scholarly journals Preparation and Characterization of Ammonium Ceric Nitrate Doped PVDF Polymer Electrolytes

2019 ◽  
Vol 8 (4S2) ◽  
pp. 903-906
Keyword(s):  
Polymer Electrolytes ◽  
Vinylidene Fluoride ◽  
Impedance Analysis ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Casting Technique ◽  
Ac Impedance Analysis ◽  
Poly Vinylidene Fluoride ◽  
Solution Casting Technique ◽  
Ammonium Ceric Nitrate

Poly [vinylidene fluoride] (PVdF): Ammonium ceric nitrate ((NH4)2Ce(NO3)6) based Proton conducting solid polymer electrolytes (SPEs) are prepared by solution casting technique. Polymer electrolytes are characterized by several techniques. The Structural property of the electrolytes are confirmed by XRD. The functional groups present in polymer electrolytes are confirmed by FTIR. The conductivity of the polymer electrolytes are calculated by using AC impedance analysis. The Maximum ionic conductivity is obtained for 2wt% of ammonium ceric nitrate doped polymer electrolyte.

Characterization of Plasticized PMMA-LiClO4 Solid Polymer Electrolytes

2012 ◽  
Vol 585 ◽  
pp. 185-189 ◽  
Author(s):  
Rajni Sharma ◽  
Anjan Sil ◽  
Subrata Ray
Keyword(s):  
Ionic Conductivity ◽  
Polymer Electrolytes ◽  
Thermal Analyses ◽  
Impedance Analysis ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Casting Technique ◽  
Ac Impedance Analysis ◽  
Solution Casting Technique

In the present work, the effect of Li salt i.e. LiClO4 contained in composite plasticizer (PC+DEC) with three different concentrations on ionic transport and other electrochemical properties of PMMA based gel polymer electrolytes synthesized has been investigated. The electrolytes have been synthesized by solution casting technique by varying the wt (%) of salt and plasticizer. The formation of polymer-salt complexes and their structural characterization have been carried out by FTIR spectroscopic and XRD analyses. The room temperature ionic conductivity of the electrolyte composition 0.6PMMA-0.125(PC+DEC)-0.15LiClO4 (wt %) has been found to be maximum whose magnitude is 0.40×10-5 S/cm as determined by ac impedance analysis. The temperature dependent ionic conductivity of electrolyte sample0.6PMMA-0.125(PC+DEC)-0.15LiClO4 has further been investigated. Thermal analyses of electrolyte samples of all three compositions have also been done.

scholarly journals Optimization of Benzoguanamine doped PVDF/KI/I2 Solid Polymer Electrolytes for Dye-Sensitized Solar Cell Applications

2021 ◽  
Author(s):  
Kannadhasan Sundaramoorthy ◽  
Muthu Senthil Pandian ◽  
P. Ramasamy
Keyword(s):  
Ionic Conductivity ◽  
Surface Morphology ◽  
Polymer Electrolytes ◽  
Photovoltaic Performance ◽  
Impedance Analysis ◽  
Sem Analysis ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Casting Technique ◽  
Ac Impedance Analysis

Abstract Benzoguanamine doped 0%, 10%, 20%, 30%, 40% and 50% PVDF/KI/I2 polymer electrolytes were prepared by solution casting technique. The crystallinity, surface morphology, ionic conductivity and photovoltaic performance of polymer electrolytes were analyzed. The PXRD studies have confirmed the decreased and increased crystallinity of benzoguanamine doped polymer electrolytes. The surface morphology of polymer electrolytes is discussed using SEM analysis. From the AC-impedance analysis, ionic conductivity of benzoguanamine doped 0%, 10%, 20%, 30%, 40% and 50% PVDF/KI/I2 polymer electrolytes were calculated as 5.57 × 10− 6 Scm− 1, 1.05 × 10− 5 Scm− 1, 5.95 × 10− 5 Scm− 1, 3.09 × 10− 5 Scm− 1, 1.56 × 10− 5 Scm− 1 and 1.48 × 10− 5 Scm− 1, respectively. The photovoltaic performance of benzoguanamine doped 0%, 10%, 20%, 30%, 40% and 50% PVDF/KI/I2 polymer electrolytes based DSSCs have achieved 1.5%, 1.9%, 2.8%, 2.5%, 2.3% and 2.1% power conversion efficiency, respectively.

