Semi-bleached paper and fermentation products from a larch biorefinery

TAPPI Journal ◽  
2012 ◽  
Vol 11 (10) ◽  
pp. 31-39 ◽  
Author(s):  
HANNA HÖRHAMMER ◽  
OKSANA BEREZINA ◽  
EERO HILTUNEN ◽  
TOM GRANSTRÖM ◽  
ADRIAAN VAN HEININGEN

This study was focused on the products from a larch biorefinery, specifically bleached paper and different fermentation products. Siberian larch (Larix sibirica Lebed.) wood chips were treated with water in a pre-extraction (PE) stage. The larch extract was removed by drainage and fermented into different products. Eight different bacteria strains were tested. The extracted wood chips were mildly washed before kraft pulping with polysulfide (PS) and anthraquinone (AQ). The PE-PSAQ pulps were bleached to about 80% brightness. Laboratory paper sheets were made and tested for different paper properties, and a conventional larch kraft pulp was also prepared as reference. The larch PE-PSAQ paper and the larch kraft paper had similar properties. The removal of a significant amount of hemicelluloses from the wood chips before pulping was not a detriment to the paper properties.

Holzforschung ◽  
2012 ◽  
Vol 66 (7) ◽  
pp. 801-808 ◽  
Author(s):  
Esa Saukkonen ◽  
Jesse Kautto ◽  
Irina Rauvanto ◽  
Kaj Backfolk

Abstract To clarify the influence of prehydrolysis on fiber characteristics, Scots pine (Pinus sylvestris L.) wood chips were subjected to pressurized hot-water and dilute-acid prehydrolysis (0.5% H2SO4) prior to kraft pulping to partially remove hemicelluloses as hydrolyzate. After the prehydrolysis, the wood chips were submitted to kraft pulping and the pulp was fully bleached in oxygen (O), chlorine dioxide (D), alkaline extraction (E) and chlorine dioxide (D)-sequence. Measurements with an automated optical fiber analyzer showed that prehydrolysis prior to kraft pulping caused significant changes in the fiber dimensions and morphology of the final bleached pulp. Especially, a decrease in fiber width and an increase in fiber deformations were observed compared to a reference kraft pulp. The scanning electron microscopy of handsheets supported the morphology analyses and revealed alterations also in the fiber ultrastructure. The changes in both chemical and physical fiber characteristics require attention when considering the correct processing and end-use of prehydrolysis-kraft pulp fibers.


2014 ◽  
Vol 900 ◽  
pp. 285-288
Author(s):  
Qi Xing Liu ◽  
Yang Chen ◽  
Jie He ◽  
Xin Gao

In this paper, the low-temperature (the maximum pulping temperature was less than 150°C) and conventional (the maximum pulping temperature was 165°C) kraft pulp of pinus kesiya and Dendrocalamus giganteus Munro were bleached by OQPaP. Then bleaching properties and paper properties of two kinds of bleached pulp were compared and evaluated respectively. The results showed that the strength indexes of the kraft pulp at low temperature were significantly higher than those of conventional pulp with lower viscosity.


2019 ◽  
Author(s):  
◽  
Nhlanhla Hlongwa

In this study, a comparison of two pulping methods namely mechanical and chemical, on the dissolution of Eucalyptus grandis (E. grandis) wood chips was undertaken. The wood chip pulp was treated with an ionic liquid (IL): 1-allyl-3-methylimidazolium chloride to extract the cellulose. The IL was mixed with unbleached mechanical pulp (UBMP), bleached mechanical pulp (BMP), unbleached kraft pulp (UBKP) and bleached kraft pulp (BKP) in ratios of 10%, 20%, 30%. Each solution contained IL, wood pulp and 2-mL of 16 v/v % of dimethyl sulfoxide (DMSO). The 30 % IL pretreatment was the most effective IL pretreatment. The cellulose yield at 30 % IL pretreatment for UBMP, BMP, UBKP and BKP was 65.12%, 63.82%, 67.43%, 67.15%, respectively. This indicated that the kraft pulping method was more effective than the mechanical pulping method for the yield of cellulose after the IL pretreatment. The Crl value at 30 % IL pretreatment was highest for UBMP (72.03%) indicating that the pretreatment used was the least effective in reducing the cellulose crystallinity. The fractions of E. grandis wood chip namely, lignin, regenerated cellulose and hemicelluloses before and after the IL pretreatment, were characterized by a variety of analytical techniques such as High-Performance Liquid Chromatography (HPLC) (carbohydrates), Fourier Transform Infra-Red Attenuated Total Reflection (FTIR-ATR) (functional groups), Pyrolysis-Gas Chromatography /Mass Spectroscopy (Py-GC/MS) (lignin fractions), Ultraviolet/Visible spectroscopy (UV/Vis) (acid soluble lignin), Thermo Gravimetric Analysis (TGA) (degradation of pulp), X-Ray Diffraction (XRD) (crystallinity) and high resolution Scanning Electron Microscopy (SEM) (morphology). Kraft pulping was the most effective method for the yield of cellulose after the [AMIM][Cl]/DMSO pretreatment. The 30% [AMIM][Cl]/DMSO pretreatment gave the highest S/G ratio indicating that minimal bleaching was required.


BioResources ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 979-986
Author(s):  
Mehmet Akgül ◽  
Mehmet Onurhan Gücüş ◽  
Birol Üner ◽  
Celil Atik

This study aimed to determine the influence of prehydrolysis of wood chips on the kraft pulping of Populus x euramericana. Optimum cooking conditions were determined by evaluating different alkali concentrations and cooking periods. Xylanase was used to hydrolyze chips before cooking. Prehydrolysis process increased the yield and viscosity of pulp. Consequently, the mechanical properties of paper changed remarkably. In contrast, the optical properties of the unbleached kraft pulp declined due to lignin content.


