Diversity of moths from the urban set-up of Valmiki Nagar, Chennai, India

A study was conducted at Valmiki Nagar, Chennai, Tamil Nadu, India to explore its moth diversity from December 2018 to May 2021. This manuscript presents a partial checklist of moths from Valmiki Nagar. Four locations around the colony were studied to record the moth fauna. The study sites were surveyed twice a month using a mercury vapour lamp along with a white sheet, along with over 100 visits at night. Diurnal surveys were conducted bimonthly to observe larval host plants and day flying moths. A total of 135 species were recorded from the study area, belonging to nine superfamilies. The most diverse family of moths recorded was family Erebidae, with 39% of moths recorded in the study belonging to this family, followed by Crambidae (30%), Geometridae (8%), and other families constituting the rest. The moth diversity in the month of July was seen to be the highest. Along with this study, future studies on similar lines will help in documenting the moth diversity of Chennai.

Pocket Mercury-Vapour Detection System Employing a Preconcentrator Based on Au-TiO2 Nanomaterials

In environments polluted by mercury vapors that are potentially harmful to human health, there is a need to perform rapid surveys in order to promptly identify the sources of emission. With this aim, in this work, a low cost, pocket-sized portable mercury measurement system, with a fast response signal is presented. It consists of a preconcentrator, able to adsorb and subsequently release the mercury vapour detected by a quartz crystal microbalance (QCM) sensor. The preconcentrator is based on an adsorbing layer of titania/gold nanoparticles (TiO2NP/AuNPs), deposited on a micro-heater that acts as mercury thermal desorption. For the detection of the released mercury vapour, gold electrodes QCM (20 MHz) have been used. The experimental results, performed in simulated polluted mercury-vapour environments, showed a detection capability with a prompt response. In particular, frequency shifts (−118 Hz ± 2 Hz and −30 Hz ± 2 Hz) were detected at concentrations of 65 µg/m3 Hg0 and 30 µg/m3 Hg0, with sampling times of 60 min and 30 min, respectively. A system limit of detection (LOD) of 5 µg/m3 was evaluated for the 30 min sampling time.

Normal light dispersion in laboratory experiments

We propose a laboratory experiment on the quantitative study of the normal dispersion of light. A triangular isosceles prism made of flint glass TF3 is used as the object of study, and we describe a simple and affordable device for observing and photographing the dispersion spectrum on a smartphone. A possibility of the quantitative investigation of light dispersion is provided by using a modern miniature mercury lamp emitting a line spectrum of mercury vapour against the background of a solid spectrum of white light. The method of processing experimental results is stated.

A comparison of methyl and gaseous elemental mercury in the urban atmosphere

This study was carried out to compare the levels of mercury species, i.e., elemental mercury (Hg°) and methyl mercury (MeHg), in indoor and outdoor air in urban areas in Canada. Offices, laboratories for undergraduate studies, and laboratories for research, in a public building located in the downtown core of the city of Toronto, were selected. Hg° was measured using an automated mercury vapour analyzer. MeHg in the air was collected using a carbotrap, and the trapped MeHg was thermally desorbed and analyzed using a CVAFS. The results showed that both indoor MeHg and Hg° levels were related to location function and air circulation. Outdoor MeHg levels were significantly elevated, ranging between 21 and 41% of total mercury (THg) levels, compared to those reported from previous studies. Outdoor Hg° fluctuations were not found to be significantly related to temperature or sunlight exposure, and outdoor MeHg levels were connected to soil and vegetation abundance. Average indoor Hg° levels were found to be between 1.4 and 15 times higher than outdoor levels, whereas MeHg indoor levels were not consistently higher than outdoor levels. Although the mercury concentrations in the indoor environment are still lower than the safety standard for Hg° and organic mercury, they are comparable to those observed near point sources. Thus, indoor air can be a source of mercury to the atmosphere.

