On the Stability of Nitrate and Chloride Complexes of Plutonium (IV).

1960 ◽  
Vol 14 ◽  
pp. 2216-2229 ◽  
Author(s):  
Ingmar Grenthe ◽  
Bertil Norén ◽  
Göran Kull ◽  
Bengt Lindberg
Keyword(s):  
Chloride Complexes ◽  
The Stability

Effects of Ionic Strength and Charge Density on the Stability of Chloride Complexes of Trivalent Lanthanides

2008 ◽  
Vol 53 (8) ◽  
pp. 1756-1761 ◽  
Author(s):  
Edelmira Fernández-Ramírez ◽  
Melania Jiménez-Reyes ◽  
Marcos J. Solache-Ríos
Keyword(s):  
Ionic Strength ◽  
Charge Density ◽  
Chloride Complexes ◽  
Trivalent Lanthanides ◽  
The Stability

scholarly journals Structural Diversity of Nickel and Manganese Chloride Complexes with Pyridin-2-One

Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 846
Author(s):  
Saša Petriček
Keyword(s):  
Thermal Analyses ◽  
Molecular Complexes ◽  
Structural Diversity ◽  
Carbonyl Oxygen ◽  
Chloride Complexes ◽  
Manganese Compound ◽  
Connectivity Patterns ◽  
Stability Of Complexes ◽  
The Stability ◽  
Monodentate Coordination

Reactions of NiCl2·6H2O and pyridin-2-one (C5H5NO = Hhp) afforded novel molecular complexes, i.e., mononuclear [NiCl2(Hhp)4] (1), dinuclear [NiCl2(Hhp)(H2O)2]2.2Hhp (3) and [Ni2Cl4(Hhp)5]·2MeCN (4), and an ionic complex [Ni(Hhp)6]Cl2 (2). Single-crystal X-ray analyses revealed two modes of Hhp ligation in these complexes: a monodentate coordination of carbonyl oxygen in all of them and an additional µ2-oxygen bridging coordination in the dinuclear complex 4. Three bridging molecules of Hhp span two nickel(II) ions in 4 with a 2.9802 (5) Å separation of the metal ions. Complex 3 is a chlorido-bridged nickel dimer with a planar Ni2(µ-Cl)2 framework. Hydrogen bonds and parallel stacking arrangements of the Hhp molecules govern the connectivity patterns in the crystals, resulting in 1D structures in 1 and 5 or 2D in 3. A single manganese compound [MnCl2(Hhp)4] (5), isostructural to 1, was isolated under the similar conditions. This is in contrast to four nickel(II) chloride complexes with Hhp. Thermal analyses proved the stability of complexes 1 and 3 in argon up to 145 °C and 100 °C, respectively. The decomposition of 1 and 3 yielded nickel in argon and nickel(II) oxide in air at 800 °C.

scholarly journals The Stability of Metal Halide Complexes in Aqueous Solution. VII. The Chloride Complexes of Copper(I).

1970 ◽  
Vol 24 ◽  
pp. 157-172 ◽  
Author(s):  
Sten Ahrland ◽  
James Rawsthorne ◽  
Arne Haaland ◽  
Bodil Jerslev ◽  
Claus Erik Schäffer ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Halide ◽  
Chloride Complexes ◽  
Halide Complexes ◽  
The Stability

The activity coefficients of cadmium chloride in water and sodium chloride solution at 25°

1970 ◽  
Vol 23 (7) ◽  
pp. 1397 ◽  
Author(s):  
PJ Reilly ◽  
RH Stokes
Keyword(s):  
Sodium Chloride ◽  
Stability Constants ◽  
Activity Coefficients ◽  
Chloride Solution ◽  
Cadmium Chloride ◽  
Sodium Chloride Solution ◽  
Chloride Complexes ◽  
The Stability

The activity coefficients of cadmium chloride in water and sodium chloride solution have been measured. The data have been used to calculate the stability constants of the cadmium chloride complexes. The results are compared with the results of previous work and reasons for the discrepancies are suggested.

The stability of Au-chloride complexes in water vapor at elevated temperatures and pressures

2001 ◽  
Vol 65 (23) ◽  
pp. 4413-4423 ◽  
Author(s):  
S.M. Archibald ◽  
A.A. Migdisov ◽  
A.E. Williams-Jones
Keyword(s):  
Water Vapor ◽  
Elevated Temperatures ◽  
Chloride Complexes ◽  
The Stability
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