scholarly journals Platinum-Group Minerals in the Placer of the Kitoy River, East Sayan, Russia

Minerals ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 21
Author(s):  
Evgenia V. Airiyants ◽  
Olga N. Kiseleva ◽  
Sergey M. Zhmodik ◽  
Dmitriy K. Belyanin ◽  
Yuriy C. Ochirov
Keyword(s):  
Primary Source ◽  
Source Rocks ◽  
Southeastern Part ◽  
Reducing Conditions ◽  
Platinum Group Minerals ◽  
Magmatic Stage ◽  
Oxide Phases ◽  
Placer Deposits ◽  
Platinum Group ◽  
Eastern Sayan

The platinum-group minerals (PGM) in placer deposits provide important information on the types of their primary source rocks and ores and formation and alteration conditions. The article shows for the first time the results of a study of placer platinum mineralization found in the upper reaches of the Kitoy River (the southeastern part of the Eastern Sayan (SEPES)). Using modern methods of analysis (scanning electron microscopy), the authors studied the microtextural features of platinum-group minerals (PGM), their composition, texture, morphology and composition of microinclusions, rims, and other types of changes. The PGM are Os‑Ir‑Ru alloys with a pronounced ruthenium trend. Many of the Os‑Ir‑Ru grains have porous, fractured, or altered rims that contain secondary PGE sulfides, arsenides, sulfarsenides, Ir-Ni-Fe alloys, and rarer selenides, arsenoselenides, and tellurides of the PGE. The data obtained made it possible to identify the root sources of PGM in the placer and to make assumptions about the stages of transformation of primary igneous Os-Ir-Ru alloys from bedrock to placer. We assume that there are several stages of alteration of high-temperature Os-Ir-Ru alloys. The late magmatic stage is associated with the effect of fluid-saturated residual melt enriched with S, As. The post-magmatic hydrothermal stage (under conditions of changing reducing conditions to oxidative ones) is associated with the formation of telluro-selenides and oxide phases of PGE. The preservation of poorly rounded and unrounded PGM grains in the placer suggests a short transport from their primary source. The source of the platinum-group minerals from the Kitoy River placer is the rocks of the Southern ophiolite branch of SEPES and, in particular, the southern plate of the Ospa-Kitoy ophiolite complex, and primarily chromitites.

Platinum-group minerals from alluvial placers of the Kitoy river (south-east part of East Sayan, Russia)

2021 ◽  
Author(s):  
Olga Kiseleva ◽  
Yuriy Ochirov ◽  
Sergey Zhmodik ◽  
Brian Nharara
Keyword(s):  
Publishing House ◽  
Primary Source ◽  
Platinum Metal ◽  
Mineral Chemistry ◽  
Source Rocks ◽  
Tectonic Deformation ◽  
Platinum Group Minerals ◽  
Placer Deposits ◽  
Platinum Group ◽  
Eastern Sayan

