scholarly journals Concentration and Spatial Distribution of Potentially Toxic Elements in Surface Soil of a Peak-Cluster Depression, Babao Town, Yunnan Province, China

Author(s):  
Hongyu Tian ◽  
Cheng Zhang ◽  
Shihua Qi ◽  
Xiangsheng Kong ◽  
Xiangfei Yue

Potentially toxic elements (PTEs) in Chinese agricultural soils, including those in some heritage protection zones, are serious and threaten food safety. Many scientists think that these PTEs may come from parent rock. Hence, at a karst rice-growing agricultural heritage area, Babao town, Guangnan County, Yunnan Province, China, the concentrations of eight PTEs (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) were determined in 148 surface soil, 25 rock, and 52 rice grain samples. A principal component analysis (PCA) and hierarchical cluster analysis were used to divide the surface soil into groups, and inverse distance weighting (IDW) was used to analyze the spatial distribution of PTEs. Soil pollution was assessed with the geoaccumulation index (Igeo). The results show that Cd, Hg, Zn, and Cr were polluting the soil (average Igeo > 0). The highest concentration of PTEs was distributed in the southwest of Babao town in the carbon rock area, which had the highest pH and soil total organic carbon (Corg), Mn, and TFe2O3 contents. PCA biplots of soil samples showed that the carbon rock area was associated with the most species of PTEs in the study area including Pb, Cd, Hg, As, and Zn. The clastic rock area was associated with Cu and Ni, and the lime and cement plants were associated with CaO, pH, Corg, TC, and aggravated PTE pollution around factories. In high-level PTE areas, rice was planted. Two out of 52 rice grain samples contained Cd and 4 out of 52 rice grain samples had Cr concentrations above the Chinese food safety standard pollutant limit (Cd 0.2 mg/kg; Cr 1 mg/kg). Therefore, the PTEs from parent rocks are already threatening rice safety. The government should therefore plan rice cultivation areas accordingly.

2020 ◽  
Vol 12 (20) ◽  
pp. 8538 ◽  
Author(s):  
He Huang ◽  
Yong Zhou ◽  
Yujie Liu ◽  
Ke Li ◽  
Liang Xiao ◽  
...  

In order to study the spatial distribution and anthropogenic sources of potentially toxic elements in Xiangzhou, soil samples were collected from arable land and were analyzed for five different potentially toxic elements: Cd, Hg, As, Pb, and Cr. Inverse distance weighting (IDW) was used to study the spatial distribution of potentially toxic elements in the soil, while principal component analysis (PCA) and random forest analysis (RFA) were applied to examine the anthropogenic sources. It was shown that the combination of multiple analysis tools provides an effective way of delineating multiple potentially toxic elements from anthropogenic sources. The results showed that the average contents of Cd, Hg, and Cr in soils were lower than the background values of Hubei, whereas the average concentrations of As and Pb in soils were higher than the background values of Hubei. Through PCA, it was concluded that human activities contributed more than 60% of the As, Pb, and Cr concentrations in Xiangzhou soils, which was verified by a random forest simulation methodology. Through random forest analysis, Pb, As, and Cr in the soil were found to originate from factories and enterprises, livestock farms, mining areas, and traffic; Cd in the soil was found to originate from mining and the processing of minerals, human production and construction activities, and agricultural irrigation; and Hg in the soil was found to originate from livestock manure, mining and processing of minerals, and human industrial production. The results of this study could provide support for better management of soil pollution through prevention practices such as specific industrial governance and layout optimization.


2021 ◽  
Vol 13 (11) ◽  
pp. 2184
Author(s):  
Zhiqi Yang ◽  
Jinwei Dong ◽  
Weili Kou ◽  
Yuanwei Qin ◽  
Xiangming Xiao

Plantations of Panax notoginseng (PN), traditional herbal medicine for the prevention and treatment of vascular diseases, are expanding rapidly in China, especially in the Yunnan province of China, due to its increasing demands and prices and causing dramatic environmental concerns. However, existing information on its planting area and spatial distribution are limited. Here, we mapped the PN planting area by using a new integrated pixel- and object-based (IPOB) approach, the Random Forest (RF) classifier, and the high-resolution ZiYuan-3 (ZY-3) imagery. We improved the procedures of classification in three aspects: (1) a new spectral index—Normalized Difference PN Index (NDPI)—was proposed, (2) the efficiency and scale of segmentation were optimized by using the Bi-level Scale-sets Model (BSM), and (3) feature variables were selected through an iteration analysis from 99 feature variables (spectral, textural, geometric, and geographic). Compared with the pixel- and the object-based methods, the IPOB has the highest F1 score of 0.98 and also has high robustness in terms of user and producer accuracies (97% and 99%, respectively), following by the object-based method (F1 = 0.94) and the pixel-based method (F1 = 0.93). The high accuracy was expected since the target class has very distinctive spectral and textural characteristics. Although all three approaches showed reasonably high accuracies due to the application of the NDPI and optimized procedures, the result showed the outperformance of the proposed IPOB approach. The framework established in this study expects to apply for regional or national PN surveys extensively. The information on the area and spatial distribution of PN can guide the government on policy making for the planting and exporting of traditional Chinese medicine resources.


