scholarly journals Effect of Different Solvents on Biginelli Reaction Using Layered Double Hyroxide (LDH) As an Ecofriendly Catalyst

2021 ◽  
pp. 223-226
Author(s):  
N. S. Ghotkar ◽  
D. A. Pund ◽  
B. N. Berad
Keyword(s):  
Layered Double Hydroxide ◽  
Efficient Method ◽  
Polar Solvent ◽  
Biginelli Reaction ◽  
High Yield ◽  
One Pot ◽  
Double Hydroxide ◽  
Biginelli Condensation

A simple and efficient method of the 3,4- dihydropyrimidin-2(1H)-ones/thiones synthesis in good to high yield is described. It consists in a one-pot three-component Biginelli condensation using Layered double hydroxide (LDH) as catalyst. The effect of different solvents on the yields of final product also been studied. Highly polar solvent as well as highly non-polar gives less yields in presence of LDH catalyst.

scholarly journals One-Pot Intercalation Strategy for the Encapsulation of a CO-Releasing Organometallic Molecule in a Layered Double Hydroxide

2020 ◽  
Vol 2020 (28) ◽  
pp. 2726-2736
Author(s):  
Isabel B. Calhau ◽  
Ana C. Gomes ◽  
Sofia M. Bruno ◽  
Ana C. Coelho ◽  
Clara I. R. Magalhães ◽  
...  
Keyword(s):  
Layered Double Hydroxide ◽  
One Pot ◽  
Double Hydroxide

Layered double hydroxide and sulindac coiled and scrolled nanoassemblies for storage and drug release

RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16419-16436 ◽  
Author(s):  
Michele A. Rocha ◽  
Philippe A. D. Petersen ◽  
Erico Teixeira-Neto ◽  
Helena M. Petrilli ◽  
Fabrice Leroux ◽  
...  
Keyword(s):  
Drug Release ◽  
Layered Double Hydroxide ◽  
Layered Double Hydroxides ◽  
P Systems ◽  
Synthetic Method ◽  
One Pot ◽  
High Crystallinity ◽  
Anti Inflammatory ◽  
Double Hydroxide ◽  
Double Hydroxides

Systems comprising anti-inflammatory sulindac intercalated into biocompatible layered double hydroxides nanovehicles were isolated through one pot synthetic method and showed high crystallinity and curled or scrolled particles.

One-pot synthesis of Ni-Co layered double hydroxide nanosheets as efficient catalysts for oxygen evolution reaction

2019 ◽  
Vol 20 ◽  
pp. 100596 ◽  
Author(s):  
Xiaoyong Ma ◽  
Pengkun Wei ◽  
Yang Yang ◽  
Hongzhi Kang ◽  
Donggang Guo ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Oxygen Evolution Reaction ◽  
One Pot ◽  
One Pot Synthesis ◽  
Double Hydroxide

One-pot synthesis of sandwich-like reduced graphene oxide@CoNiAl layered double hydroxide with excellent pseudocapacitive properties

2015 ◽  
Vol 3 (20) ◽  
pp. 10858-10863 ◽  
Author(s):  
Peipei Huang ◽  
Changyan Cao ◽  
Yongbin Sun ◽  
Shuliang Yang ◽  
Fang Wei ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Layered Double Hydroxide ◽  
Nickel Aluminum ◽  
One Pot ◽  
One Pot Synthesis ◽  
Cobalt Nickel ◽  
Reduced Graphene ◽  
Double Hydroxide

Sandwich-like nanocomposites with cobalt nickel aluminum layered double hydroxide growth on both sides of reduced graphene oxide show excellent pseudocapacitive properties.

scholarly journals One-Pot Synthesis of (Z)-β-Halovinyl Ketones via the Cascade of Sonogashira Coupling and Hydrohalogenation

2021 ◽  
Vol 8 ◽  
Author(s):  
Fa-Jie Chen ◽  
Zhenguo Hua ◽  
Jianhui Chen ◽  
Jiajia Chen ◽  
Daesung Lee ◽  
...  
Keyword(s):  
Efficient Method ◽  
Room Temperature ◽  
Copper Catalyst ◽  
High Yield ◽  
Sonogashira Coupling ◽  
Terminal Alkynes ◽  
Acid Chlorides ◽  
Triflic Acid ◽  
One Pot

Herein, we report an efficient method for the synthesis of (Z)-β-halovinyl ketones through a one-pot Sonogashira coupling and hydrohalogenation reaction promoted by palladium-copper catalyst and Brønsted acid. The ynone intermediates are generated in situ from readily available acid chlorides and terminal alkynes at room temperature, which are directly converted to (Z)-β-halovinyl ketones by treating with triflic acid. This method avoids the use of an external halogen source and features broad substrate scope, high yield, and good to excellent stereoselectivity.

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