scholarly journals ANALISIS KEMAMPUAN TANAH DI DAERAH PEMUKIMAN KOTA BENGKULU DALAM MENJERAP ALKYL BENZENE SULPHONATE (ABS) DAN LINEAR ALKYLBENZENE SULPHONATE (LAS)

Alotrop ◽  
2019 ◽  
Vol 3 (1) ◽  
Author(s):  
Fikri Ananda ◽  
I Nyoman Candra ◽  
Elvinawati Elvinawati

This research aims to know the ability of land in a residential area of the city of Bengkulu in adsorbed Alkyl Benzene Sulphonate  (ABS) and Linear Alkyl Benzene Sulphonate (LAS). Soil samples were taken at five-point i.e. the backyard of Balai Buntar,   Fatmawati  Airport, Beringin Raya , Pematang Gubernur and Simpang Nakau  with a drill ground at a depth of 20 cm and cleaned from garbage impurity. Then the soil characterized include moisture content, pH, texture and the organic content  and ABS and ALS adsorbsition measured using UV-vis spectrophotometers att 222-223 nm wavelengths. In this research tested the influence of pH, pulp and optimum contact time contacts from soil sample at in ABS and ALS adsorbsition The adsorbtion pattern is known as the Freundlich and Langmuir parameters. Based on research, generally, it can be concluded that the land in the residential area of Bengkulu city has characteristic average water content – average 23%, pH average – average 5.35 and it's Turn dusty clay. The optimum condition from soil in adsorbs from Alkyl Benzene Sulphonate (ABS) occurs at pH 3, a mass of 1 g and 2 hours of contact time with the adsorption capacity of 0.874 mg/g, while for Linear Alkyl Benzene Sulphonate (LAS)  adsorption  the optimum soil conditions occur at pH 2, mass 0.5 g and 1-hour contact time with the adsorption capacity of 1.607 mg/g.  The pattern of soil adsorption against ABS tends to follow the Langmuir equation whereas against LAS tend to follow the Freundlich equation. Adsorpstion of soil samples in Bengkulu City against ABS belongs to low and adsorpstion against LAS belongs to very low

2010 ◽  
Vol 2010 ◽  
pp. 1-9 ◽  
Author(s):  
A. K. Maayta ◽  
Mohammad M. Fares ◽  
Ali F. Al-Shawabkeh

Implementation of linear alkyl benzene sulphonate, LAS, as corrosion inhibitor on the surface of iron metal in acidic media and in the absence and presence of magnetic field has been investigated. Adsorption of inhibitor molecules on iron surface showed Langmuir adsorption isotherms fit in acidic media. In the absence of magnetic field, apparent activation energy values (Ea) in 2.0 M HCl solutions provide evidence of the inhibitory effect of LAS on iron; similarly, the enthalpy of activation values (ΔH≠) was in accordance with activation energy values. Apparent entropy of activation shows that at larger inhibitor concentration, solvent entropy decrease in 1.0 M HCl and solvent entropy increase in 2.0 M HCl were obtained. Furthermore, spontaneity, through equilibrium constant (Kads.) values and free energy value (ΔGads.) of the adsorption process, shows a drastic decrease upon temperature increase. In the presence of magnetic field, lower rates of corrosion, larger activation energies, solvent entropy increase, larger equilibrium constant (Kads.) value, and lower free energy value (ΔGads.) have been investigated.


1990 ◽  
Vol 50 (3-4) ◽  
pp. 233-239 ◽  
Author(s):  
Virendra Misra ◽  
Vinod Kumar ◽  
Shri Dhar Pandey ◽  
P. N. Viswanathan

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