scholarly journals The background content of heavy metals in the water of small rivers in the Nadym – Pur interfluvial area

Author(s):  
A. V. Soromotin ◽  
A. A. Kudryavtsev ◽  
A. A. Efimova ◽  
O. V. Gerter ◽  
N. N. Fefilov

This article considers the problem of the formation of the microelement water composition of the small rivers not directly affected by the oil and gas industrial complex in the Nadym-Pur interstream area. Physicochemical characteristics and ionic composition of the natural water samples are determined by chemical aqueous method, the total content of heavy metals is analyzed by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). More than 99% of the sum of all the heavy metal mass with concentration above 0,1 mcg/dm3 is defined by the presence of fourteen metals ranged as following: Fe>>Mn>>Sr>Ba>Zn>Rb>Cu>Co>Ni>V>Ce>Zr>Pb>La. Groups of such metals as manganese and strontium, nickel and cobalt, lead, zinc and copper, vanadium and zirconium, cerium and lanthanum form the concentration сlusters. In comparison to large and average rivers, water samples from small rivers contain higher concentrations of iron and manganese, and lower concentrations of zinc. The Fe and Mn content may vary depending on such characteristics as water color index and water turbidity. The significant exceedance of MACf of Fe and Mn is observed everywhere. The excess of zinc, caused by natural factors is occasionally fixed. The defined variability ranges for the heavy metal contents in water of small rivers located beyond the reach of the oil and gas industrial complexes effects are suggested to consider as modern background regional values of the heavy metal concentrations throughout water-collecting area of Nadym and Pur rivers in Yamalo-Nenets Autonomous Okrug of Tyumen region.

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Vivian Pedrinelli ◽  
Rafael Vessecchi Amorim Zafalon ◽  
Roberta Bueno Ayres Rodrigues ◽  
Mariana Pamplona Perini ◽  
Renata Maria Consentino Conti ◽  
...  

Abstract Pet owners often don’t acknowledge the need for home-prepared diet formulation by a trained professional and may use recipes from sources such as the internet. Macronutrient and mineral composition of home-prepared diets were analyzed and compared to NRC and FEDIAF recommendations, and heavy metal concentrations were analyzed and compared to FDA maximum tolerable levels (MTL) for dogs and cats. Recipes of home-prepared diets for adult dogs (n = 75) and cats (n = 25) were evaluated. Analyses of protein, fat, and fiber were performed according to AOAC, and mineral and heavy metal analyses were performed using inductively coupled plasma optical emission spectrometry (ICP-OES). None of the diets supplied recommended levels of all nutrients evaluated, and more than 84.0% of diets presented three or more nutrients below recommendations. Nutrients with most levels below recommendations were calcium and potassium in recipes for dogs and iron and zinc in recipes for cats. As for heavy metals, levels of lead, cobalt, mercury, uranium, and vanadium were above MTLs. Results suggest that home-prepared diets may be a health risk to dogs and cats if not properly formulated. Furthermore, the chronic heavy metal intake must be better elucidated in order to understand the full impact of results.


2018 ◽  
Vol 7 (4.35) ◽  
pp. 219
Author(s):  
Haron S.H ◽  
Ismail S ◽  
Sidek L.M

The existence of heavy metals residues in water, soil and air poses a serious risk to all living organisms. Heavy metals, such as Cd, Pb, Cr, Ni, and Hg, are major sources of environmental pollution, especially in areas with high anthropogenic and agriculture activities. The objective of this study is to determine the status of heavy metal concentrations of Cd, Cr, Ni, Pb, Zn, Cu, and Fe in the water bodies of Bertam River, which passes through agricultural areas. The water samples were collected randomly in three replicates from 10 sampling points along the Bertam River. The heavy metals in the water were extracted by using filter paper with a pore size of 0.45 mm. The extracted water sample was preserved by adding nitric acid (pH <2). Sample concentrations were then tested for metal concentrations using inductively coupled plasma mass spectrometry. In this study, the highest mean concentration was Fe (96.04 ± 90.43 ppb), followed by Zn (5.68 ± 0.2.34 ppb), Cu (5.13 ± 2.98 ppb), Cr (1.53 ± 0.19 ppb), Ni (0.85 ± 0.22 ppb), Pb (0.85 ± 1.61 ppb), and Cd (0.027 ± 0.02 ppb), where Fe> Zn> Cu> Pb> Cr> Ni> Cd. However, the concentrations of selected heavy metals in the water samples were below the standards recommended by the World Health Organization.