<p>The studied area is in the southeastern region of Eastern Sayan. Several tectonically dissected ophiolite complexes were exposed along the margin of the Gargan block and tectonically thrust over this block. Placer nuggets of PGE alloys from the Kitoy river were examined using a scanning electron microscope. Platinum-group minerals (PGM's) in placer deposits provide vital information about the types of their primary source rocks and ores as well as the conditions of formation and alteration. The primary PGM's are Os-Ir-Ru alloys, (Os, Ru)S<sub>2</sub>, and (Os, Ir, Ru)AsS. (Os, Ru)S<sub>2</sub> form overgrowth around the Os-Ir-Ru alloys. The secondary, remobilized PGM's are native osmium, (Ir-Ru) alloys, garutite (Ir, Ni, Fe), zaccarinite (RhNiAs), selenides, tellurides (Os, Ir, Ru), and non-stoichiometric (Pd, Pt, Fe, Te, Bi) phases (Fig.1). Secondary PGM's (garutite and RhNiAs) form rims around Os-Ir-Ru alloys, intergrowth with them, or form polyphase aggregates. Such PGM's (identical in composition and microstructure) are also found in chromitites from Neoproterozoic ophiolite massifs of Eastern Sayan (Kiseleva et al., 2014; 2020). Platinum-metal minerals, exotic for ophiolites, are found among secondary PGM's such as selenides and tellurides (Os, Ir, Ru), (Pt, Pd)<sub>3</sub>Fe, Pd<sub>3</sub>(Te, Bi), (Au, Ag), and non-stoichiometric (Pd, Pt, Fe, Te, Bi) phases. They occur as inclusions in the Os-Ir-Ru alloys or fill cracks in crushed grains of primary PGM's. PGM's in placer deposits of the Kitoy river are similar to the mineral composition of PGE in chromitites of the Ospa-Kitoy ophiolitic massif, which contain Pt-Pd minerals and Pt impurities in Os-Ir-Ru alloys (Kiseleva et al., 2014). Selenides (Os-Ir-Ru) are rare within PGM's from ophiolite chromitites (Barkov et al., 2017; Airiyants et al., 2020) and also occur in chromitites of the Dunzhugur ophiolite massif (Kiseleva et al., 2016). Features of selenides and tellurides (Os, Ir, Ru) indicate their late formation as a result of the influence of magmatic and metamorphic fluids on primary PGE alloys. The filling of cracks in crushed (Os-Ir-Ru) alloys indicates that selenides and tellurides formed during tectonic deformation processes. The source of platinum-group minerals from the Kitoy river placer is the Ospa-Kitoy ophiolite massif, and primarily chromitites.</p><p><img src="https://contentmanager.copernicus.org/fileStorageProxy.php?f=gepj.eb9553e3c70065361211161/sdaolpUECMynit/12UGE&app=m&a=0&c=f3ccc1c7cf7d06094d2afaa34fe9d9a1&ct=x&pn=gepj.elif&d=1" alt=""></p><p>Figure 1. BSE microphotographs of PGM from from alluvial placers of the Kitoy river</p><p>Mineral chemistry was determined at the Analytical Centre for multi-elemental and isotope research SB RAS. This work supported by RFBR grants: No. 16-05-00737a,  19-05-00764а, 19-05-00464a and the Russian Ministry of Education and Science</p><p>References</p><p>Airiyants E.V., Belyanin D.K., Zhmodik S.M., Agafonov L.V., Romashkin P.A.  // Ore Geology Reviews. 2020. V. 120. P.  103453</p><p>Barkov A.Y., Nikiforov A.A., Tolstykh N.D., Shvedov G.I., Korolyuk V.N. // European J. Mineralogy. 2017. V.29(9). P.613-621.</p><p>Kiseleva O.N., Zhmodik S.M., Damdinov B.B., Agafonov L.V., Belyanin D.K. // Russian Geology and Geophysics. <strong>2014</strong>. V. 55. P. 259-272.</p><p>Kiseleva O.N., Airiyants E.V., Belyanin D.K., Zhmodik S.M., Ashchepkov I.V., Kovalev S.A. // Minerals. 2020. V. 10. N 141. P. 1-30.</p><p>Kiseleva O.N., Airiyants E.V., Zhmodik S.M., Belyanin D.K / Russian and international conference proceedings “The problems of geology and exploitation of platinum metal deposits” – St.Petersburg: Publishing house of St.Petersburg State University. 2016. 184 P.</p>

scholarly journals New mineralogical data on platinum-group minerals from the Río Santiago alluvial placer, Esmeraldas province, Ecuador

2020 ◽  
Vol 72 (3) ◽  
pp. A090720
Author(s):  
Gladys G. López-Males ◽  
Thomas Aiglsperger ◽  
Núria Pujol-Solà ◽  
Joaquín A. Proenza
Keyword(s):  
Coastal Region ◽  
Primary Source ◽  
Primary Sources ◽  
Ultramafic Rocks ◽  
Oceanic Plateau ◽  
Western Cordillera ◽  
Type Complex ◽  
Platinum Group Minerals ◽  
Placer Deposits ◽  
Platinum Group

