Vertically aligned growth of small-diameter single-walled carbon nanotubes on flexible stainless steels by alcohol catalytic chemical vapor deposition with Ir catalyst on alumina buffer layer

Author(s):  
Shu KONDO ◽  
Daiki YAMAMOTO ◽  
Kamal Prasad Prasad Sharma ◽  
Yazid Yaakob ◽  
Takahiro SAIDA ◽  
...  

Abstract We performed single-walled carbon nanotube (SWCNT) growth on flexible stainless-steel foils by applying alcohol catalytic chemical vapor deposition using an Ir catalyst with an alumina buffer layer. When the alumina thickness was 90 nm, vertically aligned SWCNTs with a thickness of 4.6 m were grown. In addition, Raman results showed that the diameters of most SWCNTs were distributed below 1.1 nm. Compared with conventional chemical vapor deposition growth where Si wafers are used as substrates, this method is more cost effective and easier to extend for mass production of small-diameter SWCNTs.

Carbon ◽  
2010 ◽  
Vol 48 (4) ◽  
pp. 1279-1288 ◽  
Author(s):  
Charlotte T.M. Kwok ◽  
Brandon J. Reizman ◽  
Daniel E. Agnew ◽  
Gurjit S. Sandhu ◽  
J. Weistroffer ◽  
...  

2004 ◽  
Vol 858 ◽  
Author(s):  
H. Emrah Unalan ◽  
Manish Chhowalla

ABSTRACTSingle-walled carbon nanotubes (SWNTs) were synthesized both in powder form and on substrates using alcohol catalytic chemical vapor deposition method (ACCVD). A detailed parametric study was conducted. As-grown SWNTs were analyzed using transmission electron microscopy (HRTEM), field-emission scanning electron microscopy (FE-SEM) and Raman spectroscopy. Nucleation and growth of SWNTs occurred within seconds after introduction of the alcohol vapor. The results show that high quality SWNTs with a narrow diameter distribution without amorphous carbon can be grown using Co acetate catalyst doped with Fe acetate above 750°C. Defective nanotubes were observed at low (450°C) and high (950°C) temperatures with the optimum temperature being 850°C. In brief, our work has taken a step towards optimizing SWNTs growth conditions using ACCVD.


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