Spreading characteristics of molecularly thin lubricant on a grooved surface have been studied numerically by Monte Carlo simulations and compared with measurements obtained by perfluoropolyether (PFPE) thin film spreading on a solid surface with minute grooves. In the simulations, by incorporating the interactions between molecules and the side surfaces of a groove, the Monte Carlo method based on the Ising model was extended to the case of a surface with grooves and applied to simulate the spreading of non-polar lubricant inside a groove. Compared with the spreading on a smooth surface, lubricant spreads rapidly inside a groove, indicating an acceleration of the spreading along the groove. In the experiments, lubricant spreading on a surface with groove-shaped textures was measured by making use of the phenomenon in which diffracted light decreases or vanishes in the lubricant-covered region. Based on the results showing lubricant spreading predominantly along the groove, the accelerating effect obtained in the simulations is well confirmed by the measurements.
An Analysis of the Domain Structure in Soft-Magnetic Thin Film, Using the Monte-Carlo Method.
