scholarly journals Human Health Risk Assessment through Roasted Meats Consumption

2020 ◽  
Vol 17 (18) ◽  
pp. 6737 ◽  
Author(s):  
Luana C. S. Leite ◽  
Elaine S. de P. Melo ◽  
Daniela G. Arakaki ◽  
Elisvânia F. dos Santos ◽  
Valter A. do Nascimento
Keyword(s):  
Inductively Coupled Plasma ◽  
Hazard Quotient ◽  
Microwave Digestion ◽  
Adult Population ◽  
Human Health Risk ◽  
Daily Intake ◽  
Major And Trace Elements ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry ◽  
Raw Meats

Data on the content of metals and metalloids in roasted meats with different types of wood and charcoal are still scarce in the literature. The concentrations of metals (Al, Cr, Cd, Cu, Fe, Mg, Mn, Mo, Ni, V, and Zn) and metalloid (As) were determined by inductively coupled plasma mass spectrometry (ICP-OES) after microwave digestion, and the estimated daily intake (EDI) for adults was assessed to determine the hazard quotient (HQ). The concentrations of Al, Cr, Cu, and Fe in raw meats were below the data obtained in other countries. The concentration of As (0.17 ± 0.42–0.23 ± 0.10 mg/kg), Mg (206.77 ± 3.99–291.95 ± 8.87 mg/kg), V (0.42 ± 0.14–6.66 ± 0.80 mg/kg), and Zn (6.66 ± 0.80–48.13 ± 0.56 mg/kg) in raw meats exceeded the values in the literature. The concentrations of Mg, As, Cr, Fe, V, and Zn are high when the meat is roasted using wood. All levels of Al, As, Cr, Cu, Fe, Mg, Mn, Mo, V, and Zn in raw meats are lower than those of meat roasted with coal and wood. The content of As in meat roasted with Chromed Copper Arsenate (CCA) wood (15.10 ± 0.27–26.25 ± 1.47 mg/kg) is higher than meat roasted with charcoal (0.46 ± 0.09–1.16 ± 0.50 mg/kg). EDI and HQ values revealed a minimal exposure of the adult population to those metals through roasted-meats consumption. However, EDI values of As in some roasted meats are above standard limits. Roast meats with wood showed higher levels of major and trace elements than meats roasted with coal. High exposures, in the long-term, may cause damage to health.

Simultaneous determination of ultra-trace Pt, Pd, Rh and Ir in geochemical samples by inductively coupled plasma mass spectrometry following tin fire assay preconcentration and microwave digestion

2020 ◽  
Vol 16 ◽  
Author(s):  
Wenshan Ni ◽  
Xiangju Mao ◽  
Hongli Zhang ◽  
Lu Liu ◽  
Xiaorui Guo ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Nickel Oxide ◽  
Inductively Coupled Plasma ◽  
Lead Oxide ◽  
Microwave Digestion ◽  
Fire Assay ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry ◽  
Ultra Trace

Background: Platinum (Pt), palladium (Pd), rhodium (Rh) and iridium (Ir) are platinum group elements (PGEs) and also important elements of geochemistry and environmental chemistry with the similar physic-chemical properties, which have been widely used in industry and laboratory. However, due to the low abundance and inhomogeneous distribution in natural ore as well as the nugget effect, the accurate determination of PGEs has been a challenge to analytical chemistry. Methods: In this work, a novel fire assay method was reported for the determination of ultra-trace Pt, Pd, Rh and Ir in geochemical samples. Tin powder (Sn) instead of stannic oxide (SnO2) was used as fire assay collector to reduce the melting temperature from 1250 oC to 1050 oC, the escape of molten material caused by high temperature was successfully avoided. Tin bead was compressed into thin slice and dissolved by HCl. For the target Pt, Pd, Rh and Ir, HCl insoluble substance such as PtSn4, PdSn4, RhSn4 and Ir3Sn7 were formed and separated from matrix by filtering. The metal compounds precipitate together with filter paper were microwave-assisted completely digested by aqua regia (50%, v/v), thence the sample solution were determined by inductively coupled plasma mass spectrometry (ICP-MS). Results: Compared with nickel oxide and lead oxide in nickel sulfide /lead fire assay, the reagent blank of tin powder were relatively low and could be directly employed in tin fire assay to collect Pt, Pd, Rh and Ir without purifying. Moreover, the harm of nickel oxide and lead oxide to the analyst and environment was avoided by using the non-toxic tin powder. The decomposition method of chromite and black shale were investigated as well as the amount of tin powder and flour, microwave digestion program for the determination of Pt, Pd, Rh and Ir were optimized. Besides, the influence of mass spectrum interference of co-existing elements was discussed and the standard mode and kinetic energy discrimination collision pool mode were compared. Under the optimal conditions, excellent curve fitting of Pt, Pd, Rh and Ir were obtained between 0.01～100 ng mL-1 , with the correlation coefficients exceeding 0.9996. The detection limits were from 0.003 ng g -1 to 0.057 ng g -1 . Conclusion: The developed method was applied to analyze the Chinese Certified Reference Materials and the determined values were in good agreement with the certified values.

