The use of dry sorbents for the removal of SO2 from the flue gas of coal-fired power plants is of interest in reducing the complexity of SO2 removal and appears to offer economic incentives. In 1982, the Electric Power Research Institute, Public Service company of Colorado (PSCCO), and Multi-Mineral Corporation co-sponsored a full-scale demonstration of the dry injection process at the Cameo Station, Unit 1, of PSCCO near Grand Junction, Colorado.Laboratory comparative studies of nahcolite (NaHCO3), trona and soda ash Na2CO3) with that exposed to gas streams of air or of SO2 at elevated temperatures have been reported to provide microstructural data (from SEM) for correlation with microchemical information and phase identification for possible reactions of these materials which may occur under conditions for injection of a dry sorbent at the utility plant, and which may bear on the effectiveness of SO2 reaction with sorbents.