scholarly journals The Influence of Aryl Substituents on the Supramolecular Structures and Photoluminescence of Cyclic Trinuclear Pyrazolato Copper(I) Complexes

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3101
Author(s):  
Kiyoshi Fujisawa ◽  
Mai Saotome ◽  
Yoko Ishikawa ◽  
David James Young
Keyword(s):  
Coordination Chemistry ◽  
Solid State ◽  
Nitrogen Atom ◽  
Transition Metal Ions ◽  
Photoluminescence Properties ◽  
State Structure ◽  
Linear Mode ◽  
Bridging Ligand ◽  
Trinuclear Complexes ◽  
Cuprophilic Interactions

Cyclic trinuclear complexes with group 11 metal (I) ions are fascinating and important to coordination chemistry. One of the ligands known to form these cyclic trinuclear complexes is pyrazolate, which is a bridging ligand that coordinates many transition metal ions in a Npz–M–Npz linear mode (Npz = pyrazolyl nitrogen atom). In these group 11 metal (I) ions, copper is the most abundant metal. Therefore, polynuclear Copper(I) complexes are very important in this field. The cyclic trinuclear Copper(I) complex [Cu(3,5-Ph2pz)]3 (3,5-Ph2pz– = 3,5-diphenyl-1-pyrazolate anion) was reported in 1988 as a landmark complex, but its photoluminescence properties have hitherto not been described. In this study, we report the photoluminescence and two different polymorphs of [Cu(3,5-Ph2pz)]3 and its derivative [Cu(3-Me-5-Phpz)]3 (3-Me-5-Phpz– = 3-metyl-5-phenyl-1-pyrazale anion). The substituents in [Cu(3-Me-5-Phpz)]3 cause smaller distortions in the solid-state structure and a red-shift in photoluminescence due to the presence of intermolecular cuprophilic interactions.

Bindung von Metall-Ionen an Dipeptide: Struktur von Thallium(I)-(3-benzyl-6-carboxylatomethyl-2,5-diketopiperazin) / Binding of Metal Ions by Dipeptides: Structure of Thallium(I) 3-Benzyl-6-carboxylatomethyl-2,5-diketopiperazine

1992 ◽  
Vol 47 (7) ◽  
pp. 952-956
Author(s):  
P. Mikulcik ◽  
P. Bissinger ◽  
J. Riede ◽  
H. Schmidbaur
Keyword(s):  
Solid State ◽  
Nitrogen Atom ◽  
Hydrogen Bonds ◽  
Diffraction Analysis ◽  
Carbonyl Oxygen ◽  
State Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Crystalline Product ◽  
Oxygen Atoms

Ester cleavage of aspartame (L-α-aspartyl-L-phenylalanine methylester) (1), by equimolar quantities of thallium ethoxide is accompanied by intramolecular cyclisation to give thallium 3-benzyl-6-(carboxylatomethyl)-2,5-dioxopiperazine (2). The solid state structure of the crystalline product was determined by single-crystal X-ray diffraction analysis. The cations were found to form four short and four elongated contacts to seven oxygen atoms and one nitrogen atom of a total of six neighbouring 3-benzyl-6-(carboxylatomethyl)-2,5-dioxopiperazine anions. There are inter-anionic hydrogen bonds only between the imino groups and the carbonyl oxygen atoms (O3, O4), featuring a pattern similar to that found for cytosine-guanosine contacts in DNA.

Synthesis and Coordination Chemistry of Gold(I) Acetylides. The Solid-State Structure of {[η2-(Ph3P)AuC⋮CFc]Cu(μ-Cl)}2

2001 ◽  
Vol 20 (10) ◽  
pp. 1968-1972 ◽  
Author(s):  
Heinrich Lang ◽  
Stefan Köcher ◽  
Stephan Back ◽  
Gerd Rheinwald ◽  
Gerard van Koten
Keyword(s):  
Coordination Chemistry ◽  
Solid State ◽  
State Structure ◽  
Solid State Structure

Tuning Coordination Environments Through Ligand Redox Chemistry: the Thiol - Disulfide Reaction

2010 ◽  
Vol 63 (9) ◽  
pp. 1334 ◽  
Author(s):  
Edwin C. Constable ◽  
Catherine E. Housecroft ◽  
Markus Neuburger ◽  
Jason R. Price ◽  
Jennifer A. Zampese
Keyword(s):  
Solid State ◽  
Oxidative Coupling ◽  
Sulfonic Acid ◽  
Redox Chemistry ◽  
Methyl Substituent ◽  
State Structure ◽  
Solid State Structure ◽  
Bridging Ligand

Oxidative coupling of 6-(pyridin-2-yl)pyridine-2(1H)-thione yields 1,2-bis(2,2′-bipyridin-6-yl)disulfide (4), which can act as a bis(chelate) to a single zinc(ii) centre. The effects on the solid-state structure of introducing a methyl substituent into each 6-position of 4 have been examined. Ligand 4 functions as a bridging ligand in [Cu2(μ-4)(μ-6)]4+ in which ligand 6 is 1,2-bis(2,2′:6′,2″-terpyridin-4′-yl)disulfide; [Cu2(μ-4)(μ-6)]4+ self-assembles from the components according to the preference shown by copper(ii) for a five-coordinate {Cu(bpy)(tpy)} environment. Reaction of 4 with [Cu(NCMe)4][PF6] leads to a product, tentatively formulated as {[Cu(4)][PF6]}n, which, in air, undergoes oxidation of both copper and ligand to yield [Cu(5)2] (H5 = 2,2′-bipyridine-6-sulfonic acid), the solid state structure of which is presented.