Author(s):  
Aneta Olszewska ◽  
Anetta Hanć

Abstract Purpose Tooth enamel might provide past chronological metabolic, nutritional status and trace metal exposure during development. Thus, the trace elements distribution embedded in tooth tissues represents an archive of the environmental conditions. The choice of biomarker is estimated as critical to the measurement of metal exposure. Natal teeth are defined as teeth being present at birth. Methods LA-ICP-MS provides a quantitative assessment of spatial distribution of trace elements in a natal tooth. The objective of the current study was to compare concentrations of building and other elements in a rare but reliable and valid biomarker - natal tooth. Results It have been reported presence of potentially toxic elements: Pb, Cu, Mn, Cd, Ni distributed in prenatally and perinatally formed enamel and dentine. Conclusions Analyses of deciduous enamel can provide answers into individuals’ earliest development, including critical pre- and perinatal period.


Atmosphere ◽  
2021 ◽  
Vol 12 (10) ◽  
pp. 1307
Author(s):  
Jin-Young Choi ◽  
Hyeryeong Jeong ◽  
Kongtae Ra ◽  
Kyung-Tae Kim

Road and industrial origin particulate matters (PM) are a significant source of potentially toxic elements (PTEs), with health risks to the surrounding residents. In Korea for 60 years, although industries, roads and automobiles have increased aggressively, there are still few PTEs data in PM in road-deposited sediment (RDS) of industrial complexes (ICs). Therefore, this study aimed to investigate the PTE composition of on-road PM10 from nine major ICs and its pollution degree in Korea and evaluate its human health risks. The geo-accumulation index (Igeo) and pollution load index (PLI) elucidated that on-road PM10 were severely polluted by Sb, Zn, Ag and Pb. A combination of principal component analysis (PCA) and chemical tracers was used to define the PTEs sources. The results showed that non-exhaust emission from vehicles’ activity is the primary source of PTEs in on-road PM10, and industrial emissions are the secondary source. The riskiest pathway on carcinogenic and non-carcinogenic by on-road PM10 with PTEs was in-gestion. Traffic origin PTEs including Pb, As, Sb and Cd had a more significant impact on carcinogenic and non-carcinogenic health than those of industrial origins. These results could help mitigate public health risks arising from on-road PM10 and improve air quality in ICs.


2018 ◽  
Vol 190 ◽  
pp. 436-452 ◽  
Author(s):  
Gian Maria Beone ◽  
Franca Carini ◽  
Laura Guidotti ◽  
Riccardo Rossi ◽  
Marina Gatti ◽  
...  

Author(s):  
Long Ma ◽  
Jilili Abuduwaili ◽  
Wen Liu

A geographically weighted regression and classical linear model were applied to quantitatively reveal the factors influencing the spatial distribution of potentially toxic elements of forty-eight surface soils from Bosten Lake basin in Central Asia. At the basin scale, the spatial distribution of the majority of potentially toxic elements, including: cobalt (Co), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), thallium (Tl), vanadium (V), and zinc (Zn), had been significantly influenced by the geochemical characteristics of the soil parent material. However, the arsenic (As), cadmium (Cd), antimony (Sb), and mercury (Hg) have been influenced by the total organic matter in soils. Compared with the results of the classical linear model, the geographically weighted regression can significantly increase the level of simulation at the basin spatial scale. The fitting coefficients of the predicted values and the actual measured values significantly increased from the classical linear model (Hg: r2 = 0.31; Sb: r2 = 0.64; Cd: r2 = 0.81; and As: r2 = 0.68) to the geographically weighted regression (Hg: r2 = 0.56; Sb: r2 = 0.74; Cd: r2 = 0.89; and As: r2 = 0.85). Based on the results of the geographically weighted regression, the average values of the total organic matter for As (28.7%), Cd (39.2%), Hg (46.5%), and Sb (26.6%) were higher than those for the other potentially toxic elements: Cr (0.1%), Co (4.0%), Ni (5.3%), V (0.7%), Cu (18.0%), Pb (7.8%), Tl (14.4%), and Zn (21.4%). There were no significant non-carcinogenic risks to human health, however, the results suggested that the spatial distribution of potentially toxic elements had significant differences.


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