scholarly journals Development of Novel High Li-Ion Conductivity Hybrid Electrolytes of Li10GeP2S12 (LGPS) and Li6.6La3Zr1.6Sb0.4O12 (LLZSO) for Advanced All-Solid-State Batteries

Oxygen ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 16-21
Author(s):  
Linsheng Wang

A lithium superionic conductor of Li10GeP2S12 that exhibits the highest lithium ionic conductivity among the sulfide electrolytes and the most promising oxide electrolytes, namely, Li6.6La3Sr0.06Zr1.6Sb0.4O12 and Li6.6La3Zr1.6Sb0.4O12, are successfully synthesized. Novel hybrid electrolytes with a weight ratio of Li6.6La3Zr1.6Sb0.4O12 to Li10GeP2S12 from 1/1 to 1/3 with the higher Li-ion conductivity than that of the pure Li10GeP2S12 electrolyte are developed for the fabrication of the advanced all-solid-state Li batteries.

2020 ◽  
Vol 56 (3) ◽  
pp. 2425-2434
Author(s):  
Bing Huang ◽  
Biyi Xu ◽  
Jingxi Zhang ◽  
Zhihong Li ◽  
Zeya Huang ◽  
...  

2015 ◽  
Vol 3 (40) ◽  
pp. 20338-20344 ◽  
Author(s):  
Lincoln J. Miara ◽  
Naoki Suzuki ◽  
William D. Richards ◽  
Yan Wang ◽  
Jae Chul Kim ◽  
...  

Li9S3N is a novel Li–metal barrier coating for all-solid-state batteries. The conductivity is greatly improved by substitution.


Nanoscale ◽  
2021 ◽  
Author(s):  
Feihu Tan ◽  
Hua An ◽  
Ning Li ◽  
Jun Du ◽  
Zhengchun Peng

As flexible all-solid-state batteries are highly safe and lightweight, they can be considered as candidates for wearable energy sources. However, their performance needs to be first improved, which can be...


Author(s):  
Diego Holanda Pereira de Souza ◽  
Kasper T. Møller ◽  
Stephen A. Moggach ◽  
Terry D Humphries ◽  
Anita D’Angelo ◽  
...  

Metal boron-hydrogen compounds are considered as promising solid electrolyte candidates for the development of all-solid-state batteries (ASSB), owing to the high ionic conductivity exhibited by closo- and nido-boranes. In this...


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 946
Author(s):  
Qianyi Yang ◽  
Fuqiang Lu ◽  
Yulin Liu ◽  
Yijie Zhang ◽  
Xiujuan Wang ◽  
...  

Solid electrolytes with high Li-ion conductivity and electrochemical stability are very important for developing high-performance all-solid-state batteries. In this work, Li2(BH4)(NH2) is nanoconfined in the mesoporous silica molecule sieve (SBA-15) using a melting–infiltration approach. This electrolyte exhibits excellent Li-ion conduction properties, achieving a Li-ion conductivity of 5.0 × 10−3 S cm−1 at 55 °C, an electrochemical stability window of 0 to 3.2 V and a Li-ion transference number of 0.97. In addition, this electrolyte can enable the stable cycling of Li|Li2(BH4)(NH2)@SBA-15|TiS2 cells, which exhibit a reversible specific capacity of 150 mAh g−1 with a Coulombic efficiency of 96% after 55 cycles.


2020 ◽  
Vol 8 (37) ◽  
pp. 19603-19611
Author(s):  
Adam R. Symington ◽  
John Purton ◽  
Joel Statham ◽  
Marco Molinari ◽  
M. Saiful Islam ◽  
...  

Solid electrolytes for all-solid-state batteries are generating considerable research interest as a means to improving their safety, stability and performance.


2019 ◽  
Vol 12 (9) ◽  
pp. 2665-2671 ◽  
Author(s):  
Xiaona Li ◽  
Jianwen Liang ◽  
Jing Luo ◽  
Mohammad Norouzi Banis ◽  
Changhong Wang ◽  
...  

Ambient-air-stable Li3InCl6 halide solid electrolyte, with high ionic conductivity of 1.49 × 10−3 S cm−1 at 25 °C, delivers essential advantages over commercial sulfide-based solid electrolyte.


2020 ◽  
Vol MA2020-02 (1) ◽  
pp. 16-16
Author(s):  
Karim Zaghib ◽  
Wen Zhu ◽  
Shirin Kaboli ◽  
Hendrix Demers ◽  
Michel Trudeau ◽  
...  

2019 ◽  
Vol 7 (26) ◽  
pp. 15924-15932 ◽  
Author(s):  
Xiangfei Yuan ◽  
Cui Sun ◽  
Jia-Ning Duan ◽  
Jingmin Fan ◽  
Ruming Yuan ◽  
...  

By combining inorganic LVC with organic PEO matrix, a polyoxometalate-based polymer electrolyte (PPE) was constructed for solid state batteries.


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