scholarly journals Magnetic Properties of Li3V2(PO4)3/Li3PO4 Composite

2021 ◽  
Vol 7 (5) ◽  
pp. 64
Author(s):  
Tatiana Gavrilova ◽  
Sergey Khantimerov ◽  
Mikhail Cherosov ◽  
Ruslan Batulin ◽  
Nickolay Lyadov ◽  
...  

Here, we present the investigation of the magnetic properties of Li3V2(PO4)3/Li3PO4 composites, which can be potentially used as a cathode material in lithium-ion batteries. Li3V2(PO4)3/Li3PO4 was synthesized by the thermal hydrolysis method and has a granular mesoporous structure. Magnetic properties of the composite were investigated using magnetometry and electron spin resonance methods. Based on magnetization measurements, the simultaneous existence of the paramagnetic phase with antiferromagnetic interactions between spins of V3+ ions and magnetically correlated regions was suggested. Most probably, magnetically correlated regions were formed due to anti-site defects and the presence of V4+ ions that was directly confirmed by electron spin resonance measurements.

1992 ◽  
Vol 06 (23n24) ◽  
pp. 3953-3958 ◽  
Author(s):  
Kazuyoshi Tanaka ◽  
Anvar A. Zakhidov ◽  
Kazunari Yoshizawa ◽  
Kenji Okahara ◽  
Tokio Yamabe ◽  
...  

Magnetic properties of C 60 and C 70 complexes with tetrakis(dimethylamino)ethylene (TDAE) have been studied based on the measurements of the Faraday-balance magnetization and the electron spin resonance (ESR). It has been found that both TDAE- C 60 and TDAE- C 70 possess about one radical spin per fullerene molecule. TDAE- C 60 has been confirmed to show ferromagnetic-type transition at Tc=16.7–17.5 K . Appearance of a new broad and intense ESR signal below Tc of TDAE- C 60 suggests that the radical spins in the magnetically ordered state rather localize on each C 60 molecule and are ferromagnetically correlated. On the other hand, TDAE- C 70 does not show ferromagnetism in all the temperature range down to 4.5K.


1960 ◽  
Vol 38 (3) ◽  
pp. 323-328 ◽  
Author(s):  
Yoshio Matsunaga

Electron spin resonance absorption was detected in mesonaphthodianthrene and mesonaphthodianthrone. The spectra of both of these compounds consist of, at least, seven lines with a separation of 4.4 oersteds and the central line has a g-value of 2.0024 ± 0.0002. The growth of the central line by admission of air was observed in the case of the hydrocarbon. Some suggestions are presented as to the nature of the unpaired electrons in these compounds. The magnitude of the molar diamagnetic susceptibility of mesonaphthodianthrene, after correction for the paramagnetic contribution from the unpaired electrons, is discussed in relation to the molecular structure.


2001 ◽  
Vol 40 (Part 2, No. 11A) ◽  
pp. L1151-L1153 ◽  
Author(s):  
Shin-ichi Kuroda ◽  
Kazuhiro Marumoto ◽  
Hideji Kihara ◽  
Hironobu Ofuchi ◽  
Masao Tabuchi ◽  
...  

2015 ◽  
Vol 44 (31) ◽  
pp. 14027-14033 ◽  
Author(s):  
Alberto Ghirri ◽  
Johan van Tol ◽  
Inigo Vitorica-Yrezabal ◽  
Grigore A. Timco ◽  
Richard E. P. Winpenny

An oxo-centered [Cr3O(O2CtBu)6(H2O)3](O2CtBu) HO2CtBu·2EtOH triangular cluster has been synthesized and its magnetic properties have been studied by means of complementary techniques.


2015 ◽  
Vol 41 (1) ◽  
pp. 777-786 ◽  
Author(s):  
Manoj Kumar ◽  
Prakash Chandra Sati ◽  
Sandeep Chhoker ◽  
Vivek Sajal

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