Three-dimensional diagnostics in air and water by molecular tagging and molecular scattering

1996 ◽  
Author(s):  
R. Miles ◽  
W. Lempert
2000 ◽  
Author(s):  
J. S. Park ◽  
K. D. Kihm ◽  
D. M. Pratt

Abstract The development of a molecular tagging fluorescence velocimetry (MTFV) system is discussed and measurement results are presented for a meso-scale flow field of thermally driven capillary pore of 5-mm inner diameter that is tilted 5° from the horizon. The developed technique uses caged Dextran conjugates of caged fluorescene dyes of less than 10 nm in size for tracers. The frequency-tripled UV band (λ = 355 nm) of a pulsed Nd:YAG laser uncages the molecules by photo-cleaving that is decomposition of a caging chemical group and a fluorescence chemical group. Then a CW blue Argon-ion laser (λ = 488 nm) pumps the fluorescence of only those uncaged molecules, whose emmission band is centered at λ = 518 nm, and a sequential recording of the fluorescence images are digitally recorded and analyzed for Lagrangian velocity field mapping. The use of the technique allows detailed measurements of the thermally driven three-dimensional flow inside a heated capillary pore. The measurement shows that the meniscus surface flow is mainly driven by the thermocapillary stress field, occurring due to the surface temperature gradient, while the bulk flow inside the pore is driven largely by the natural convection buoyancy. The whole capillary flow is made by a combination of these two different flow effects. As to the heater position, above or below the interface, the three dimensional flow patterns are measured totally in the opposite way.


1983 ◽  
Vol 404 (1 Fourth Intern) ◽  
pp. 347-347
Author(s):  
R. Goulard ◽  
P. J. Emmerman ◽  
R. J. Santoro ◽  
H. G. Semerjian

Recent experiments in high-energy molecular spectroscopy have shown that coarse grained molecular spectra are often very simple, characterized by a few frequencies or correlation times. Experiments in molecular scattering such as the hydrogen exchange reactions have demonstrated the existence of short-lived resonances. I show that these seemingly differing experiments may be interpreted and assigned in terms of the normal modes of periodic orbits, which are determined by a linear stability analysis. Specific examples include three-dimensional resonances of the hydrogen exchange reaction as well as three-dimensional high-energy bound states of the Hg molecular ion. A new semiclassical quantization method based on unstable periodic orbits is presented and used to explain the observed scarring of high-energy quantum states.


2013 ◽  
Vol 38 (11) ◽  
pp. 1893 ◽  
Author(s):  
Jian Gao ◽  
Daniel R. Guildenbecher ◽  
Phillip L. Reu ◽  
Varun Kulkarni ◽  
Paul E. Sojka ◽  
...  

2021 ◽  
Vol 92 (5) ◽  
pp. 053526
Author(s):  
D. J. Schlossberg ◽  
R. M. Bionta ◽  
D. T. Casey ◽  
M. J. Eckart ◽  
D. N. Fittinghoff ◽  
...  

Author(s):  
R. Goulard ◽  
P.J. Emmerman ◽  
R.J. Santoro ◽  
H.G. Semerjian

2016 ◽  
Vol 16 (21) ◽  
pp. 13791-13806 ◽  
Author(s):  
Shi Song ◽  
K. Sebastian Schmidt ◽  
Peter Pilewskie ◽  
Michael D. King ◽  
Andrew K. Heidinger ◽  
...  

Abstract. In this paper, we used cloud imagery from a NASA field experiment in conjunction with three-dimensional radiative transfer calculations to show that cloud spatial structure manifests itself as a spectral signature in shortwave irradiance fields – specifically in transmittance and net horizontal photon transport in the visible and near-ultraviolet wavelength range. We found a robust correlation between the magnitude of net horizontal photon transport (H) and its spectral dependence (slope), which is scale-invariant and holds for the entire pixel population of a domain. This was surprising at first given the large degree of spatial inhomogeneity. We prove that the underlying physical mechanism for this phenomenon is molecular scattering in conjunction with cloud spatial structure. On this basis, we developed a simple parameterization through a single parameter ε, which quantifies the characteristic spectral signature of spatial inhomogeneities. In the case we studied, neglecting net horizontal photon transport leads to a local transmittance bias of ±12–19 %, even at the relatively coarse spatial resolution of 20 km. Since three-dimensional effects depend on the spatial context of a given pixel in a nontrivial way, the spectral dimension of this problem may emerge as the starting point for future bias corrections.


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