Mineralogical studies on platinum-group minerals found in placer deposits from the Río Santiago (Ecuador) are scarce. In this investigation, one sample collected from the Río Santiago alluvial placer was studied via a multi-disciplinary approach, including optical microscopy, scanning electron microscopy, electron microprobe, and Raman spectroscopy. Whole-rock geochemistry data of the sample confirms elevated Au and platinum-group elements contents and the chondrite-normalized pattern reveals pronounced positive Ir and Pt anomalies. Free grains of platinum-group minerals were separated via hydroseparation techniques and identified as: i) Pt-Fe alloy (Pt3Fe), ii) tulameenite (Pt2FeCu) and iii) hongshiite (PtCu). The most abundant platinum-group mineral is Pt-Fe alloy (85%) that occasionally hosts cuprorhodsite (CuRh2S4) inclusions. Although the primary source remains unknown, the geochemical and mineralogical data suggests that the source of platinum-group minerals in the Río Santiago alluvial placer is a mafic-ultramafic Ural-Alaska type complex. Possible primary sources are the mafic and ultramafic rocks found in the mafic basement of the coastal region and the Western Cordillera (Piñón, San Juan and Pallatanga units), which derive from the Late Cretaceous Caribbean Colombia Oceanic Plateau (CCOP).

Techniques and methodology used in a mineralogical and osmium isotope study of platinum group minerals from alluvial deposits in Colombia, California, Oregon and Alaska

1997 ◽  
Vol 61 (406) ◽  
pp. 367-375 ◽  
Author(s):  
I. C. Lyon ◽  
H. Tamana ◽  
D. J. Vaughan ◽  
A. J. Criddle ◽  
J. M. Saxton ◽  
...  
Keyword(s):  
Trace Element ◽  
Alluvial Deposits ◽  
Ion Probe ◽  
Platinum Group Minerals ◽  
Placer Deposits ◽  
Trace Element Contents ◽  
Isotope Study ◽  
Platinum Group ◽  
Textural Evidence ◽  
Rhenium Content

AbstractPlatinum-group minerals (PGM) from placer deposits in Colombia, California, Oregon and Alaska were investigated with the electron microprobe, proton microprobe (μ-PIXE) and ion probe to analyse their major and trace element contents and 187Os/186Os isotopic ratios. Most of the grains in the samples investigated proved to be essentially homogeneous alloys of Pt-Fe and Os-Ir-Ru although a few of them contained inclusions of other PGM such as cooperite and laurite. Detailed analyses were undertaken on the Os-Ir-Ru alloy phases.The 187Os/186Os isotope ratios fell into a range from 1.005 to 1.156 and are consistent with data published on PGM from other placer deposits from these regions. The ratios, together with the trace element data (and in particular the low rhenium content) determined by ion probe and μ-PIXE, indicate that crustal osmium was not incorporated in the grains and that no significant evolution of the 187Os/186Os ratios occurred during their history. These data, along with mineralogical and textural evidence, are consistent with a mantle origin for the grains through ultramafic intrusions, although the data do not entirely rule out alternative interpretations.

The evolution of the ore-forming system in the low sulfide horizon of the Noril'sk 1 intrusion, Russia

2019 ◽  
Vol 83 (5) ◽  
pp. 673-694 ◽  
Author(s):  
Nadezhda D. Tolstykh ◽  
Liudmila M. Zhitova ◽  
Maria O. Shapovalova ◽  
Ivan F. Chayka
Keyword(s):  
Mafic Magma ◽  
Chromian Spinel ◽  
Reducing Conditions ◽  
Platinum Group Minerals ◽  
Sulfide Melt ◽  
Formation And Evolution ◽  
Fe Alloys ◽  
Platinum Group ◽  
Monoclinic Pyrrhotite ◽  
Increased Activity

AbstractWe present here new data on the low-sulfide mineralisation in the upper endocontact of the Noril'sk 1 intrusion. Twenty four mineral species of platinum-group elements and their solid solutions, as well as numerous unnamed phases, including an Sb analogue of vincentite, As and Sn analogues of mertieite-I and a Sn analogue of mertieite-II have been found. It is shown that the features of the mineral association: (1) the atypical trend of TiO2 and Fe2+ in chromian spinel; (2) the composition of the Pt–Fe alloys with a Fe/Fe + Pt range of 0.26–0.37 (logfO2 ≈ – (9–10); and (3) crystallisation of high-temperature sperrylite from silicate melt (at >800°C and logfS2 < –10.5), which is possible under fO2 of FMQ to FMQ-2 in mafic magma, are due to the reducing conditions of their formation and evolution. Droplet-like inclusions of silicate-oxide minerals in сhromian spinels and sulfides in platinum-group minerals are interpreted to be trapped droplets of co-existing sulfide melt. The captured sulfide melt has evolved in the direction of increasing the fugacity of sulfur: troilite + pentlandite (Fe>Ni) – in sperrylite (paragenesis I) to monoclinic pyrrhotite + pentlandite (Ni≈Fe) + chalcopyrite – in Pt–Fe alloys (paragenesis II). Paragenesis from the sulfide aggregates in the silicate matrix are more fractionated: pyrrhotite + pyrrhotite (Ni>Fe) + chalcopyrite (III) and pyrite + pentlandite (Ni>>Fe) + millerite (IV). Pd arsenides and antimonides crystallised later than sperrylite and isoferroplatinum, as a result of the evolution of a sulfide melt with an increased activity of the element ligands (Te, Sn, Sb and As).

