scholarly journals Optimizing Spacer Length for Positioning Functional Groups in Bio-Waste

Environments ◽  
2018 ◽  
Vol 5 (9) ◽  
pp. 100 ◽  
Author(s):  
Revathi Iyengar ◽  
Maria Faure-Betancourt ◽  
Saleh Talukdar ◽  
Jinting Ye ◽  
Abel Navarro

The goal of this study was to determine the optimal chain length needed for tethering functional groups on bio-wastes. The purpose of modifying the surface of bio-waste is to improve their affinity for phenols. To this end, four different aminated green tea leaves, with the amine group located at the end of 6, 8, 10, and 12 carbons were synthesized. Green approaches to functionalization lead to fewer reactive sites. Optimizing spacer length is one way to ameliorate this. The aminated tea leaves were prepared by a tosylation reaction followed by displacement with a diamine used in excess. The tea leaves with the amine at the end of six carbons proved to have the best ability to remove 2-chlorophenol (2-CP) from its aqueous solution. It was at least 3–4 times better than native spent tea leaves. The mechanism by which the phenol was removed proved to be primarily an acid–base reaction followed by H-bonding and dipole–dipole interactions. Because of the acid–base interactions, the relatively low-boiling 2-CP did not volatilize off the aminated tea leaves enabling recycling. On the other hand, with activated charcoal, the adsorbed 2-CP volatilized almost completely under ambient conditions.

2018 ◽  
Vol 1 (1) ◽  
pp. 114-124 ◽  
Author(s):  
Jesie Silva ◽  
Lizebel Morante ◽  
Tesfamichael Demeke ◽  
Jacqueline Baah-Twum ◽  
Abel Navarro

The prevalence of antibiotics in water creates microbial resistance and has a negative impact on the ecosystem. Biomaterials such as spent tea leaves are rich in functional groups and are suitable for chemical modification for diverse applications. This research proposes the use of spent tea leaves of chamomile (CM), green tea (GT), and peppermint (PM) as structural scaffolds for the incorporation of carboxyl, sulfonyl, and thiol groups to improve the adsorption of Penicillin G (Pe). Adsorbents characterization reported a higher number of acidic functional groups, mainly in thiolated products. Scanning electron microscopy (SEM) analysis showed changes on the surfaces of the adsorbents due to reaction conditions, with a stronger effect on thiolated and sulfonated adsorbents. Elemental analysis by Energy dispersive X-ray spectrophotometry (EDS) corroborated the chemical modification by the presence of sulfur atoms and the increase in oxygen/carbon ratios. Batch experiments at different pH shows a strong pH-dependence with a high adsorption at pH 8 for all the adsorbents. The adsorption follows the trend CMs > GTs > PMs. Thiolation and sulfonation reported higher adsorptions, which is most likely due to the sulfur bridge formation, reaching adsorption percentages of 25%. These results create a new mindset in the use of spent tea leaves and their chemical modifications for the bioremediation of antibiotics.


2007 ◽  
Vol 12 (1) ◽  
pp. 35-39 ◽  
Author(s):  
Dae-Jin Kim ◽  
Dae-Soo Chung ◽  
Sung-Chul C. Bai ◽  
Hyeong-Soo Kim ◽  
Yu-Bang Lee

Author(s):  
Ali Forouzanfar ◽  
Hamideh Sadat Mohammadipour ◽  
Fatemeh Forouzanfar

: Periodontal diseases are highly prevalent and can affect high percentage of the world population. Oxidative stress and inflammation plays an important role in the pathogenesis of periodontal diseases. Nowadays, more attention has been focused on the herbal remedies in the field of drug discovery. Green tea is an important source of polyphenol antioxidants, it has long been used as a beverage worldwide. The most interesting polyphenol components of green tea leaves that are related with health benefits are the catechins. Taken together this review suggested that green tea with its wide spectrum of activities could be a healthy alternative for controlling the damaging reactions seen in periodontal diseases.


Author(s):  
Syie Luing Wong ◽  
Mohamed Hizam Mohamed Noor ◽  
Norzita Ngadi ◽  
Ibrahim Mohammed Inuwa ◽  
Ramli Mat ◽  
...  

2021 ◽  
Vol 1795 (1) ◽  
pp. 012070
Author(s):  
Hamsa A. Abdulmageed ◽  
Abdulhadi. K. Judran ◽  
Farah T. M. Noori

Cellulose ◽  
2021 ◽  
Author(s):  
Nina Čuk ◽  
Martin Šala ◽  
Marija Gorjanc

Abstract The development of cellulose-based textiles that are functionalised with silver nanoparticles (AgNP), synthesised according to a green approach, and offer protection against ultraviolet (UV) radiation and pathogenic bacteria is very important today. In the present work we demonstrate the environmentally friendly approach to obtain such textile material by AgNP synthesis directly (in-situ) on cotton fabrics, using water extracts of plant food waste (green tea leaves, avocado seed and pomegranate peel) and alien invasive plants (Japanese knotweed rhizome, goldenrod flowers and staghorn sumac fruit) as reducing agents. The extracts were analysed for their total content of phenols and flavonoids and their antioxidant activity. The synthesised AgNP on cotton were round, of different size and amount depending on the reducing agent used. The highest amount of AgNP was found for samples where Japanese knotweed rhizome extract was used as reducing agent and the lowest where extracts of goldenrod flowers and green tea leaves were used. Regardless of the reducing agent used to form AgNP, all cotton samples showed excellent protection against E. coli and S. aureus bacteria and against UV radiation with UV protection factor values above 50. The best results for UV protection even after the twelve repetitive washing cycles were found for the sample functionalized with AgNP synthesised with an extract of the Japanese knotweed rhizome. Due to the presence of AgNP on cotton, the air permeability and thermal conductivity decreased. AgNP had no effect on the change in breaking strength or elongation of fabrics. Graphic abstract


2021 ◽  
Author(s):  
Zhu-Lin Luo ◽  
Hongyu Sun ◽  
Xiao-Bo Wu ◽  
Long Cheng ◽  
Jian-Dong Ren

Green tea has been considered as a health-promoting beverage and is widely consumed worldwide. Epigallocatechin-3-gallate (EGCG), the most abundant polyphenol derived from green tea leaves with potent antioxidative and chemopreventive...


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