scholarly journals Effects of Brownfield Remediation on Total Gaseous Mercury Concentrations in an Urban Landscape

Sensors ◽  
2020 ◽  
Vol 20 (2) ◽  
pp. 387
Author(s):  
Linghui Meng ◽  
Charles T. Driscoll ◽  
Mario Montesdeoca ◽  
Huiting Mao
Keyword(s):  
Urban Areas ◽  
Urban Landscape ◽  
Urban Ecosystems ◽  
Atmospheric Mercury ◽  
Soil Restoration ◽  
Total Gaseous Mercury ◽  
Annual Average ◽  
Mercury Emissions ◽  
Gaseous Mercury ◽  
Parking Lot

In order to obtain a better perspective of the impacts of brownfields on the land–atmosphere exchange of mercury in urban areas, total gaseous mercury (TGM) was measured at two heights (1.8 m and 42.7 m) prior to 2011–2012 and after 2015–2016 for the remediation of a brownfield and installation of a parking lot adjacent to the Syracuse Center of Excellence in Syracuse, NY, USA. Prior to brownfield remediation, the annual average TGM concentrations were 1.6 ± 0.6 and 1.4 ± 0.4 ng · m − 3 at the ground and upper heights, respectively. After brownfield remediation, the annual average TGM concentrations decreased by 32% and 22% at the ground and the upper height, respectively. Mercury soil flux measurements during summer after remediation showed net TGM deposition of 1.7 ng · m − 2 · day − 1 suggesting that the site transitioned from a mercury source to a net mercury sink. Measurements from the Atmospheric Mercury Network (AMNet) indicate that there was no regional decrease in TGM concentrations during the study period. This study demonstrates that evasion from mercury-contaminated soil significantly increased local TGM concentrations, which was subsequently mitigated after soil restoration. Considering the large number of brownfields, they may be an important source of mercury emissions source to local urban ecosystems and warrant future study at additional locations.

Gaseous mercury in coastal urban areas

2010 ◽  
Vol 7 (6) ◽  
pp. 537 ◽  
Author(s):  
Anne L. Soerensen ◽  
Henrik Skov ◽  
Matthew S. Johnson ◽  
Marianne Glasius
Keyword(s):  
Urban Areas ◽  
Marine Boundary Layer ◽  
Elemental Mercury ◽  
Atmospheric Mercury ◽  
Mercury Deposition ◽  
Mercury Emissions ◽  
Gaseous Elemental Mercury ◽  
Gaseous Mercury ◽  
Range Transport ◽  
Aquatic Food

Environmental context Mercury is a neurotoxin that bioaccumulates in the aquatic food web. Atmospheric emissions from urban areas close to the coast could cause increased local mercury deposition to the ocean. Our study adds important new data to the current limited knowledge on atmospheric mercury emissions and dynamics in coastal urban areas. Abstract Approximately 50% of primary atmospheric mercury emissions are anthropogenic, resulting from e.g. emission hotspots in urban areas. Emissions from urban areas close to the coast are of interest because they could increase deposition loads to nearby coastal waters as well as contribute to long range transport of mercury. We present results from measurements of gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) in 15 coastal cities and their surrounding marine boundary layer (MBL). An increase of 15–90% in GEM concentration in coastal urban areas was observed compared with the remote MBL. Strong RGM enhancements were only found in two cities. In urban areas with statistically significant GEM/CO enhancement ratios, slopes between 0.0020 and 0.0087 ng m–3 ppb–1 were observed, which is consistent with other observations of anthropogenic enhancement. The emission ratios were used to estimate GEM emissions from the areas. A closer examination of data from Sydney (Australia), the coast of Chile, and Valparaiso region (Chile) in the southern hemisphere, is presented.

Baseline atmospheric mercury studies at Ross Island, Antarctica

1993 ◽  
Vol 5 (3) ◽  
pp. 323-326 ◽  
Author(s):  
S. J. de Mora ◽  
J. E. Patterson ◽  
D. M. Bibby
Keyword(s):  
Mercury Concentration ◽  
Limit Of Detection ◽  
Atmospheric Mercury ◽  
Polar Regions ◽  
Total Gaseous Mercury ◽  
Gaseous Mercury

The first extended baseline studies of total gaseous mercury (TGM) and dimethylmercury (DMM) in Antarctica are reported. Mean TGM concentrations of 0.52, 0.60 and 0.52 ng m−3 were obtained for three consecutive years at the southern tip of Ross Island (77°S). The levels of DMM in Antarctica are less than 10% of the TGM, and frequently fall below the limit of detection. These results represent the lowest TGM concentrations recorded globally and extend into polar regions the observation of a decrease in atmospheric mercury concentration with increasing latitude.