Micro-PIXE analysis of platinum group minerals from placer deposits

1993 ◽  
Vol 77 (1-4) ◽  
pp. 444-449 ◽  
Author(s):  
Alan J. Criddle ◽  
Hardeep Tamana ◽  
John Spratt ◽  
Karen J. Reeson ◽  
David Vaughan ◽  
...  
Keyword(s):  
Pixe Analysis ◽  
Platinum Group Minerals ◽  
Placer Deposits ◽  
Platinum Group

PLATINUM-GROUP MINERALS FROM FIVE PLACER DEPOSITS IN BRITISH COLUMBIA, CANADA

2005 ◽  
Vol 43 (5) ◽  
pp. 1687-1710 ◽  
Author(s):  
A. Y. Barkov ◽  
M. E. Fleet ◽  
G. T. Nixon ◽  
V. M. Levson
Keyword(s):  
British Columbia ◽  
Platinum Group Minerals ◽  
Placer Deposits ◽  
Platinum Group

scholarly journals Hydrothermal remobilization platinum group elements and their secondary minerals in chromitite deposits of the Eastern Sayan ophiolites (Russia)

2019 ◽  
Vol 98 ◽  
pp. 08014
Author(s):  
Ol’ga Kiseleva ◽  
Evgeniya Airiyants ◽  
Dmytriy Belyanin ◽  
Sergey Zhmodik
Keyword(s):  
Fluid Phase ◽  
Platinum Group Elements ◽  
Base Metals ◽  
Crustal Fluid ◽  
Platinum Group Minerals ◽  
Mantle Peridotites ◽  
Mantle Fluids ◽  
Platinum Group ◽  
Hydrothermal Remobilization ◽  
Eastern Sayan

Serpentinization is an important post-magmatic process in spreading and subducted zones. This process is the cause of the remobilization and redistribution of highly mobile elements, platinum group elements (PGE) and base metals. Secondary platinum group minerals (PGMs) formed because of PGE remobilization under the action of mantle and crustal fluid on the rocks. The formation of the secondary PGMs can occur in several stages. Under the effect on the chromitites of reduced mantle fluids, native PGE alloys were formed during early serpentinization. Under dehydrating subducted slab fluid phase was caused in serpentinization mantle peridotites and have been dissolved magmatic high-temperature platinum group minerals. During the obduction of ophiolites, an inversion from reducing to oxidizing condition took place with the formation of nickel arsenides and As, Sb – bearing PGMs.

scholarly journals Placer platinum-group minerals in the Shetland ophiolite complex derived from anomalously enriched podiform chromitites

2018 ◽  
Vol 82 (3) ◽  
pp. 491-514
Author(s):  
Hazel M. Prichard ◽  
Saioa Suárez ◽  
Peter C. Fisher ◽  
Robert D. Knight ◽  
John S. Watson
Keyword(s):  
Cold Climate ◽  
Source Rocks ◽  
Ophiolite Complex ◽  
Cu Alloy ◽  
Platinum Group Minerals ◽  
Small Streams ◽  
Podiform Chromitites ◽  
Fe Alloys ◽  
Platinum Group