A comparison of methyl and gaseous elemental mercury in the urban atmosphere

This study was carried out to compare the levels of mercury species, i.e., elemental mercury (Hg°) and methyl mercury (MeHg), in indoor and outdoor air in urban areas in Canada. Offices, laboratories for undergraduate studies, and laboratories for research, in a public building located in the downtown core of the city of Toronto, were selected. Hg° was measured using an automated mercury vapour analyzer. MeHg in the air was collected using a carbotrap, and the trapped MeHg was thermally desorbed and analyzed using a CVAFS. The results showed that both indoor MeHg and Hg° levels were related to location function and air circulation. Outdoor MeHg levels were significantly elevated, ranging between 21 and 41% of total mercury (THg) levels, compared to those reported from previous studies. Outdoor Hg° fluctuations were not found to be significantly related to temperature or sunlight exposure, and outdoor MeHg levels were connected to soil and vegetation abundance. Average indoor Hg° levels were found to be between 1.4 and 15 times higher than outdoor levels, whereas MeHg indoor levels were not consistently higher than outdoor levels. Although the mercury concentrations in the indoor environment are still lower than the safety standard for Hg° and organic mercury, they are comparable to those observed near point sources. Thus, indoor air can be a source of mercury to the atmosphere.

Effect of sources and meteorological conditions on the concentration and distribution of gaseous elemental mercury in the urban atmosphere

Atmospheric gaseous elemental mercury (GEM) and meteorological parameters were monitored at two sites in downtown Toronto, Canada from Oct. 2015 to Oct. 2016 using Tekran 2537A mercury vapour analyzers. The average concentration was found to be 1.78 ± 0.89 ng/m3 for Kerr Hall North (KHN) and 1.46 ± 0.54 ng/m3 for Jorgenson Hall (JOR) site. Analysis of the data reveals that sporadic events of high mercury concentration are related to local sources. Comparing this data set with that collected in 2004 revealed that the average atmospheric GEM concentration in downtown Toronto dropped from 4.5 ng/m3 to 1.78 ng/m3. Decreases in GEM were also observed over the same period in rural areas as measured by CAMNet. The decrease might be a result of policy change, as three key national and provincial environmental policies have been enacted since 2004. The data collected in Toronto suggest GEM concentration and distribution are influenced by local and regional sources, meteorological conditions, and changes in environmental policy.

Effect of sources and meteorological conditions on the concentration and distribution of gaseous elemental mercury in the urban atmosphere

Atmospheric gaseous elemental mercury (GEM) and meteorological parameters were monitored at two sites in downtown Toronto, Canada from Oct. 2015 to Oct. 2016 using Tekran 2537A mercury vapour analyzers. The average concentration was found to be 1.78 ± 0.89 ng/m3 for Kerr Hall North (KHN) and 1.46 ± 0.54 ng/m3 for Jorgenson Hall (JOR) site. Analysis of the data reveals that sporadic events of high mercury concentration are related to local sources. Comparing this data set with that collected in 2004 revealed that the average atmospheric GEM concentration in downtown Toronto dropped from 4.5 ng/m3 to 1.78 ng/m3. Decreases in GEM were also observed over the same period in rural areas as measured by CAMNet. The decrease might be a result of policy change, as three key national and provincial environmental policies have been enacted since 2004. The data collected in Toronto suggest GEM concentration and distribution are influenced by local and regional sources, meteorological conditions, and changes in environmental policy.