Total gaseous mercury emissions from mercury-enriched soil in Guizhou, China

2006 ◽  
Vol 25 (S1) ◽  
pp. 243-244
Author(s):  
Xinbin Feng ◽  
Shaofeng Wang ◽  
Guangle Qiu ◽  
Yamin Hou ◽  
Shunlin Tang
Keyword(s):  
Total Gaseous Mercury ◽  
Mercury Emissions ◽  
Gaseous Mercury

scholarly journals Worldwide atmospheric mercury measurements: a review and synthesis of spatial and temporal trends

2010 ◽  
Vol 10 (1) ◽  
pp. 1261-1307 ◽  
Author(s):  
F. Sprovieri ◽  
N. Pirrone ◽  
R. Ebinghaus ◽  
H. Kock ◽  
A. Dommergue
Keyword(s):  
Temporal Trends ◽  
Ambient Air ◽  
Atmospheric Mercury ◽  
Water Soluble ◽  
Polar Regions ◽  
Mercury Emissions ◽  
Gaseous Mercury ◽  
National Programs ◽  
Spatial And Temporal Trends

Abstract. A large number of activities have been carried out during the last decade in different regions of the world, including polar regions, aiming to assess the level of mercury (Hg) species in ambient air and in precipitation observing their variation over time and with changing meteorological conditions. Following the discovery of atmospheric Hg depletion events (AMDEs) in Polar Regions several studies have indeed been conducted in order to assess the chemical-physical mechanisms related to AMDEs occurred in polar atmospheres with special attention to the consequences of these phenomena in terms of contamination of polar environment due to the rapid conversion of atmospheric gaseous Hg (Hg0) into reactive and water-soluble forms that may potentially become bioavailable. The understanding of the way in which mercury released to the atmosphere is eventually incorporated into biota is of crucial importance not only for the polar regions but also for the marine environment in general. The world's oceans and seas are in fact both sources and sinks of Hg and although it appears that the atmosphere is the major transport/distribution medium for Hg, because most Hg emissions are to the atmosphere, oceans and seas also play an important role. Currently, however, a coordinated observational network for Hg does not exist. There are a number of state and national programs that are collecting atmospheric Hg data but the parameters monitored, the locations of the monitoring sites and the methods employed may prohibit their utility in assessing Hg long-trend variations. The large increase in mercury emissions in fast developing countries (i.e., China, India) over the last decade due primarily to a sharp increase in energy production from the combustion of coal are not currently reflected in the long-term measurements of total gaseous mercury in ambient air and in precipitation data at several continuous monitoring sites in North Europe and North America. The discrepancy between observed gaseous mercury concentrations (steady or decreasing) and global mercury emission inventories (increasing) is not yet clear however, could be at least in part accounted by the increasing in the potential oxidation of the atmosphere recently documented. Therefore, measurements of other key atmospheric constituents at the global monitoring sites are necessary for us to develop a better understanding of the global redistribution of Hg and to further refine model parameterizations of the key processes. The sharing of data from this network, allowing, in fact, access to comparable and long-term data from a wide array of locations for understanding temporal and spatial patterns of Hg transport, deposition and re-emission process producing thus data that will support the validation of regional and global atmospheric Hg models. This paper presents a detailed overview of atmospheric mercury measurements conducted in the Northern and Southern Hemispheres at several terrestrial sites (industrial, rural and remote) during the last decade as well as measurements performed over the world's ocean and seas and in Polar Regions with reference to the monitoring techniques and location of monitoring sites in most of the continents.

scholarly journals Atmospheric total gaseous mercury (TGM) concentrations and wet and dry deposition of mercury at a high-altitude mountain peak in south China

2009 ◽  
Vol 9 (6) ◽  
pp. 23465-23504 ◽  
Author(s):  
X. W. Fu ◽  
X. Feng ◽  
Z. Q. Dong ◽  
R. S. Yin ◽  
J. X. Wang ◽  
...  
Keyword(s):  
South China ◽  
Dry Deposition ◽  
Urban Areas ◽  
Wet Deposition ◽  
Ambient Air ◽  
Total Gaseous Mercury ◽  
Deposition Fluxes ◽  
Wet And Dry Deposition ◽  
Gaseous Mercury ◽  
Seasonal And Diurnal Variations

Abstract. China is regarded as the largest contributor of mercury (Hg) to the global atmospheric Hg budget. However, concentration levels and depositions of atmospheric Hg in China are poorly known. Continuous measurements of atmospheric total gaseous mercury (TGM) were carried out from May 2008 to May 2009 at the summit of Mt. Leigong in south China. Wet and dry deposition fluxes of Hg were also calculated following collection of precipitation, throughfall and litterfall. Atmospheric TGM concentrations averaged 2.80±1.51 ng m−3, which was highly elevated compared to global background values but much lower than semi-rural and industrial/urban areas in China, indicating great emissions of Hg in central, south and southwest China. Seasonal and diurnal variations of TGM were observed, which reflected variations in source intensity, deposition processes and meteorological factors. Wet deposition of Hg was quite low, while its dry deposition of Hg (litterfall + throughfall-direct wet deposition) constituted a major portion of total deposition (~88% for total mercury (THg) and 84% for methyl mercury (MeHg)). This highlights the importance of vegetation to Hg atmospheric cycling. In a remote forest ecosystem of China, dry deposition of TGM, especially gaseous elemental mercury (GEM), was very important for the depletion of atmospheric Hg. Elevated TGM level in ambient air may accelerate the foliar uptake of Hg through air which may partly explain the elevated Hg dry deposition fluxes observed in Mt. Leigong.