Vanadium and niobium diamidophosphine complexes and their reactivity

2003 ◽  
Vol 81 (12) ◽  
pp. 1431-1437 ◽  
Author(s):  
Michael P Shaver ◽  
Robert K Thomson ◽  
Brian O Patrick ◽  
Michael D Fryzuk
Keyword(s):  
Coordination Chemistry ◽  
Solid State ◽  
Molecular Nitrogen ◽  
Tridentate Ligand ◽  
State Structure ◽  
Butyl Lithium ◽  
Solid State Structure ◽  
X Ray ◽  
X Ray Crystallography ◽  
Unstable Complex

The tridentate ligand precursors R′P(CH2SiMe2NR′′)2 (R′R′′[NPN]: R′ = Cy, Ph; R′′ = Ph, Mes, Me) were prepared from metathesis reactions of a lithiated amine, chloro(chloromethyl)dimethylsilane, the appropriate 1° phosphine, and n-butyl lithium and were isolated as solvent adducts. Metathesis between CyPh[NPN]Li2(OEt2), 2, and VCl3(THF)3 afforded (CyPh[NPN]VCl)2, 7, whose solid-state structure was established by X-ray crystallography. Reduction attempts of the (R′R′′[NPN]VCl)2 species with KC8 incorporated molecular nitrogen but were complicated by imide formation and ligand decomposition. Metathesis of 2 with NbCl2Me3 afforded the highly unstable complex CyPh[NPN]NbMe3, 15. Attempts to hydrogenate this species were unsuccessful.Key words: vanadium, niobium, metathesis, coordination chemistry, reduction, hydrogenation.

3d-4f-3d trinuclear complexes with di-maltol-polyamine ligands. Solid state structure and solution behaviour

2018 ◽  
Vol 470 ◽  
pp. 254-262 ◽  
Author(s):  
P. Rossi ◽  
S. Ciattini ◽  
M. Formica ◽  
V. Fusi ◽  
L. Giorgi ◽  
...  
Keyword(s):  
Solid State ◽  
State Structure ◽  
Solid State Structure ◽  
Trinuclear Complexes ◽  
Solution Behaviour

Metal complexes of an amine bisphenol with a thiophene side-arm

2010 ◽  
Vol 75 (10) ◽  
pp. 1051-1060 ◽  
Author(s):  
Eero Salminen ◽  
Reijo Sillanpää ◽  
Ari Lehtonen
Keyword(s):  
Solid State ◽  
Nitrogen Atom ◽  
Dimeric Complex ◽  
State Structure ◽  
Molybdenum Complex ◽  
Reaction Conditions ◽  
One Pot ◽  
X Ray ◽  
X Ray Crystallography ◽  
Phenolic Oxygen

Dioxomolybdenum(VI) and oxotungsten(VI) complexes with a new amine bisphenol ligand (H2L) are reported. The ligand which carries a neutral nitrogen atom, two phenolic oxygen atoms and a thiophene side-arm was synthesized by a simple one-pot Mannich reaction. Further reaction with [MoO2(acac)2] yielded a monomeric molybdenum complex [MoO2(L)(MeOH)] (2a) or a dimeric complex [Mo2O2(μ-O)2(L)2] (2b), depending on the reaction conditions. The reaction with a tungsten trisglycolate [W(eg)3] led to the formation of a monomeric compound [WO(eg)(L)] (3). In these complexes, the potentially tetradentate amine bisphenolate dianion coordinates as a tridentate O,N,O donor while the sulfur side-arm donor remains intact. The solid-state structure of 2a was investigated by X-ray crystallography.

The structure of [Cu(bipy)3][Cu(bipy)(ala)(ClO4)2]ClO4 � a Compound with Two Different Coordination Modes in the same Complex

2008 ◽  
Vol 59 (11) ◽  
Author(s):  
Mircea Braban ◽  
Ionel Haiduc
Keyword(s):  
Solid State ◽  
Chelate Ring ◽  
Octahedral Complex ◽  
State Structure ◽  
Complex Species ◽  
Solid State Structure ◽  
Coordination Modes ◽  
Coordination Center ◽  
Self Assembled ◽  
Chelate Rings

The paper describes the solid state structure of a compound of composition [Cu(bipy)3][Cu(bipy)(ala) (ClO4)2]ClO4, in which both the cation and anion are octahedral complex species with copper(II) as coordination center. The cation contains three chelate rings formed by bipy; the anion contains in the quatorial plane a CuONC2 chelate ring formed by the alaninato ligand and a CuN2C2 chelate ring formed by bipy, with two monodentate perchorato ligands in axial positions completing the six-coordination. In the crystal p-p stackings lead to a supramolecular self-assembled structure.

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