MICRO RAMAN, 7Li NMR AND ac IMPEDANCE ANALYSIS OF PVAC:LiClO4 SOLID POLYMER ELECTROLYTES

2006 ◽  
Author(s):  
R. BASKARAN ◽  
S. SELVASEKARAPANDIAN ◽  
N. KUWATA ◽  
O. KAMISHIMA ◽  
J. KAWAMURA ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Impedance Analysis ◽  
Ac Impedance ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
7Li Nmr ◽  
Ac Impedance Analysis

The Investigation on Ionic Conduction of PEMA Based Solid Polymer Electrolytes

2010 ◽  
Vol 93-94 ◽  
pp. 381-384
Author(s):  
Shahrul Amir ◽  
Mohamed Nor Sabirin ◽  
Ri Hanum Yahaya Subban
Keyword(s):  
Polymer Electrolytes ◽  
Ionic Conduction ◽  
Lithium Perchlorate ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
X Ray Diffraction ◽  
Conducting Film ◽  
X Ray ◽  
Casting Technique ◽  
Solution Casting Technique

Solid polymer electrolytes comprising of various weight ratios of poly(ethyl methacrylate) (PEMA) and lithium perchlorate (LiClO4) salt were prepared via solution casting technique using N,N-Dimethylformamide (DMF) as the solvent. The conductivity values of the electrolytes were determined utilizing Solatron 1260. The highest conductivity obtained is in the order of 10-6 S cm-1. Structural properties of the electrolytes were investigated by X-ray diffraction and the results show that the highest conducting film is the most amorphous.

Structural and ion transport properties of lithium triflate/poly(vinylidene fluoride-co-hexafluoropropylene)-based polymer electrolytes

2016 ◽  
Vol 49 (6) ◽  
pp. 513-526 ◽  
Author(s):  
Asheesh Kumar ◽  
Raghunandan Sharma ◽  
M Suresh ◽  
Malay K Das ◽  
Kamal K Kar
Keyword(s):  
Polymer Electrolytes ◽  
Vinylidene Fluoride ◽  
Complex Impedance ◽  
Weight Ratio ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Spectroscopic Techniques ◽  
Lithium Triflate ◽  
Increase With Increase ◽  
Poly Vinylidene Fluoride

Polymer electrolytes consisting of poly(vinylidene fluoride-co-hexafluoropropylene) in combination with lithium triflate (LiCF3SO3) salt of varying concentration have been prepared using the conventional solution casting technique in the argon atmosphere. Structural electrical characterizations of the synthesized electrolytes have been performed using various imaging and spectroscopic techniques. The DC conductivities determined by complex impedance plots reveal gradual increase with increase in salt concentration up to a particular limit and decrease subsequently. The maximum DC conductivity obtained at 300 K is 1.64 × 10−4 Scm−1 for the electrolyte with a polymer to salt weight ratio of 1:1.8. The temperature-dependent conductivity followed a mixed Arrhenius and Vogel–Tamman–Fulcher type behaviour for the polymer electrolytes. From the Summerfield master curve plot, the conductivity of the solid polymer electrolytes is found to depend not only on ion dynamics but also on the segmental mobility of the polymer chains.

Effect of Ionic Liquid Anion Type in the Performance of Solid Polymer Electrolytes Based on Poly(Vinylidene fluoride‐trifluoroethylene)

2014 ◽  
Vol 27 (2) ◽  
pp. 457-464 ◽  
Author(s):  
R. Leones ◽  
C. M. Costa ◽  
A. V. Machado ◽  
J. M. S. S. Esperança ◽  
M. M. Silva ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Polymer Electrolytes ◽  
Vinylidene Fluoride ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Poly Vinylidene Fluoride ◽  
Anion Type
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