Mercury vapour haloes in near-surface air above ore deposits and faults on Vancouver Island, British Columbia, Canada

<p>Volatile geogenic components, such as CO<sub>2</sub>, He, Rn, and Hg<sup>0</sup>, form haloes in soil gas and near-surface air directly above mineral deposits. This contrasts with lithochemical, hydrochemical, and biochemical dispersion haloes that can be laterally displaced or obscured by transported overburden. Mercury vapour surveys have been used in exploration, because Hg occurs in most types of enogenic ore deposit types and is highly mobile. Low background concentrations in the atmosphere (1.2 to 1.5 ng/m<sup>3</sup>) enable detecting even weak Hg emissions directly above buried ore deposits. In this study, we measured Hg vapour in air 1-50 cm above ground at 15 sites on Vancouver Island, British Columbia, Canada. To evaluate the effectiveness of the method across a range of settings, these sites include different types of known mineralized zones, barren rocks, and faults, both buried and exposed. The direct and continuous analysis via a portable RA-915M mercury analyzer reveals Hg vapour concentrations ranging from 0.5 to 54.4 ng/m<sup>3</sup>. The highest Hg concentration was observed above tailings at the Bentley Au occurrence, possibly due to the amalgamation technique used for fine gold extraction between late 1800s and early 1900s. Prominent Hg vapour haloes mark shear-hosted Cu-Ag-Au sulphides at Mount Skirt (13.4x background Hg), epithermal Au-Ag-Cu at Mount Washington (8.9x background Hg), and sediment-covered polymetallic volcanogenic massive sulphides at the Lara-Coronation occurrence (4.2 to 6.6x background Hg). Basalt-hosted Cu-Ag-Au sulphide zones at the Sunro past producer are marked by weak Hg vapour anomalies relative to local background. Faults, including the Leech River fault, which was active in the Quaternary, are also marked by weak Hg vapour anomalies. The study confirms that, although the Hg level is influenced by weather, the real-time Hg vapour measurement of near-surface air can instantly delineate mineralized zones and fault structures that are buried under overburden 10s of m thick. In contrast to soil gas sampling, this simple and rapid technique can be applied to mineral exploration and geological mapping under overburden above any type of surface, including outcrops, talus, bogs, water bodies, snow, and permafrost.</p>

Photodegradation Properties of Earlywood and Latewood Spruce Timber Surfaces

Spruce (Picea abies Karst.) samples were irradiated using an ultraviolet light emitter mercury vapour lamp. The examined specimen surfaces contained earlywood or latewood to determine the photodegradation properties of these two tissue types. The generated chemical changes were monitored by diffuse reflectance Fourier transformed infrared spectroscopy. The difference spectrum method was used to present absorption changes. The earlywood suffered considerably greater degradation than the latewood during the UV irradiation. Most of the lignin molecules in the examined surface layer degraded during the first 11 days of UV irradiation for both earlywood and latewood. Results demonstrated that two types of unconjugated carbonyls absorbing at 1705 and 1764 cm–1 wavenumbers were created during the photodegradation. Time dependence of the absorption changes showed correlation between the guaiacyl lignin degradation and the generation of unconjugated carbonyl group absorbing at 1764 cm–1 wavenumber.

Electrical Characteristics of the High-frequency Induction Coil for Low Pressure Discharge in Ferrite-free Closed-loop Tubes

The effect the high-frequency field frequency and lamp design parameters have on the performance characteristics of the inductor of a ferrite-free inductively-coupled closed-loop tube is studied within the framework of a transformer model. The discharge was excided in tubes with diameters equal to 16, 25 and 38 mm in a mixture of mercury vapour (~ 0.01 mm Hg) and argon (0.6 mm Hg) at driving frequencies equal to 1.7, 3.4 and 8.5 MHz and plasma power equal to 25–200 W by means of an induction coil containing 1, 2 and 3 turns, and placed over the closed-loop tube inner perimeter. It has been found that the dependences of inductor high-frequency current and voltage, and power loss in the coil wire on the discharge plasma power have a minimum, which shifts toward lower power levels with increasing the driving frequency and discharge tube diameter. The minimal values of coil current, voltage, and power losses decrease with increasing the driving frequency, tube diameter and number of coil turns. The prediction results are in satisfactory qualitative agreement with the experimental data; the mismatches are supposedly due to the assumptions adopted in the model, according to which the skin effect and electric field spatial inhomogeneity were not taken into account.