DENITRIFICATION KINETICS OF PSEUDOMONAS STUTZERI AZ101

Nitrogen removal from environment is significant due to its effect on health and the whole ecosystems. Hence a highly nitrogen tolerant aerobic denitrifier, Pseudomonas stutzeri AZ101 was isolated from aquaculture wastewater and characterized using 16S rRNA analysis. The ability of the isolate to carry out simultaneously nitrification and denitrification (SND) was investigated. Different initial concentrations of nitrate and ammonium were used to determine the rate of SND. The denitrification data fitted well with the second order reaction kinetics with correlation coefficient between 0.923-0.9588. The nitrification data does not fit to both first and second order reaction kinetic but progressive shifts in the logarithm phase of the growth were observed at different initial concentrations. The kinetics data provide a significant insight to nitrogen removal from the wastewater.

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Kinetics of the reaction between hexamethylenediisocyanate and 1-pentanol

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19833279 ◽

1983 ◽

Vol 48 (11) ◽

pp. 3279-3286

Author(s):

Slavko Hudeček ◽

Miloslav Bohdanecký ◽

Ivana Hudečková ◽

Pavel Špaček ◽

Pavel Čefelín

Keyword(s):

Liquid Chromatography ◽

Rate Constants ◽

Reversed Phase ◽

Order Reaction ◽

Second Order ◽

Second Order Reaction ◽

Reversed Phase Liquid Chromatography ◽

Consecutive Reactions ◽

Phase Liquid ◽

Kinetics Of

The reaction between hexamethylenediisocyanate and 1-pentanol in toluene was studied by means of reversed-phase liquid chromatography. By employing this method, it was possible to determine all components of the reaction mixture including both products, i.e. N-(6-isocyanate hexyl)pentylcarbamate and N,N'-bis(pentyloxycarbonyl)hexamethylenediamine. Relations for the calculation of kinetic constants were derived assuming a competitive consecutive second-order reaction. It was demonstrated that the reaction involved in this case is indeed a second-order reaction, and the rate constants of the first and second consecutive reactions were determined.

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Kinetics of binding the mRNA cap analogues to the translation initiation factor eIF4E under second-order reaction conditions

Biophysical Chemistry ◽

10.1016/j.bpc.2007.06.009 ◽

2007 ◽

Vol 129 (2-3) ◽

pp. 289-297 ◽

Cited By ~ 4

Author(s):

Elżbieta Błachut-Okrasińska ◽

Elżbieta Bojarska ◽

Janusz Stępiński ◽

J.M. Antosiewicz

Keyword(s):

Translation Initiation ◽

Order Reaction ◽

Second Order ◽

Translation Initiation Factor ◽

Initiation Factor ◽

Second Order Reaction ◽

Reaction Conditions ◽

Kinetics Of

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Power optimization of chemically driven heat engine based on first and second order reaction kinetic theory and probability theory

Physica A Statistical Mechanics and its Applications ◽

10.1016/j.physa.2015.11.009 ◽

2016 ◽

Vol 445 ◽

pp. 221-230 ◽

Cited By ~ 18

Author(s):

Lei Zhang ◽

Lingen Chen ◽

Fengrui Sun

Keyword(s):

Probability Theory ◽

Kinetic Theory ◽

Reaction Kinetic ◽

Power Optimization ◽

Heat Engine ◽

Order Reaction ◽

Second Order ◽

Second Order Reaction

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Kinetics and thermodynamics of the reaction between thyroxine and antithyroxine antiserum under the conditions of radioimmunoanalysis

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19822077 ◽

1982 ◽

Vol 47 (8) ◽

pp. 2077-2086

Author(s):

Peter Talán ◽

Juraj Mucha

Keyword(s):

Reaction Rate ◽

Serum Proteins ◽

Relative Rate ◽

Order Reaction ◽

Second Order ◽

Second Order Reaction ◽

Reaction Enthalpy ◽

Thermodynamics And Kinetics ◽

Relative Rate Constants ◽

Kinetics Of

Thermodynamics and kinetics of the reaction between thyroxine and antithyroxine antiserum has been studied using the concentration and temperature conditions usual in the radioimmunoanalysis. The reaction is assumed to be homogeneous and of the second order. Because of the initial concentrations of thyroxine and of the free bonds of the heterogeneous population of antibodies present in the used antiserum the rate constant equation for second-order reaction has been used in the integrated form. The relative rate constants have been obtained and the activation energy of the reaction in absence of the serum proteins in the reaction mixture or, respectively, in the presence of the euthyroidic serum has been calculated. The nature of the effect of so-called deblockators (J) (8-anilino-1-naphthalene sulphonic acid and tiomersal) on the reaction rate and on the change of the reaction enthalpy (or entropy) has also been investigated. The association constant of this reaction has been evaluated from the radioimmunoanalytical data transformed by the Scatchard relation, modified for the conditions of thyroxine radioimmunoanalysis.

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