scholarly journals Geophagic Clays from Cameroon: Provenance, Metal Contamination and Health Risk Assessment

2021 ◽  
Vol 18 (16) ◽  
pp. 8315
Author(s):  
Georges-Ivo Ekosse ◽  
George Elambo Nkeng ◽  
Nenita Bukalo ◽  
Olaonipekun Oyebanjo
Keyword(s):  
Health Risk ◽  
Inductively Coupled Plasma ◽  
Risk Index ◽  
Human Health Risk ◽  
Carcinogenic Risk ◽  
Anthropogenic Sources ◽  
Contamination Assessment ◽  
X Ray ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry

This study assessed the mineralogical and geochemical characteristics of geophagic clays sold in some markets in Cameroon to ascertain their provenance, contamination status and human health risk. To achieve this, 40 samples from 13 markets in Cameroon were purchased and analysed using X-ray diffractometry, X-ray fluorescence and laser ablation inductively coupled plasma mass spectrometry for their mineralogy and geochemistry, respectively. The geophagic clays were dominantly made up of kaolinite and quartz. Their chemistry was dominated by SiO2, Al2O3 and LOI with means of 48.76 wt%, 32.12 wt% and 13.93 wt%, respectively. The major, trace and rare earth elements data showed that these geophagic clays were predominantly derived from felsic rocks. The contamination assessment indicated no enrichment of metals from anthropogenic sources, except for Zn in samples from Acacia, Madagascar and Mfoudi markets. The index of geo-accumulation indicated no contamination to moderate contamination of the clays. The non-carcinogenic index values for Fe, Co, Cr, Cu, Ni, Pb and Zn were generally less than 1, suggesting no non-carcinogenic risk exposure to children and adults consuming the geophagic clays from these metals. The carcinogenic risk index (TCR) for Ni and Cr were above 10−6, which implies that children and adults are vulnerable to minimal carcinogenic health risk. The TCR values from Ni posed the highest risk, especially to children consuming clays from some markets.

Heavy metal and essential elements in beers from turkey market: A risk assessment study

2021 ◽  
pp. 096032712199321
Author(s):  
M Charehsaz ◽  
S Helvacıoğlu ◽  
S Çetinkaya ◽  
R Demir ◽  
O Erdem ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inductively Coupled Plasma ◽  
Hazard Quotient ◽  
Daily Intake ◽  
Hazard Index ◽  
Carcinogenic Risk ◽  
Essential Elements ◽  
Inductively Coupled ◽  
Multiple Heavy Metals

In this study, the level of arsenic (As), lead (Pb) and cadmium (Cd) and also essential elements in beer samples consumed in Turkey were investigated using the inductively coupled plasma mass spectrometry (ICP-MS) method. The heavy metal-induced non-carcinogenic and carcinogenic risks were calculated. For essential elements, the calculated estimated daily intake of iron (Fe), copper (Cu), selenium (Se) and cobalt (Co) from beer consumption were compared with their toxicity reference values. Tukey post-hoc test showed that As was found at a significantly higher level when compared to Pb. Also, a significant correlation was found between As level and alcohol by volume percent. All samples had a hazard quotient and hazard index <1, indicating no non-carcinogenic risk from exposure to single or multiple heavy metals. Some samples exceeded the threshold limit of acceptable cancer risk for As in the high beer consumer group. This assessment showed that in addition to health implications based on the alcohol content of beer, there might be a carcinogenic risk associated with the heavy metals content of these beverages.

