chemical vapor deposition method
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2022 ◽  
Author(s):  
Guoliang Zhou ◽  
Hui Gao ◽  
Jin Li ◽  
Xiaoyue He ◽  
Yanbing He ◽  
...  

Abstract WTe2 nanostructures have intrigued much attention due to their unique properties, such as large non-saturating magnetoresistance, quantum spin Hall effect and topological surface state. However, the controllable growth of large-area atomically thin WTe2 nanostructures remains a significant challenge. In the present work, we demonstrate the controllable synthesis of 1T’ atomically thin WTe2 nanoflakes (NFs) by water-assisted ambient pressure chemical vapor deposition method based on precursor design and substrate engineering strategies. The introduction of water during the growth process can generate a new synthesized route by reacting with WO3 to form intermediate volatile metal oxyhydroxide. Using WO3 foil as the growth precursor can drastically enhance the uniformity of as-prepared large-area 1T’ WTe2 NFs compared to WO3 powders. Moreover, highly oriented WTe2 NFs with distinct orientations can be obtained by using a-plane and c-plane sapphire substrates, respectively. Corresponding precursor design and substrate engineering strategies are expected to be applicable to other low dimensional transition metal dichalcogenides, which are crucial for the design of novel electronic and optoelectronic devices.


Nanomaterials ◽  
2022 ◽  
Vol 12 (2) ◽  
pp. 195
Author(s):  
Htet Su Wai ◽  
Chaoyang Li

Aluminum-doped zinc oxide film was deposited on a glass substrate by mist chemical vapor deposition method. The influence of different aluminum doping ratios on the structural and optical properties of zinc oxide film was investigated. The XRD results revealed that the diffraction peak of (101) crystal plane was the dominant peak for the deposited AZO films with the Al doping ratios increasing from 1 wt % to 3 wt %. It was found that the variation of AZO film structures was strongly dependent on the Al/Zn ratios. The intertwined nanosheet structures were obtained when Zn/O ratios were greater than Al/O ratios with the deposition temperature of 400 °C. The optical transmittance of all AZO films was greater than 80% in the visible region. The AZO film deposited with Al doping ratio of 2 wt % showed the highest photocatalytic efficiency between the wavelength of 475 nm and 700 nm, with the high first-order reaction rate of 0.004 min−1 under ultraviolet radiation. The mechanism of the AZO film influenced by aluminum doping ratio during mist chemical vapor deposition process was revealed.


Author(s):  
Linden K. Allison ◽  
Trisha Andrew

Abstract Wearable thermoelectric generator arrays have the potential to use waste body heat to power on-body sensors and create, for example, self-powered health monitoring systems. In this work, we demonstrate that a surface coating of a conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT-Cl), created on one face of a wool felt using a chemical vapor deposition method was able to manifest a Seebeck voltage when subjected to a temperature gradient. The wool felt devices can produce voltage outputs of up to 120 mV when measured on a human body. Herein, we present a strategy to create arrays of polymer-coated fabric thermopiles and to integrate such arrays into familiar garments that could become a part of a consumer’s daily wardrobe. Using wool felt as the substrate fabric onto which the conducting polymer coating is created allowed for a higher mass loading of the polymer on the fabric surface and shorter thermoelectric legs, as compared to our previous iteration. Six or eight of these PEDOT-Cl coated wool felt swatches were sewed onto a backing/support fabric and interconnected with silver threads to create a coupled array, which was then patched onto the collar of a commercial three-quarter zip jacket. The observed power output from a six-leg array while worn by a healthy person at room temperature (ΔT = 15 °C) was 2 µW, which is the highest value currently reported for a polymer thermoelectric device measured at room temperature.


2021 ◽  
Vol 2119 (1) ◽  
pp. 012087
Author(s):  
V Yu Vladimirov ◽  
S Ya Khmel ◽  
A I Safonov ◽  
V V Semionov ◽  
E A Chinnov

Abstract In this paper, the investigation of pool boiling heat transfer on biphilic micro/nanostructured surfaces is presented. An array of micrococoons from silicon oxide nanowires was synthesized on the surface of a copper heater using the gas-jet electron beam plasma chemical vapor deposition method. The biphilic properties of the surface were achieved by applying fluoropolymer spots by hot wire chemical vapor deposition. Technology of creating biphilic surfaces was developed and boiling curves were obtained for used samples. The advantages of using a biphilic surface to enhance heat transfer were demonstrated in comparison with a smooth surface and a micro-nanostructured surface without local hydrophobic fluoropolymer regions. This technology can be applied to enhance boiling heat transfer.


