Thermal Stability of N-Heterocycle-Stabilized Iodanes – A Systematic Investigation
Keyword(s):
<p>The thermal stability of pseudocyclic and cyclic <i>N</i>-heterocycle-stabilized (hydroxy)aryl- and mesityl(aryl)-l<sup>3</sup>-iodanes (NHIs) through thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) is investigated. NHIs bearing <i>N</i>-heterocycles with a high N/C-ratio such as triazoles show among the lowest descomposition temperatures and the highest decomposition energies. A comparison of NHIs with known (pseudo)cyclic benziodoxolones is made and we further correlated their thermal stability with reactivity in a model oxygenation. </p>
2019 ◽
Vol 15
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pp. 2311-2318
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pp. 263-279
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2008 ◽
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pp. 2718-2726
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Thermal stability of fatty acid-serum albumin complexes studied by differential scanning calorimetry
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pp. 189-196
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2018 ◽
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pp. 20383-20392
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