Synthesis and Characterization of Urethane Side Chain Substituted Diketopyrrolopyrrole

2021 ◽  
Vol 13 (2) ◽  
pp. 635-642
Author(s):  
S. Dharmapurikar ◽  
J. Aher ◽  
A. Puyad ◽  
G. K. Kakade ◽  
V. G. Kalalawe ◽  
...  
Keyword(s):  
Optical Properties ◽  
Hydrogen Bonding ◽  
Alkyl Chain ◽  
Side Chain ◽  
Synthesis And Characterization ◽  
Side Chains ◽  
Easy Method ◽  
Secondary Interaction ◽  
Sensing Applications

The synthesis of Diketopyrrolopyrrole (DPP) having secondary interaction in the side chain explores its possibility to use in electronic and sensing applications. Herein we report easy method to engineer side chains of DPP. The hydrogen bonding is introduced on the side chain by substitution of urethane side chains on Diketopyrrolopyrrole (DPPurethane).The urethane side chain comprises a branched alkyl chain with good yields and purities. The DPPurethane characterized by NMR and IR, optical properties along with energy minimized structure were studied.  

Synthesis and characterization of chiral PEDOT enantiomers bearing chiral moieties in side chains: chiral recognition and its mechanism using electrochemical sensing technology

RSC Advances ◽  
2016 ◽  
Vol 6 (14) ◽  
pp. 11536-11545 ◽  
Author(s):  
Liqi Dong ◽  
Long Zhang ◽  
Xuemin Duan ◽  
Daize Mo ◽  
Jingkun Xu ◽  
...  
Keyword(s):  
Chiral Recognition ◽  
Electrochemical Sensing ◽  
Side Chain ◽  
Synthesis And Characterization ◽  
Side Chains ◽  
Sensing Technology

This manuscript reports a couple of novel polymers of side-chain functionalized PEDOT. The new polymers can be employed to successfully recognize 3,4-dihydroxyphenylalanine enantiomers and we also discuss the mechanism of chiral recognition.

Controlled RAFT synthesis of side-chain oleic acid containing polymers and their post-polymerization functionalization

RSC Advances ◽  
2014 ◽  
Vol 4 (99) ◽  
pp. 56415-56423 ◽  
Author(s):  
Binoy Maiti ◽  
Sonu Kumar ◽  
Priyadarsi De
Keyword(s):  
Oleic Acid ◽  
Renewable Resource ◽  
Side Chain ◽  
Synthesis And Characterization ◽  
Cross Linking ◽  
Side Chains ◽  
Double Bonds ◽  
Ene Reaction

We report the synthesis and characterization of well-defined polymers from oleic acid as the bio-renewable resource. Double bonds in oleate side-chains in the polymer are further modified by thiol-ene reaction, epoxidation, and cross-linking.

Synthesis and characterization of block copolythiophene with hexyl and triethylene glycol side chains

Polymer ◽  
2011 ◽  
Vol 52 (17) ◽  
pp. 3687-3695 ◽  
Author(s):  
Tomoya Higashihara ◽  
Kaoru Ohshimizu ◽  
Yecheol Ryo ◽  
Takuya Sakurai ◽  
Ayumi Takahashi ◽  
...  
Keyword(s):  
Triethylene Glycol ◽  
Synthesis And Characterization ◽  
Side Chains

Synthesis and Characterization of a Regioregular Side‐Chain Semifluorinated Polythiophene

2019 ◽  
Vol 216 (12) ◽  
pp. 1800747 ◽  
Author(s):  
Christoph Horn ◽  
Doris Pospiech ◽  
Johanna Zessin ◽  
Sebastian Stein ◽  
Dieter Jehnichen ◽  
...  
Keyword(s):  
Side Chain ◽  
Synthesis And Characterization

scholarly journals Synthesis, Mesomorphism and the Optical Properties of Alkyl-deuterated Nematogenic 4-[(2,6-difluorophenyl)ethynyl]biphenyls

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4653
Author(s):  
Jakub Herman ◽  
Piotr Harmata ◽  
Michał Czerwiński ◽  
Olga Strzeżysz ◽  
Marta Pytlarczyk ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Mass Spectrometry ◽  
Differential Scanning Calorimetry ◽  
Optical Properties ◽  
Liquid Crystalline ◽  
Near Infrared ◽  
Synthesis And Characterization ◽  
Molecular Approach ◽  
Scanning Calorimetry

The synthesis and characterization of new deuterated liquid crystal (LC) compounds based on phenyl tolane core is described in this paper. The work presents an alternative molecular approach to the conventional LC design. Correlations between molecular structure and mesomorphic and optical properties for compounds which are alkyl-hydrogen terminated and alkyl-deuterium, have been drawn. The compounds are characterized by mass spectrometry (electron ionization) analysis and infrared spectroscopy. They show enantiotropic nematic behavior in a broad temperature range, confirmed by a polarizing thermomicroscopy and differential scanning calorimetry. Detailed synthetic procedures are attached. Synthesized compounds show a significantly reduced absorption in the near-infrared (NIR) and medium-wavelength infrared (MWIR) radiation range, and stand as promising components of medium to highly birefringent liquid crystalline mixtures.

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