2021 ◽  
Vol 13 (8) ◽  
pp. 4508
Author(s):  
Lenka Štofejová ◽  
Juraj Fazekaš ◽  
Danica Fazekašová

A high content of heavy metals in the soil and plants of a magnesite mining area might cause serious damage to the environment and can be a threat to the health of the surrounding population. This paper presents the results of research that focused on analyzing the heavy metal content in soil and plants in the dumping grounds of the magnesite mining factory Jelšava-Lubeník (Slovakia). The analysis focused on the content of heavy metals in soil (X-ray fluorescence spectrometry, atomic absorption spectrometry), in plants (inductively coupled plasma mass spectrometry, inductively coupled plasma atomic emission spectrometry), and pH (1M KCl solution). The results showed that the soil in the study area was slightly acidic to strongly alkaline and the content of Cr, As, Mn, and Mg exceeded by several times the limit values for the Slovak Republic. The results of the hierarchical cluster analysis and the correlation analysis show that the grouped metals come from the same sources of pollution. The content of heavy metals in plants was high and the highest concentration was found in the roots of Elytrigia repens > Agrostis stolonifera > Phragmites australis and flowers of Phragmites australis. The findings confirmed the suitability of the used plants in the process of phytoextraction and phytostabilization. The acquired knowledge can help in planning and realization remediation measures and improve the state of the environment in areas exposed to magnesite mining.


Author(s):  
Horacio Sabejon Factura

<p>Pit latrine (PL) is one of the most common disposal systems for human excreta in low-income countries but because it is a hole in the ground, infiltration of liquid effluent into the soil can continuously occur. Poor sanitation systems permit the spread of heavy metals in urine to water bodies especially the groundwater. This study investigated the accumulation of heavy metals in shoots of corn plants irrigated with urine. A pot experiment with corn was conducted under greenhouse conditions. Urine was diluted to 3:1 ratio (water and urine respectively) and was compared to control (water only). Using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), heavy metals such as Boron, Barium, Cobalt, Copper, Iron, Manganese, Nickel, Silicon, Strontium and Zinc were detected in shoots of all plants with contents ranging from 0.22 to 2,487.44 milligram (mg) per kilogram (kg). The higher amounts detected in urine irrigated plants than the control proved the presence of the metals in the urine. Reuse of urine will definitely benefit farmers while at the same time reduce the risk of heavy metal contamination in groundwater.</p>


2021 ◽  
pp. 096032712199321
Author(s):  
M Charehsaz ◽  
S Helvacıoğlu ◽  
S Çetinkaya ◽  
R Demir ◽  
O Erdem ◽  
...  

In this study, the level of arsenic (As), lead (Pb) and cadmium (Cd) and also essential elements in beer samples consumed in Turkey were investigated using the inductively coupled plasma mass spectrometry (ICP-MS) method. The heavy metal-induced non-carcinogenic and carcinogenic risks were calculated. For essential elements, the calculated estimated daily intake of iron (Fe), copper (Cu), selenium (Se) and cobalt (Co) from beer consumption were compared with their toxicity reference values. Tukey post-hoc test showed that As was found at a significantly higher level when compared to Pb. Also, a significant correlation was found between As level and alcohol by volume percent. All samples had a hazard quotient and hazard index <1, indicating no non-carcinogenic risk from exposure to single or multiple heavy metals. Some samples exceeded the threshold limit of acceptable cancer risk for As in the high beer consumer group. This assessment showed that in addition to health implications based on the alcohol content of beer, there might be a carcinogenic risk associated with the heavy metals content of these beverages.


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