scholarly journals Biosorption of Methylene Blue Dye from Aqueous Solutions

Synthetic dyes, like methylene blue, in effluents of chemical industries, are reported to be toxic with alleged carcinogenic and genotoxic consequences. Biosorption is considered as a low-cost alternative to the costly removal processes. Agricultural wastes and plant biomass and are contemplated to be low-cost candidates because they can be used without or with a minimum of processing. This work was intended to test the possibility and comparative study of different low-cost natural adsorbents [Coconut husk (H), Groundnut shell (G), Cow Dung (C) and moss (M)] for the sequestration of methylene blue dye from aqueous solution. A batch process was done to study the effects of different parameters such as contact time, pH, adsorbent dosage and initial dye concentration. Adsorption equilibrium data were represented using Langmuir, Freundlich and Temkin isotherm models. 75 % of dye removal was observed with moss, hence proves to be an effective, low-cost adsorbent.

2020 ◽  
Vol 2020 ◽  
pp. 1-11 ◽  
Author(s):  
Rekha Singh ◽  
Tony S. Singh ◽  
John O. Odiyo ◽  
James A. Smith ◽  
Joshua N. Edokpayi

This paper presents a study on batch sorption of methylene blue dye from aqueous solution onto Ginkgo biloba sorbent, a waste material produced during the Fall season in many parts of the world. Batch kinetics, equilibrium, and thermodynamic studies were conducted to evaluate the effect of contact time (0–150 min), sorbent dose (0.5–3.0 g/L), pH (2–11), temperature (30–50°C), initial MB concentration (10–30 mg/L), and particle size (177 μm—590 μm) on the methylene blue dye sorption. More than 99% removal of methylene blue was observed within 120 minutes. A Lagergren pseudo-first-order model, a pseudo-second-order model, and intraparticle diffusion models fitted well to the kinetics experimental data. Langmuir and Freundlich isotherm models also fitted well with the observed equilibrium data. Additionally, removal of methylene blue increased with increase in solution pH. Higher sorption capacity (∼20 mg/g) was observed with smaller particle size (170 μm) as compared to larger particle sizes (590 μm). Thermodynamic parameters such as ∆G°, ∆H°, and ∆S° indicated that the sorption process was feasible, spontaneous, and endothermic in nature. The study shows that Ginkgo biloba leaves have the potential to be an efficient sorbent for the removal of methylene blue from surface water samples.


2015 ◽  
Vol 74 ◽  
pp. 903-911 ◽  
Author(s):  
Fatma Bouaziz ◽  
Mohamed Koubaa ◽  
Fatma Kallel ◽  
Fatma Chaari ◽  
Dorra Driss ◽  
...  

Author(s):  
Iliane Muller Otto ◽  
Luiza Beatriz Gamboa Araújo Morselli ◽  
Dienifer Aline Braun Bunde ◽  
Simone Pieniz ◽  
Maurízio Silveira Quadro ◽  
...  

The textile industry, very important for the world economy, generates an effluent containing dyes, and which, when discarded in water bodies without proper treatment, can cause impacts to human health and the environment. One of these widely used dyes is methylene blue, whose characteristics are high solubility in water and its toxic potential, and which effects range from eye irritations, nausea, vomiting and even mental confusion. Among the potential adsorbents of this dye is chitin, which is a biopolymer extracted from the shrimp exoskeleton. Aiming at the development of a low-cost adsorbent material with potential use in the textile effluent treatment industry, the ability to remove methylene blue dye by shrimp residue chitin, obtained by eleven different methodologies, was verified. The three most efficient treatments reached approximately 75% of dye removal, proving the high adsorption power of shrimp residue. In addition to providing technological development of materials, the research brings socioeconomic benefits to the fishermen’s colony with the use of shrimp residue for the adsorption of other waste from the textile industry, contributing to the sustainability of both activities and reducing the environmental impact.


Author(s):  
Fabiano Mendonça De Oliveira ◽  
Priscila Afonso Rodrigues de Sousa ◽  
Edmar Isaias De Melo ◽  
Luciana Melo Coelho

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