scholarly journals Unconventional Superconductivity in Samarium Nitride

2021 ◽  
Author(s):  
◽  
William Doonan

<p>We have studied the nature of unconventional superconductivity in the rare-earth nitride (REN) samarium nitride (SmN) for the purposes of providing a deeper understanding of the mechanisms that lead to such a phenomenon in an already extremely interesting material. An approximate low energy model has been introduced for SmN based on previous bandstructure calculation and recent experimental results. This consists of the non-dispersive 4f band associated with the samarium ion crossing through the dispersive 5d band associated with the nitrogen ion. Due to large spin polarisation in the bandstructure we need only consider the majority-spin 5d and 4f bands which lead to an essentially spinless two band system. Starting from this two band system, we apply the k dot p method to it in order to create an effective model for the system. This effective model for the material acts as the platform from which we study the possible triplet superconducting pairing. Basing our pairing on the electron-phonon interaction we have postulated the existence of triplet pairing in the 5d band, from which we have successfully characterised the pair potential in this system through the self-consistency equation. The pair potential Delta_d could be solved analytically in a special case where the Fermi level was equal to the 4f band. In this case we find that above a threshold effective coupling strength the superconducting state is established and analytically known. In contrast to this result for the more general case where the Fermi level is different to the 4f band we numerically recover a solution that was exponential in the effective coupling strength which is similar to the pairing as we expect from the single band case. Analytic solutions in this case were not able to be found, however, we know that from our numerical investigations there will exist a solution for any effective coupling strength, contrasting with the special case where the pairing amplitude can disappear below a certain threshold. In conjunction to these results we also examined the situation where the 5d and 4f bands have hybridised together in order to search for unique pairing that may be resistant to disorder. By keeping the triplet pairing only in the 5d band, this translates to hybrid pairing between electrons in the two hybridised bands. Results from the hybridised bands system show a new singlet-like pairing Delta_S which is even in k and singlet in the hybridised band indices. Preliminary numerical results suggest that this pairing indeed exists and occurs only near the avoided crossing of the hybridised bands. The existence of such a pairing, originating from triplet pairing, has exciting implications for the robustness of the superconductivity in the presence of disorder and/or impurities.</p>

2021 ◽  
Author(s):  
◽  
William Doonan

<p>We have studied the nature of unconventional superconductivity in the rare-earth nitride (REN) samarium nitride (SmN) for the purposes of providing a deeper understanding of the mechanisms that lead to such a phenomenon in an already extremely interesting material. An approximate low energy model has been introduced for SmN based on previous bandstructure calculation and recent experimental results. This consists of the non-dispersive 4f band associated with the samarium ion crossing through the dispersive 5d band associated with the nitrogen ion. Due to large spin polarisation in the bandstructure we need only consider the majority-spin 5d and 4f bands which lead to an essentially spinless two band system. Starting from this two band system, we apply the k dot p method to it in order to create an effective model for the system. This effective model for the material acts as the platform from which we study the possible triplet superconducting pairing. Basing our pairing on the electron-phonon interaction we have postulated the existence of triplet pairing in the 5d band, from which we have successfully characterised the pair potential in this system through the self-consistency equation. The pair potential Delta_d could be solved analytically in a special case where the Fermi level was equal to the 4f band. In this case we find that above a threshold effective coupling strength the superconducting state is established and analytically known. In contrast to this result for the more general case where the Fermi level is different to the 4f band we numerically recover a solution that was exponential in the effective coupling strength which is similar to the pairing as we expect from the single band case. Analytic solutions in this case were not able to be found, however, we know that from our numerical investigations there will exist a solution for any effective coupling strength, contrasting with the special case where the pairing amplitude can disappear below a certain threshold. In conjunction to these results we also examined the situation where the 5d and 4f bands have hybridised together in order to search for unique pairing that may be resistant to disorder. By keeping the triplet pairing only in the 5d band, this translates to hybrid pairing between electrons in the two hybridised bands. Results from the hybridised bands system show a new singlet-like pairing Delta_S which is even in k and singlet in the hybridised band indices. Preliminary numerical results suggest that this pairing indeed exists and occurs only near the avoided crossing of the hybridised bands. The existence of such a pairing, originating from triplet pairing, has exciting implications for the robustness of the superconductivity in the presence of disorder and/or impurities.</p>


