Aging-Resistant Behavior and Room Temperature Electron Spin Resonance of Nd3+ in Singly and Doubly Doped BaTiO3 Ceramics Associated with Preservation History
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The (Ba0.96Nd0.04)Ti0.99O3 (BN4T) and (Ba0.96Nd0.04)(Ti0.94Ce0.05)O3 (BN4TC5) ceramics were prepared via the mixed oxide route exhibited tetragonal and pseudo-cubic structures, respectively. After they were preserved over a long period of time, a broader electron spin resonance (ESR) signal at g = 2.338 and a narrow ESR signal at g = 2.151 were detected at room temperature (RT) for BN4T and BN4TC5, respectively. They most likely originated from the Nd3+ Kramers ions in BN4T and Nd3+-Ce4+ defect complexes in BN4TC5 ceramics, respectively. The origins of these two ESR signals and the aging-resistant dielectric behavior are further discussed.
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1983 ◽
Vol 105
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pp. 1504-1506
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1989 ◽
Vol 979
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pp. 99-104
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1997 ◽
Vol 14
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pp. 625-628
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1961 ◽
Vol 262
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pp. 207-218
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1994 ◽
pp. 369
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1973 ◽
Vol 28
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pp. 104-106
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