scholarly journals Stability and Transportation of Iron Oxide Nanoparticles in Subsurface Water and Soil

2021 ◽  
Vol 14 ◽  
pp. 1-9
Author(s):  
Nur Suraya Ahmad ◽  
Shahidan Radiman ◽  
Wan Zuhairi Wan Yaacob

Iron oxide nanoparticles are utilised in a broad range of applications (magnetic data storage, biosensing, drug delivery, treatment and remediation of contaminated soil and groundwater); causing noticeable quantities of iron oxide nanoparticles to be released into the environment. In this study, aggregation and stability of iron oxide nanoparticles in water were investigated within the range of pH 3 – pH 9 at a constant concentration of iron oxide nanoparticles and humic acid. The pH of the solution was selected to be continuously monitored at pH 7 to investigate the transportation and deposition behaviour of iron oxide nanoparticles in porous media at different velocities. It was found that iron oxide nanoparticles were aggregated and settle down as settled particles at low pH (pH 3 – pH 5). Iron oxide nanoparticles were stable, mobile and transported at a high pH, which is the pH range of natural water (pH 6.5 – pH 8.5). Iron oxide nanoparticles were strongly attached to the silica sand at natural water velocity in porous media, which is 2.93 ml min-1. Overall, the presence of humic acid in aquifers and porous media, the pH range of natural water (pH 6.5 – pH 8.5) and the slow speed (2.93 ml min-1) of water are expected to be a key factor that enhances the stability and mobility of iron oxide nanoparticles in natural water and porous media.

RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105239-105251 ◽  
Author(s):  
Matthew J. O'Hara ◽  
Jennifer C. Carter ◽  
Cynthia L. Warner ◽  
Marvin G. Warner ◽  
R. Shane Addleman

The sorption performance of two amphoteric magnetic nanomaterials, Fe3O4and Mn-doped Fe3O4, has been evaluated for Po, Ra, U, and Am in natural waters (river, ground, and sea) as well as human urine across a pH range.


2019 ◽  
Vol 26 (29) ◽  
pp. 30044-30054 ◽  
Author(s):  
Shilpa Gnanamuthu Singaraj ◽  
Biswanath Mahanty ◽  
Darshan Balachandran ◽  
Anamika Padmaprabha

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
M. Golzar ◽  
S. F. Saghravani ◽  
M. Azhdari Moghaddam

Recently, iron nanoparticles have attracted more attention for groundwater remediation due to its potential to reduce subsurface contaminants such as PCBs, chlorinated solvents, and heavy metals. The magnetic properties of iron nanoparticles cause to attach to each other and form bigger colloid particles of iron nanoparticles with more rapid sedimentation rate in aqueous environment. Using the surfactants such as poly acrylic acid (PAA) prevents iron nanoparticles from forming large flocs that may cause sedimentation and so increases transport distance of the nanoparticles. In this study, the transport of iron oxide nanoparticles (Fe3O4) stabilized with PAA in a one-dimensional porous media (column) was investigated. The slurries with concentrations of 20,100 and 500 (mg/L) were injected into the bottom of the column under hydraulic gradients of 0.125, 0.375, and 0.625. The results obtained from experiments were compared with the results obtained from numerical solution of advection-dispersion equation based on the classical colloid filtration theory (CFT). The experimental and simulated breakthrough curves showed that CFT is able to predict the transport and fate of iron oxide nanoparticles stabilized with PAA (up to concentration 500 ppm) in a porous media.


2015 ◽  
Vol 51 (14) ◽  
pp. 2863-2866 ◽  
Author(s):  
K. Mandel ◽  
M. Straßer ◽  
T. Granath ◽  
S. Dembski ◽  
G. Sextl

Ferrofluids of superparamagnetic Fe3O4 nanoparticles with “patchy” silica shell are stable over a wide pH range and in physiological solutions.


2021 ◽  
Vol 33 (12) ◽  
pp. 3031-3038
Author(s):  
Arti Jangra ◽  
Jaiveer Singh ◽  
Radhika Khanna ◽  
Parvin Kumar ◽  
Suresh Kumar ◽  
...  

In present work, the synthesis of the humic acid functionalized iron oxide nanoparticles and their application in water treatment are reported. The bare and humic acid functionalized iron oxide nanoparticles were characterized using different techniques such as X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. The synthesized magnetite nanoparticles coated with humic acid showed efficient removal of crystal violet dye from the aqueous solution. The functionalized magnetite nanoparticles were found to have higher adsorption capacity as compared to bare magnetite nanoparticles and the pure humic acid under specific conditions. The adsorption kinetics study was found in accordance with pseudo-second order kinetics while the isotherm data was observed to be in good agreement with the Tempkin isotherm. A comparative study of dye removal efficiency of humic acid functionalized magnetite nanoparticles with reported adsorbents has also been made.


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