Tellus B ◽  
2007 ◽  
Vol 59 (5) ◽  
Author(s):  
Brynhildur Bjarnadottir ◽  
Bjarni D. Sigurdsson ◽  
Anders Lindroth

Author(s):  
М.А. Чубинский ◽  
К.В. Чаузов

Несмотря на огромные запасы, древесина лиственницы до сего времени в незначительных объемах используется в строительной индустрии, других отраслях экономики, что связано как с технологическими сложностями ее переработки, так и недостаточной изученностью ее свойств. Одним из уникальных свойств древесины лиственницы сибирской (Larix sibirica) является ее повышенная естественная биостойкость, наряду с максимально высокой среди отечественных хвойных пород прочностью. Стойкость древесины лиственницы (Larix sibirica) к воздействию дереворазрушающих грибов Coniofora puteana значительно превышает стойкость сосны. В среднем потеря массы ядровой древесины лиственницы сибирской под воздействием дереворазрушающего гриба Coniophora puteana составляет 14,84%, снижаясь с увеличением возраста дерева, а контрольные образцы из ядровой древесины сосны в возрасте 90 лет имели потерю массы 57,8%. Возраст дерева является одним из наиболее значимых факторов, влияющих на степень биостойкости древесины. По мере его увеличения значительно повышается устойчивость деструктивному воздействию дереворазрушающих грибов Coniophora puteana. Положение образцов также влияет на степень биостойкости древесины, однако эта зависимость слабо выражена по сравнению с влиянием возраста и плотности древесины. Исследования кинетики разложения древесины лиственницы сибирской и роли экстрактивных веществ в развитии дереворазрушающих грибов позволяют утверждать наличие связи биостойкости и содержания в древесине экстрактивных веществ. Для изготовления клееного бруса из древесины лиственницы предложена клеевая композиция, включающая карбамидомеламиноформальдегидный клей и карбамидоформальдегидную смолу, модифицированную шунгитами. Ее применение позволяет получать клеевые соединения, не уступающие по прочности при скалывании массивной древесине, как по сухому образцу, так и после его вымачивания. Таким образом, клееный брус из древесины лиственницы сибирской характеризуется высокими показателями биостойкости, прочности и водостойкости. Despite vast reserves, larch wood so far in small volumes used in the construction industry and other sectors of the economy, which is connected as the technological difficulties of its treatment, as well as insufficient knowledge of its properties. One of the unique properties of the wood of Siberian larch (Larix sibirica) is its increased natural biological stability (decay resistant), along with the highest among the domestic softwood strength. Resistance Larch (Larix sibirica) to the effects of wood-destroying fungi Coniofora puteana is much higher than pine. The average weight loss of Siberian larch heartwood exposed wood-destroying fungi Coniophora puteana is 14.84%, decreasing with increasing age of the tree, and control samples of heartwood pine at age 90 had a weight loss of 57.8%. Age of a tree is one of the most significant factors affecting the degree of biological stability of wood. With the increase it significantly increases the stability of the destructive effects of wood-destroying fungi and Coniophora puteana. The position of the sample in tree also affects the degree of biological stability of wood, but this dependence is poorly developed in comparison with the influence of age and wood density. Studies of the kinetics of decomposition of Siberian larch wood and the role of extractives in the development of wood-destroying fungi suggest a link, and the decay resistant of the content in the wood extractives. For the manufacture of larch glued laminated beam proposed adhesive composition comprising urea and melamine-formaldehyde glue and urea-formaldehyde resins, modified shungites. Its use allows to obtain the bonds are not inferior in strength at shearing solid wood as dry sample, and after soaking. Thus, glued laminated beam from Siberian larch wood is characterized by high decay resistant, strength and water resistance.


2020 ◽  
Vol 66 (1) ◽  
Author(s):  
Bayasaa Tumenjargal ◽  
Futoshi Ishiguri ◽  
Yusuke Takahashi ◽  
Ikumi Nezu ◽  
Bayartsetseg Baasan ◽  
...  

2010 ◽  
Vol 83 (3) ◽  
pp. 497-500 ◽  
Author(s):  
R. Kh. Mudarisova ◽  
L. A. Badykova ◽  
E. I. Koptyaeva ◽  
A. A. Fatykhov ◽  
Yu. B. Monakov

TAPPI Journal ◽  
2020 ◽  
Vol 19 (3) ◽  
pp. 139-148
Author(s):  
MARYAM SADEGH MOUSAVI ◽  
NIKOLAI DEMARTINI

The accumulation of nonprocess elements in the recovery cycle is a common problem for kraft pulp mills trying to reduce their water closure or to utilize biofuels in their lime kiln. Nonprocess elements such as magne-sium (Mg), manganese (Mn), silicon (Si), aluminum (Al), and phosphorus (P) enter the recovery cycle via wood, make-up chemicals, lime rock, biofuels, and process water. The main purge point for these elements is green liquor dregs and lime mud. If not purged, these elements can cause operational problems for the mill. Phosphorus reacts with calcium oxide (CaO) in the lime during slaking; as a result, part of the lime is unavailable for slaking reactions. The first part of this project, through laboratory work, identified rhenanite (NaCa(PO4)) as the form of P in the lime cycle and showed the negative effect of P on the availability of the lime. The second part of this project involved field studies and performing a mass balance for P at a Canadian kraft pulp mill.


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