Mathematical modeling of nonstationary 1:1 electrolyte transfer and study of the space charge region in membrane systems taking into account electric convection and water dissociation/recombination reactions

Author(s):  
M.Kh. Urtenov ◽  
A.V. Kovalenko ◽  
M.V. Sharafan ◽  
V.A. Gudza ◽  
N.O. Chubyr
2015 ◽  
Vol 22 ◽  
pp. 29-34 ◽  
Author(s):  
Patric Büchele ◽  
Mauro Morana ◽  
Diego Bagnis ◽  
Sandro Francesco Tedde ◽  
David Hartmann ◽  
...  

2002 ◽  
Vol 91 (11) ◽  
pp. 9147-9150 ◽  
Author(s):  
S. von Aichberger ◽  
O. Abdallah ◽  
F. Wünsch ◽  
M. Kunst

2016 ◽  
Vol 4 (19) ◽  
pp. 7437-7444 ◽  
Author(s):  
Jonathan M. Polfus ◽  
Tor S. Bjørheim ◽  
Truls Norby ◽  
Rune Bredesen

First-principles calculations were utilized to elucidate the complete defect equilibria of surfaces of proton conducting BaZrO3, encompassing charged species adsorbed to the surface, defects in the surface layer as well as in the subsurface space-charge region and bulk.


1973 ◽  
Vol 28 (3-4) ◽  
pp. 417-428 ◽  
Author(s):  
G. Ecker

Abstractfor given values of the total current density j and the cathode spot surface temperature T a unified and consistent calculation of the cathode drop, Uc , the electron temperature in the ionization region T _- the electron emission current density je , the ion current density j+ , and the extension of the space charge region lsp are presented.We find that the counter diffusion of plasma electrons into the space charge region plays a decisive role. It causes an effective space charge region extension lsp of a few plasma electron Debey lengths which in general is much less than the ion mean-free-path commonly used. Without the effect of the counter diffusing electrons, the theoretical results deviate from the experimental data by orders of magnitude.For the example of a Cu metal vapour-or vacuum arc the cathode drop is found to be approximately Uc = 15 [V], the electron temperature about T- =25000 [°K] and the ratio j+/j= 0.5.Since the analysis allows for multiple ionization the presence of multiply charged ions in the spot area can be calculated.The results of this investigation justify within the E-areas the approximations used in the analysis for the copper arc in an earlier investigation 1. Outside these E-areas a recalculation with the new results derived here may cause markable changes.


Sign in / Sign up

Export Citation Format

Share Document