The Effect of Synthesis Parameters on Luminescence Properties of Ca-α-Sialon:Eu2+

2013 ◽  
Vol 58 (4) ◽  
pp. 1309-1312 ◽  
Author(s):  
D. Michalik ◽  
M. Sopicka-Lizer ◽  
T. Pawlik ◽  
R. Lisiecki
Keyword(s):  
Optical Properties ◽  
Phase Composition ◽  
Strong Influence ◽  
Solid State Reaction Method ◽  
Synthesis Temperature ◽  
Luminescence Properties ◽  
Reflection Spectra ◽  
Reaction Method ◽  
Structure And Morphology ◽  
Synthesis Parameters

Abstract The goal of this study was to investigate influence of the synthesis parameters on the luminescence properties of Ca- α -Sialon doped with Eu2+. The compound of Eu0:07Ca0:73Si9:6Al2:4O0:8N15:2 was prepared by the solid state reaction method from the mixture of the relevant oxides, Si3N4 and CaCO3. Synthesis was carried out in the temperature range of 1600-1700°C for 2-8 h in a reduction atmosphere (N2+CO). The structure and morphology of obtained powders were analyzed by XRD and SEM/EDS methods, respectively. Content of nitrogen/oxygen was also measured. Optical properties were investigated by excitation, emission and reflection spectra. Obtained results show strong influence of synthesis temperature on the phase composition and intensity of emission of Ca- -Sialon:Eu2+ powder compound.

scholarly journals Developments of crystal structures and photoluminescence properties of Sr0.85Eu0.15Al12O19 green phosphors using different synthesis parameters

2021 ◽  
Author(s):  
Jie Li ◽  
Qing-Hao Yang ◽  
Hsin-Hua Li ◽  
Cheng-Fu Yang ◽  
David Jui-Yang Feng
Keyword(s):  
Crystal Structures ◽  
Solid State Reaction Method ◽  
Synthesis Temperature ◽  
Emission Peak ◽  
Photoluminescence Excitation ◽  
Photoluminescence Properties ◽  
Apparent Effect ◽  
Reaction Method ◽  
Pl Spectra ◽  
Synthesis Parameters

First, a solid-state reaction method was used to synthesize a [Formula: see text] phosphor at 1250[Formula: see text]C–1400[Formula: see text]C for 1 h, and its crystal structures and photoluminescence properties were investigated as a function of synthesis temperature. When the furnace reached the synthesis temperature, the 5% [Formula: see text] reduction atmosphere was infused and the reduction atmosphere was removed as the temperature was dropped to 800[Formula: see text]C. When 1200[Formula: see text]C was used as the synthesis temperature, the [Formula: see text], [Formula: see text], and [Formula: see text] phases co-existed; only one weak emission peak was observed in the photoluminescence excitation (PLE) spectra, and two weak emission peaks were observed in the photoluminescence emission (PL) spectra. When the [Formula: see text] phosphors were synthesized at a temperature higher than 1200[Formula: see text]C, the diffraction intensities of [Formula: see text], [Formula: see text], and [Formula: see text] phases were almost unchanged, but the crystal sizes of [Formula: see text] powders increased. For [Formula: see text] phosphors, PLE spectra had one broad exciting band with two centered wavelengths of 317 and 365 nm, and PL spectra had one emission band with one centered wavelength of 513 nm. As the synthesis temperature rose, the emission intensities of PLE and PL spectra increased. Second, we show that the removed temperature of reduction atmosphere of [Formula: see text] phosphors had an apparent effect on their emission properties of PLE and PL spectra.

Luminescence properties of dysprosium doped calcium magnesium silicate phosphor by solid state reaction method

2015 ◽  
Vol 649 ◽  
pp. 1329-1338 ◽  
Author(s):  
Ishwar Prasad Sahu ◽  
Priya Chandrakar ◽  
R.N. Baghel ◽  
D.P. Bisen ◽  
Nameeta Brahme ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Magnesium Silicate ◽  
Solid State Reaction Method ◽  
Luminescence Properties ◽  
Reaction Method ◽  
Silicate Phosphor ◽  
Calcium Magnesium

Broadband near-infrared BaMSi3O9:Cr3+ (M = Zr, Sn, Hf) phosphors for light-emitting diode applications

2021 ◽  
Author(s):  
Yan Zhang ◽  
Yanjie Liang ◽  
Shihai Miao ◽  
Dongxun Chen ◽  
Shao Yan ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Near Infrared ◽  
Light Emitting Diode ◽  
Solid State Reaction Method ◽  
Luminescence Properties ◽  
Light Emitting ◽  
Reaction Method ◽  
Simple Solid State Reaction

A series of Cr3+-doped BaMSi3O9 (M = Zr, Sn, Hf) near-infrared emitting phosphors with tunable luminescence properties have been successfully synthesized by using a simple solid-state reaction method. The developed...

The long persistent luminescence properties of phosphors: Li2ZnGeO4 and Li2ZnGeO4:Mn2+

RSC Advances ◽  
2014 ◽  
Vol 4 (22) ◽  
pp. 11360-11366 ◽  
Author(s):  
Yahong Jin ◽  
Yihua Hu ◽  
He Duan ◽  
Li Chen ◽  
Xiaojuan Wang
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Luminescence Properties ◽  
Persistent Luminescence ◽  
Reaction Method

The blue emitting long persistent phosphor (LPP) Li2ZnGeO4 and green emitting LPP Li2ZnGeO4:Mn2+ were newly prepared by a high temperature solid-state reaction method.

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