scholarly journals Chemical Solution Deposition of La-Substituted BiFe0.5Sc0.5O3 Perovskite Thin Films on Different Substrates

Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 307
Author(s):  
Diana Griesiute ◽  
Dovydas Karoblis ◽  
Lina Mikoliunaite ◽  
Aleksej Zarkov ◽  
Andrei N. Salak ◽  
...  

In the present work, polycrystalline Bi0.67La0.33Fe0.5Sc0.5O3 thin films were synthesized using a simple and cost-effective chemical solution deposition process employing the spin coating technique. In order to check the feasibility of the fabrication of thin films on various types of substrates, the films were deposited on Pt-coated silicon, silicon, sapphire, corundum, fused silica and glass. Based on the results of thermogravimetric analysis of precursor and thermal stability study, it was determined that the optimal annealing temperature for the formation of perovskite structure is 600 °C. It was observed that the relative intensity of the pseudocubic peaks (001)p and (011)p in the XRD patterns is influenced by the nature of substrates, suggesting that the formed crystallites have some preferred orientation. Roughness of the films was determined to be dependent on the nature of the substrate.

2013 ◽  
Vol 121 (1416) ◽  
pp. 638-643 ◽  
Author(s):  
Takanori KIGUCHI ◽  
Tomohito TSUKAMOTO ◽  
Cangyu FAN ◽  
Masahiko NISHIJIMA ◽  
Toyohiko J. KONNO

1999 ◽  
Vol 14 (4) ◽  
pp. 1495-1502 ◽  
Author(s):  
Wataru Sakamoto ◽  
Toshinobu Yogo ◽  
Takae Kuroyanagi ◽  
Shin-ichi Hirano

Crack-free and transparent Sr2KNb5O15 (SKN) thin films have been synthesized by the chemical solution deposition method. A homogeneous and stable precursor solution was prepared via controlling the reaction of metal alkoxides. SKN precursor was found to be the complex alkoxide between Sr[Nb(OEt)6]2 and KNb(OEt)6 with high structural symmetry. SKN powders and thin films on fused silica substrates directly crystallized to the polycrystalline tetragonal tungsten bronze phase at 600 °C. Highly oriented SKN thin films with the tetragonal tungsten bronze phase were fabricated on MgO(100) and Pt(100)/MgO(100) substrates. Two crystal lattice planes of SKN were intergrown at an orientation of 18.5° on MgO(100). The dielectric constant of SKN thin films on Pt(100)/MgO(100) was about 590 at 20 °C at 1 kHz.


2004 ◽  
Vol 64 (1) ◽  
pp. 227-236 ◽  
Author(s):  
KIYOTAKA TANAKA ◽  
KAZUYUKI SUZUKI ◽  
DESHENG FU ◽  
KAORI NISHIZAWA ◽  
TAKESHI MIKI ◽  
...  

2006 ◽  
Vol 11-12 ◽  
pp. 101-104 ◽  
Author(s):  
Yi Ping Guo ◽  
Kazuyuki Suzuki ◽  
Kaori Nishizawa ◽  
Takeshi Miki ◽  
Kazumi Kato

A chemical solution deposition process for preparation of highly (100)-oriented Ba(Zr0.05Ti0.95)O3 films was developed. The orientation degree of Ba(Zr0.05Ti0.95)O3 thin films prepared by this process can reach up to 99.1%. The electrical properties of the (100)-oriented films prepared by this process have been studied. The Ba(Zr0.05Ti0.95)O3 films with a thickness of about 270 nm show a dielectric constant of ∼740 and a loss tangent of ∼3%. The remanent polarization (2Pr) and coercive field (2Ec) are 3.2 μC/cm2 and 34 kV/cm, respectively.


2002 ◽  
Vol 756 ◽  
Author(s):  
Hirofumi Kakuta ◽  
Takashi Iijima ◽  
Hitoshi Takamura

ABSTRACTOxygen-ionic and electronic conductive thin films with the composition of La0.6Sr0.4Co0.5Fe0.5O3-α (LSCF) were prepared on a porous alumina substrate by a chemical solution deposition (CSD) process and their oxygen permeating flux densities were measured. Thickness of the LSCF layer on the substrate was about 0.4 μm. Oxygen flux density of the LSCF sample was found to be 0.6 μmol·cm-2·s-1, however, time-dependent degradation of oxygen flux was observed. The CeO2 barrier layer between the LSCF layer and the substrate was effective in order to improve time-dependent degradation of oxygen flux.


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