scholarly journals Characterization of Atmospheric Mercury in the High-Altitude Background Station and Coastal Urban City in South Asia

2020 ◽  
Author(s):  
Manikanda Bharath Karuppasamy ◽  
Srinivasalu Seshachalam ◽  
Usha Natesan ◽  
Karthik Ramasamy
Keyword(s):  
High Altitude ◽  
Weather Conditions ◽  
Ambient Air ◽  
Atmospheric Mercury ◽  
Mercury Vapour ◽  
Total Gaseous Mercury ◽  
Gaseous Mercury ◽  
Rural And Urban ◽  
Sub Saharan ◽  
Management Approaches

This study is performed to evaluate the potential sources and seasonal variation of atmospheric mercury (Hg) emissions from regional sources and other influences in India. To achieve this, using the gold amalgam technique with an automated continuous mercury vapour analyzer (TekranTM 2537B). To assess the total gaseous mercury in high altitude mountain peak station at Kodaikanal & coastal/urban air in Chennai region, the impact of changing weather conditions is also evaluated. To compare the past and recent reports of mercury at different locations in the world. The average total gaseous mercury value in Chennai is 4.68 ng/m3, which is higher as compared to Kodaikanal, where it is 1.53 ng/m3. The association between TGM with meteorological parameters in ambient air such as temperature, relative humidity, rainfall intensity, the direction of wind and velocity of was studied. The TGM concentration in India are compared with other nations, the TGM levels are similar to the east and Southeast Asian countries, and also Europe, Sub-Saharan Africa and North America are the averages and maximum concentration generally smaller. This research will help to establish more effective management approaches to mitigate the impacts of atmospheric mercury on the rural and urban environment.

scholarly journals Seasonal patterns of atmospheric mercury in tropical South America as inferred by a continuous total gaseous mercury record at Chacaltaya station (5240 m) in Bolivia

2021 ◽  
Vol 21 (5) ◽  
pp. 3447-3472
Author(s):  
Alkuin Maximilian Koenig ◽  
Olivier Magand ◽  
Paolo Laj ◽  
Marcos Andrade ◽  
Isabel Moreno ◽  
...  
Keyword(s):  
South America ◽  
Dry Season ◽  
Atmospheric Mercury ◽  
Small Scale ◽  
Co2 Uptake ◽  
Total Gaseous Mercury ◽  
Wet Season ◽  
Air Masses ◽  
Gaseous Mercury ◽  
Vegetation Activity

Abstract. High-quality atmospheric mercury (Hg) data are rare for South America, especially for its tropical region. As a consequence, mercury dynamics are still highly uncertain in this region. This is a significant deficiency, as South America appears to play a major role in the global budget of this toxic pollutant. To address this issue, we performed nearly 2 years (July 2014–February 2016) of continuous high-resolution total gaseous mercury (TGM) measurements at the Chacaltaya (CHC) mountain site in the Bolivian Andes, which is subject to a diverse mix of air masses coming predominantly from the Altiplano and the Amazon rainforest. For the first 11 months of measurements, we obtained a mean TGM concentration of 0.89±0.01 ng m−3, which is in good agreement with the sparse amount of data available from the continent. For the remaining 9 months, we obtained a significantly higher TGM concentration of 1.34±0.01 ng m−3, a difference which we tentatively attribute to the strong El Niño event of 2015–2016. Based on HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectory) back trajectories and clustering techniques, we show that lower mean TGM concentrations were linked to either westerly Altiplanic air masses or those originating from the lowlands to the southeast of CHC. Elevated TGM concentrations were related to northerly air masses of Amazonian or southerly air masses of Altiplanic origin, with the former possibly linked to artisanal and small-scale gold mining (ASGM), whereas the latter might be explained by volcanic activity. We observed a marked seasonal pattern, with low TGM concentrations in the dry season (austral winter), rising concentrations during the biomass burning (BB) season, and the highest concentrations at the beginning of the wet season (austral summer). With the help of simultaneously sampled equivalent black carbon (eBC) and carbon monoxide (CO) data, we use the clearly BB-influenced signal during the BB season (August to October) to derive a mean TGM / CO emission ratio of (2.3±0.6)×10-7 ppbvTGM ppbvCO-1, which could be used to constrain South American BB emissions. Through the link with CO2 measured in situ and remotely sensed solar-induced fluorescence (SIF) as proxies for vegetation activity, we detect signs of a vegetation sink effect in Amazonian air masses and derive a “best guess” TGM / CO2 uptake ratio of 0.058 ±0.017 (ng m−3)TGM ppmCO2-1. Finally, significantly higher Hg concentrations in western Altiplanic air masses during the wet season compared with the dry season point towards the modulation of atmospheric Hg by the eastern Pacific Ocean.

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