Sodium Diethyldithiocarbamate

1993 ◽  
Vol 58 (8) ◽  
pp. 1813-1820 ◽  
Author(s):  
Jan Vácha ◽  
Lumír Sommer

The sorption of uranyl ions on columns with the macrophorus hydrophobic sorbent Amberlite XAD 4 modified with 1-(2-pyridylazo)-2-naphthol and sodium diethyldithiocarbamate was examined. Following elution of the uranyl ion with HNO3 (2 - 4 mol l-1) or of the diethyldithiocarbamate UO22+-chelate with a methanolic solution of HCl (0.1 mol l-1), uranium was determined spectrophotometrically with 4-(2-pyridylazo)resorcinol or with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol. The preconcentration of uranium on Amberlite XAD 4 type sorbents is convenient for its spectrophotometric determination in waters.


1988 ◽  
Vol 6 (11) ◽  
pp. 1785-1787 ◽  
Author(s):  
D R Gandara ◽  
E A Perez ◽  
M W DeGregorio ◽  
R Borch

Solar RRL ◽  
2021 ◽  
pp. 2000811
Author(s):  
Miriam Más-Montoya ◽  
David Curiel ◽  
Junke Wang ◽  
Bardo J. Bruijnaers ◽  
René A. J. Janssen

Author(s):  
W. R. G. Atkins

Sea water contains very little zinc. Values from 0–73 mg. per cubic metre have been cited in Physics of the Earth, V, 180, Washington, 1932. According to Orton it is less than 0–1 parts per million in the English Channel. Dieulafait found 2 nig. and Bodansky 7–3, erroneously quoted as 73 above. The method described here permits of the detection of as little as 8 mg. per m3 using 200 ml. of distilled water in a Hehner tube, the delicacy of the reaction being much greater than that of any other for zinc. Sea water from the English Channel gives no turbidity and so is unlikely to contain as much as 8 mg. per m3. The method is brought forward on account of its usefulness in detecting and estimating zinc in sea water contaminated by contact with metallic surfaces. Its use in fresh water has already been described (Analyst, 1935, 60, p. 400, No. 711, June), and to this paper reference may be made for some possible sources of interference and for the origin of the reagent.


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