Sustainable Conversion of Biomass-Derived d-Xylose to Furfuryl Alcohol in a Deep Eutectic Solvent–Water System

2021 ◽  
Author(s):  
Qi Li ◽  
Jia-Qiang Ren ◽  
Qing Li ◽  
Jun-Hua Di ◽  
Cuiluan Ma ◽  
...  
Keyword(s):  
Furfuryl Alcohol ◽  
Deep Eutectic Solvent ◽  
Water System ◽  
Solvent Water

scholarly journals Chemoenzymatic Conversion of Biomass-Derived D-Xylose to Furfuryl Alcohol with Corn Stalk-Based Solid Acid Catalyst and Reductase Biocatalyst in a Deep Eutectic Solvent–Water System

Processes ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 113
Author(s):  
Jianguang Liang ◽  
Li Ji ◽  
Jiarui He ◽  
Shuxin Tang ◽  
Yucai He
Keyword(s):  
Furfuryl Alcohol ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Deep Eutectic Solvent ◽  
Water System ◽  
Value Added ◽  
Acid Catalyst ◽  
Corn Stalk ◽  
Solvent Water ◽  
Water Media

In this work, the feasibility of chemoenzymatically transforming biomass-derived D-xylose to furfuryl alcohol was demonstrated in a tandem reaction with SO42−/SnO2-CS chemocatalyst and reductase biocatalyst in the deep eutectic solvent (DES)–water media. The high furfural yield (44.6%) was obtained by catalyzing biomass-derived D-xylose (75.0 g/L) in 20 min at 185 °C with SO42−/SnO2-CS (1.2 wt%) in DES ChCl:EG–water (5:95, v/v). Subsequently, recombinant E.coli CF cells harboring reductases transformed D-xylose-derived furfural (200.0 mM) to furfuryl alcohol in the yield of 35.7% (based on D-xylose) at 35 °C and pH 7.5 using HCOONa as cosubstrate in ChCl:EG–water. This chemoenzymatic cascade catalysis strategy could be employed for the sustainable production of value-added furan-based chemical from renewable bioresource.

Molar Enthalpy of Mixing for Choline Chloride/Urea Deep Eutectic Solvent + Water System

2016 ◽  
Vol 61 (12) ◽  
pp. 4172-4177 ◽  
Author(s):  
Chunyan Ma ◽  
Yanhua Guo ◽  
Dongxue Li ◽  
Jianpeng Zong ◽  
Xiaoyan Ji ◽  
...  
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Water System ◽  
Enthalpy Of Mixing ◽  
Molar Enthalpy ◽  
Solvent Water

Exploration of benign deep eutectic solvent–water system for the high-efficient production of furfurylamine from sugarcane bagasse via chemoenzymatic cascade catalysis

2021 ◽  
Author(s):  
Qing Li ◽  
Junhua Di ◽  
Xiaolong Liao ◽  
Jiacheng Ni ◽  
Qi Li ◽  
...  
Keyword(s):  
Sugarcane Bagasse ◽  
Deep Eutectic Solvent ◽  
Reaction System ◽  
Water System ◽  
Value Added ◽  
Environmentally Friendly ◽  
Cost Effective ◽  
Efficient Production ◽  
Solvent Water ◽  
High Efficient

Recently, cost-effective production of highly value-added furan chemicals from abundant and renewable bioresources has gained much attentions via chemoenzymatic approach in environmentally-friendly reaction system. In this work, chemoenzymatic cascade reaction...

Transition from molecular- to nano-scale segregation in a deep eutectic solvent - water mixture

2021 ◽  
Vol 331 ◽  
pp. 115747
Author(s):  
Matteo Busato ◽  
Valerio Di Lisio ◽  
Alessandra Del Giudice ◽  
Pierpaolo Tomai ◽  
Valentina Migliorati ◽  
...  
Keyword(s):  
Deep Eutectic Solvent ◽  
Water Mixture ◽  
Solvent Water ◽  
Nano Scale
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