scholarly journals Tribological Investigation of Self-Healing Composites Containing Metal/Polymer Microcapsules

Author(s):  
Dawei Sun ◽  
◽  
Jianhua Yan ◽  
Xiaoyu Ma ◽  
Mingzhang Lan ◽  
...  
Keyword(s):  
Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1760
Author(s):  
Rose K. Baimuratova ◽  
Gulzhian I. Dzhardimalieva ◽  
Evgeniy V. Vaganov ◽  
Valentina A. Lesnichaya ◽  
Gulsara D. Kugabaeva ◽  
...  

We report here our successful attempt to obtain self-healing supramolecular hydrogels with new metal-containing monomers (MCMs) with pendent 4-phenyl-2,2′:6′,2″-terpyridine metal complexes as reversible moieties by free radical copolymerization of MCMs with vinyl monomers, such as acrylic acid and acrylamide. The resulting metal-polymer hydrogels demonstrate a developed system of hydrogen, coordination and electron-complementary π–π stacking interactions, which play a critical role in achieving self-healing. Kinetic data show that the addition of a third metal-containing comonomer to the system decreases the initial polymerization rate, which is due to the specific effect of the metal group located in close proximity of the active center on the growth of radicals.


2019 ◽  
Vol 6 (4) ◽  
Author(s):  
Vladimir Erofeev ◽  
Valeriy Kruglov ◽  
Nikolay Vatin ◽  
Salman Dawood Salman Al-Dulaimi

It is shown that during operation reinforced concrete structures are very often susceptible to cracking, which leads to a deterioration in the quality and expected life of them. The traditional methods of restoration and strengthening of structures are methods of building up, impregnating the structure of concrete with polymer and other materials, applying monolithic coatings or gluing metal polymer and other elements. Known repair methods are characterized by high complexity of execution, high cost, etc. It is shown that there is a pressing economic incentive for the development of concrete capable of self-repairing and repairing damage. Recently, tendencies toward the creation of new materials that are capable of actively interacting with external factors have been outlined towards world practice; such materials have received the name “intellectual”. The use of «intelligent» materials allows you to monitor and predict the state of various structures and structures, at the required time and even in hard-to-reach areas, significantly increase the resource of engineering systems and their reliability. It has been shown that to date, various chemical methods have been developed for creating self-healing concrete. One of the breakthrough technologies in the field of obtaining effective materials and structures based on them are biotechnologies based on the use of microorganisms. Many researchers have studied the use of calcite produced by bacteria to increase the life of concrete-based structures and restore buildings by eliminating cracks, increasing the strength of concrete, reducing permeability, and reducing water absorption. The article provides an overview of the work of foreign specialists in these areas.


2020 ◽  
Vol 11 (41) ◽  
pp. 6549-6558
Author(s):  
Yohei Miwa ◽  
Mayu Yamada ◽  
Yu Shinke ◽  
Shoichi Kutsumizu

We designed a novel polyisoprene elastomer with high mechanical properties and autonomous self-healing capability at room temperature facilitated by the coexistence of dynamic ionic crosslinks and crystalline components that slowly reassembled.


1982 ◽  
Vol 118 (4) ◽  
pp. 267-272 ◽  
Author(s):  
E. Bonifazi
Keyword(s):  

1988 ◽  
Vol 49 (C5) ◽  
pp. C5-49-C5-59 ◽  
Author(s):  
P. S. HO ◽  
R. HAIGHT ◽  
R. C. WHITE ◽  
B. D. SILVERMAN

1995 ◽  
Vol 131 (4) ◽  
pp. 459-461 ◽  
Author(s):  
R. Caputo
Keyword(s):  

1986 ◽  
Vol 14 (1) ◽  
pp. 44-72 ◽  
Author(s):  
C. M. Mc C. Ettles

Abstract It is proposed that tire-pavement friction is controlled by thermal rather than by hysteresis and viscoelastic effects. A numerical model of heating effects in sliding is described in which the friction coefficient emerges as a dependent variable. The overall results of the model can be expressed in a closed form using Blok's flash temperature theory. This allows the factors controlling rubber friction to be recognized directly. The model can be applied in quantitative form to metal-polymer-ice contacts. Several examples of correlation are given. The difficulties of characterizing the contact conditions in tire-pavement friction reduce the model to qualitative form. Each of the governing parameters is examined in detail. The attainment of higher friction by small, discrete particles of aluminum filler is discussed.


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