ABSTRACTHighly anomalous platinum-group element (PGE) concentrations in the podiform chromitites at the Cliff and Harold's Grave localities in the Shetland ophiolite complex have been well documented previously. The focus of this study is alluvial platinum-group minerals (PGM) located in small streams that drain from the PGE-rich chromitites. The placer PGM assemblage at Cliff is dominated by Pt-arsenides (64%) and Pd-antimonides (17%), with less irarsite–hollingworthite (11%) and minor Pd-sulfides, Pt–Pd–Cu and Pt–Fe alloys and laurite. Gold also occurs with the PGM. Alluvial PGM have average sizes of 20 µm × 60 µm, with sperrylite the largest grain identified at 110 µm in diameter, matching the range reported for the primary PGM in the source rocks. The placer assemblage contains more Pt-bearing and less Pd-bearing PGM compared with the rocks. The more resistant sperrylite and irarsite–hollingworthite grains which are often euhedral become more rounded further downstream whereas the less resistant Pd-antimonides which are commonly subhedral may become striated and etched. Less stable phases such as Pt- and Pd-oxides and other Ni-Cu-bearing phases located in the rocks (i.e. Ru-pentlandite, PtCu, Pd–Cu alloy) are absent in the placer assemblage. Also the scarce PGM (PdHg, Rh- and Ir-Sb) and Os in the rocks are absent. At Harold's Grave only three alluvial PGM (laurite, Ir, Os) and Au were recovered reflecting the limited release of IPGM from chromite grains in the rocks. In this cold climate with high rainfall, where erosion dominates over weathering, the PGM appear to have been derived directly from the erosion of the adjacent PGE-rich source rocks and there is little evidence of in situ growth of any newly formed PGM. Only the presence of dendritic pure Au and Pd-, Cu-bearing Au covers on the surface of primary minerals may indicate some local reprecipitation of these metals in the surficial conditions.

scholarly journals Platinum-Group Minerals of Pt-Placer Deposits Associated with the Svetloborsky Ural-Alaskan Type Massif, Middle Urals, Russia

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 77 ◽  
Author(s):  
Sergey Stepanov ◽  
Roman Palamarchuk ◽  
Aleksandr Kozlov ◽  
Dmitry Khanin ◽  
Dmitry Varlamov ◽  
...  
Keyword(s):  
Morphological Features ◽  
Middle Urals ◽  
Transport Distance ◽  
Mechanical Attrition ◽  
Platinum Group Minerals ◽  
Placer Deposits ◽  
Fe Alloys ◽  
Platinum Group ◽  
Ore Zones

The alteration of platinum group minerals (PGM) of eluval, proximal, and distal placers associated with the Ural-Alaskan type clinopyroxenite-dunite massifs were studied. The Isovsko-Turinskaya placer system is unique regarding its size, and was chosen as research object as it is PGM-bearing for more than 70 km from its lode source, the Ural-Alaskan type Svetloborsky massif, Middle Urals. Lode chromite-platinum ore zones located in the Southern part of the dunite “core” of the Svetloborsky massif are considered as the PGM lode source. For the studies, PGM concentrates were prepared from the heavy concentrates which were sampled at different distances from the lode source. Eluvial placers are situated directly above the ore zones, and the PGM transport distance does not exceed 10 m. Travyanistyi proximal placer is considered as an example of alluvial ravine placer with the PGM transport distance from 0.5 to 2.5 km. The Glubokinskoe distal placer located in the vicinity of the Is settlement are chosen as the object with the longest PGM transport distance (30–35 km from the lode source). Pt-Fe alloys, and in particular, isoferroplatinum prevail in the lode ores and placers with different PGM transport distance. In some cases, isoferroplatinum is substituted by tetraferroplatinum and tulameenite in the grain marginal parts. Os-Ir-(Ru) alloys, erlichmanite, laurite, kashinite, bowieite, and Ir-Rh thiospinels are found as inclusions in Pt-Fe minerals. As a result of the study, it was found that the greatest contribution to the formation of the placer objects is made by the erosion of chromite-platinum mineralized zones in dunites. At a distance of more than 10 km, the degree of PGM mechanical attrition becomes significant, and the morphological features, characteristic of lode platinum, are practically not preserved. One of the signs of the significant PGM transport distance in the placers is the absence of rims composed of the tetraferroplatinum group minerals around primary Pt-Fez alloys. The sie of the nuggets decreases with the increasing transport distance. The composition of isoferroplatinum from the placers and lode chromite-platinum ore zones are geochemically similar.

Sign in / Sign up

Export Citation Format

Share Document