scholarly journals Elemental analysis of coffee: a comparison of ICP-MS and AAS methods 

2014 ◽  
Vol 32 (No. 4) ◽  
pp. 354-359 ◽  
Author(s):  
M. Jarošová ◽  
D. Milde ◽  
M. Kuba
Keyword(s):  
Inductively Coupled Plasma ◽  
Microwave Digestion ◽  
Absorption Spectrometry ◽  
Mineral Nutrients ◽  
Multivariate Statistical Methods ◽  
Multivariate Statistical ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Microwave Digestion System

We determined the mineral nutrients and toxic elements (Ca, Cu, Fe, Mg, Zn, Cd, Cr, Mn, Ni, and Pb) in five types of coffee by atomic absorption spectrometry and inductively coupled plasma mass spectrometry. The decomposition of the samples took place in a microwave digestion system with HNO<sub>3</sub> and H<sub>2</sub>O<sub>2</sub> reagents. Partial validation of the method was performed by using the certified reference material (NCS ZC 73014). Univariate and multivariate statistical methods were used to compare both the coffee samples and the techniques used. No significant differences were found between two used methods. Significant differences occurred between the coffee samples but only the application of multivariate statistics helps to distinguish among samples from different locations.

scholarly journals Evaluation of Selected Essential Elements in Khalas Dates from Date Palm Determined by Inductively Coupled Plasma-Mass Spectrometry

2019 ◽  
Vol 2019 ◽  
pp. 1-5
Author(s):  
Eid I. Brima
Keyword(s):  
Mass Spectrometry ◽  
Saudi Arabia ◽  
Inductively Coupled Plasma ◽  
Daily Intake ◽  
Essential Elements ◽  
Limited Information ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Wet Weight

In terms of nutrition, dates are an important commodity because they are a source of carbohydrates and minerals. Saudi Arabia is the second largest producer of dates worldwide. Khalas is the tenth most popular date type in the Kingdom of Saudi Arabia (KSA), but only limited information related to the levels of essential nutrients in Khalas dates is available. The concentrations of Mn, Cu, Zn, and Se were determined using inductively coupled plasma-mass spectrometry (ICP-MS). The average concentrations in wet weight were as follows (mg/kg): Mn (2.90 ± 0.54), Cu (1.78 ± 0.64), Zn (1.72 ± 0.42), and Se (0.10 ± 0.06). The calculated intakes (μg/kg bw day) per 100 g dates for each element were as follows: Mn (4.14), Cu (2.54), Zn (2.46), and Se (0.14), which represent 0.14%, 0.51%, 0.25%, and 0.2%, respectively, of the provisional maximum tolerable daily intake (PMTDI) recommended by the EFSA/WHO. It was found that levels of the analysed essential elements in up to 100 g of Khalas dates do not exceed the level set by the EFSA/WHO.

Comments on Technical Progress in Pretreatment and Analysis Method of Inorganic Elements of Electroplating Sludge

2014 ◽  
Vol 1010-1012 ◽  
pp. 413-416
Author(s):  
Xiao Jing Mao ◽  
Ye Hong Shi ◽  
Hua Chang Li
Keyword(s):  
Technical Progress ◽  
Inductively Coupled Plasma ◽  
Microwave Digestion ◽  
Absorption Spectrometry ◽  
Analysis Method ◽  
Inorganic Elements ◽  
Exposure System ◽  
Inductively Coupled ◽  
Electroplating Sludge ◽  
Plasma Mass Spectrometry

The latest technical progress in pretreatment and analysis method of inorganic elements of electroplating sludge was briefly reviewed. Some pretreatment methods were summarized, including exposure system digestion, high-pressure tank digestion, microwave digestion and dry ash digestion as well as some analysis methods, such as spectrophotometry, atomic absorption spectrometry, inductively coupled plasma spectrometry and inductively coupled plasma mass spectrometry. Finally, the trend for future technical development in inorganic elements determination of electroplating sludge was prospected.

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