Science ◽  
2019 ◽  
Vol 366 (6462) ◽  
pp. 238-241 ◽  
Author(s):  
Yufan Li ◽  
Xiaoying Xu ◽  
M.-H. Lee ◽  
M.-W. Chu ◽  
C. L. Chien

Magnetic flux quantization is one of the defining properties of a superconductor. We report the observation of half-integer magnetic flux quantization in mesoscopic rings of superconducting β-Bi2Pd thin films. The half-quantum fluxoid manifests itself as a π phase shift in the quantum oscillation of the superconducting critical temperature. This result verifies unconventional superconductivity of β-Bi2Pd and is consistent with a spin-triplet pairing symmetry. Our findings may have implications for flux quantum bits in the context of quantum computing.


1995 ◽  
Vol 78 (10) ◽  
pp. 6276-6282 ◽  
Author(s):  
M. Gottschlich ◽  
E. Sodtke ◽  
Y. Zhang ◽  
A. M. Portis

1957 ◽  
Vol 18 (1) ◽  
pp. 89-91
Author(s):  
Tetsuro Kobayashi ◽  
Jun'ichi Osada ◽  
Smio Tani

2018 ◽  
Vol 41 ◽  
Author(s):  
Daniel Crimston ◽  
Matthew J. Hornsey

AbstractAs a general theory of extreme self-sacrifice, Whitehouse's article misses one relevant dimension: people's willingness to fight and die in support of entities not bound by biological markers or ancestral kinship (allyship). We discuss research on moral expansiveness, which highlights individuals’ capacity to self-sacrifice for targets that lie outside traditional in-group markers, including racial out-groups, animals, and the natural environment.


Author(s):  
Dr. G. Kaemof

A mixture of polycarbonate (PC) and styrene-acrylonitrile-copolymer (SAN) represents a very good example for the efficiency of electron microscopic investigations concerning the determination of optimum production procedures for high grade product properties.The following parameters have been varied:components of charge (PC : SAN 50 : 50, 60 : 40, 70 : 30), kind of compounding machine (single screw extruder, twin screw extruder, discontinuous kneader), mass-temperature (lowest and highest possible temperature).The transmission electron microscopic investigations (TEM) were carried out on ultra thin sections, the PC-phase of which was selectively etched by triethylamine.The phase transition (matrix to disperse phase) does not occur - as might be expected - at a PC to SAN ratio of 50 : 50, but at a ratio of 65 : 35. Our results show that the matrix is preferably formed by the components with the lower melting viscosity (in this special case SAN), even at concentrations of less than 50 %.


Author(s):  
D J H Cockayne ◽  
D R McKenzie

The study of amorphous and polycrystalline materials by obtaining radial density functions G(r) from X-ray or neutron diffraction patterns is a well-developed technique. We have developed a method for carrying out the same technique using electron diffraction in a standard TEM. It has the advantage that studies can be made of thin films, and on regions of specimen too small for X-ray and neutron studies. As well, it can be used to obtain nearest neighbour distances and coordination numbers from the same region of specimen from which HREM, EDS and EELS data is obtained.The reduction of the scattered intensity I(s) (s = 2sinθ/λ ) to the radial density function, G(r), assumes single and elastic scattering. For good resolution in r, data must be collected to high s. Previous work in this field includes pioneering experiments by Grigson and by Graczyk and Moss. In our work, the electron diffraction pattern from an amorphous or polycrystalline thin film is scanned across the entrance aperture to a PEELS fitted to a conventional TEM, using a ramp applied to the post specimen scan coils. The elastically scattered intensity I(s) is obtained by selecting the elastically scattered electrons with the PEELS, and collecting directly into the MCA. Figure 1 shows examples of I(s) collected from two thin ZrN films, one polycrystalline and one amorphous, prepared by evaporation while under nitrogen ion bombardment.


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