2021 ◽  
Vol 2119 (1) ◽  
pp. 012132
Author(s):  
D Y Kochkin ◽  
A L Bogoslovtseva ◽  
O A Kabov

Abstract This work investigates the dynamics of the contact line during the propagation of a dry spot in a water layer on a solid substrate. The substrate is coated with fluoropolymer by using a hot wire chemical vapor deposition method. The dry spot is generated using a thermocapillary mechanism caused by the heating of the substrate from below by the laser. By analyzing schlieren images, the dependence of the velocity of the contact line during the propagation of a dry spot was obtained for various initial thicknesses of liquid films.


Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7356
Author(s):  
Bo Yang ◽  
Lanxing Gao ◽  
Miaoxuan Xue ◽  
Haihe Wang ◽  
Yanqing Hou ◽  
...  

Carbon nano-materials have been widely used in many fields due to their electron transport, mechanics, and gas adsorption properties. This paper introduces the structure and properties of carbon nano-materials the preparation of carbon nano-materials by chemical vapor deposition method (CVD)—which is one of the most common preparation methods—and reaction simulation. A major factor affecting the material structure is its preparation link. Different preparation methods or different conditions will have a great impact on the structure and properties of the material (mechanical properties, electrical properties, magnetism, etc.). The main influencing factors (precursor, substrate, and catalyst) of carbon nano-materials prepared by CVD are summarized. Through simulation, the reaction can be optimized and the growth mode of substances can be controlled. Currently, numerical simulations of the CVD process can be utilized in two ways: changing the CVD reactor structure and observing CVD chemical reactions. Therefore, the development and research status of computational fluid dynamics (CFD) for CVD are summarized, as is the potential of combining experimental studies and numerical simulations to achieve and optimize controllable carbon nano-materials growth.


2021 ◽  
Vol 10 (1) ◽  
pp. 67-73
Author(s):  
Giang Pham Thi Thu ◽  
Quang Nguyen Ke ◽  
Thanh Duong Anh ◽  
Manh Nguyen Ba

Fe containing nano ZSM-5 composites (Fe/H-ZSM-5) were successfully prepared by chemical vapor deposition method.  The physical properties of Fe/H-ZSM-5 were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), N2 adsorption-desorption isotherm (BET) analysis. Effects of pH and H2O2 concentration were investigated. The best conditions were found to be pH of 3; 0.3 g.L−1 catalyst and reaction time of 60 min at room temperature. The novel Fe/H-ZSM-5 composite exhibited highly photocatalytic performance of RR-195 degradation and the conversion reached to the value of 92.3 % for after 60 min of reaction.


2021 ◽  
Vol 7 (4) ◽  
pp. 79
Author(s):  
Abdul Hoque ◽  
Ahamed Ullah ◽  
Beth S. Guiton ◽  
Noe T. Alvarez

Carbon nanotubes (CNTs) offer unique properties that have the potential to address multiple issues in industry and material sciences. Although many synthesis methods have been developed, it remains difficult to control CNT characteristics. Here, with the goal of achieving such control, we report a bottom-up process for CNT synthesis in which monolayers of premade aluminum oxide (Al2O3) and iron oxide (Fe3O4) nanoparticles were anchored on a flat silicon oxide (SiO2) substrate. The nanoparticle dispersion and monolayer assembly of the oleic-acid-stabilized Al2O3 nanoparticles were achieved using 11-phosphonoundecanoic acid as a bifunctional linker, with the phosphonate group binding to the SiO2 substrate and the terminal carboxylate group binding to the nanoparticles. Subsequently, an Fe3O4 monolayer was formed over the Al2O3 layer using the same approach. The assembled Al2O3 and Fe3O4 nanoparticle monolayers acted as a catalyst support and catalyst, respectively, for the growth of vertically aligned CNTs. The CNTs were successfully synthesized using a conventional atmospheric pressure-chemical vapor deposition method with acetylene as the carbon precursor. Thus, these nanoparticle films provide a facile and inexpensive approach for producing homogenous CNTs.


Author(s):  
Ji Li ◽  
Jiawen Qiu ◽  
Xiaogang Chen ◽  
Muhammed Said Ergoktas ◽  
Coskun Kocabas

AbstractThis study aims to improve the tensile properties of the polyethylene film deposited with a multilayer graphene membrane, in order to establish the understanding of the influence of the methane to hydrogen ratio on the tensile properties of the multilayer graphene membrane. Multilayer graphene membranes were prepared using the chemical vapor deposition method. Four types of multilayer graphene membranes were prepared with different ratios of methane to hydrogen before depositing a membrane on the polyethylene film. Experiments showed that the tensile strength of the polyethylene films with multilayer graphene deposition increased 7 times and the Young’s modulus 5 times more than that of pure polyethylene films, when the ratio of methane to hydrogen was set to 35/100 sccm. A compromise between hydrogen and methane mixture is required to achieve uniform growth of graphene. Insufficient hydrogen cannot activate the surface bound carbon that is necessary for continuous growth. Continuous and well-defined multilayer graphene was synthesized when the ratio of methane to hydrogen reached up a proper value.


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