
pp. 120855
Author(s):  
J.W. Lv ◽  
D.W. Yin ◽  
F.L. Wang ◽  
Y.J. Yang ◽  
M.Z. Ma ◽  
...  

2019 ◽  
Vol 26 (08) ◽  
pp. 1950037
Author(s):  
BO SHI ◽  
SHIYU LUAN ◽  
PEIPENG JIN

Nanoscale dimples and periodic corrugations are observed on the fracture surface of Zr-based bulk metallic glass composite (BMGC). The nanoscale periodic corrugations display a curved shape, which is different from that observed in previous works. In addition, the crystallization behavior of [Formula: see text][Formula: see text][Formula: see text][Formula: see text] BMG was investigated. The second crystallization event of Zr-Cu-Ni-Al BMG can be controlled by annealing or tuning cooling rate. The in situ Zr-based BMGC was prepared via lowering cooling rate. The Zr-based BMGC displays completely brittleness.


2010 ◽  
Vol 37 (8) ◽  
pp. 2104-2110 ◽  
Author(s):  
刘伟伟 Liu Weiwei ◽  
林鑫 Lin Xin ◽  
杨高林 Yang Gaolin ◽  
杨海欧 Yang Hai′ou ◽  
黄卫东 Huang Weidong ◽  
...  

2020 ◽  
Vol 1158 ◽  
pp. 43-97
Author(s):  
Muhammad Musaddique Ali Rafique

Bulk metallic glass matrix composites have emerged as new potential material for structural engineering applications owing to their superior strength, hardness and high elastic strain limit. However, their behaviour is dubious. They manifest brittleness and inferior ductility which limit their applications. Various methods have been proposed to overcome this problem. Out of these, introduction of foreign particles (inoculants) during solidification have been proposed as most effective. In this study, an effort has been made to delimit this drawback. A systematic tale has been presented which explain the evolution of microstructure in Zr47.5Cu45.5Al5Co2 and Zr65Cu15Al10Ni10 bulk metallic glass matrix composites with varying percentage of ZrC inoculant as analysed by secondary electron and back scatter electron imaging of as cast unetched samples. A support is provided to hypothesis that inoculation remain successful in promoting phase formation and crystallinity and improve toughness.


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