scholarly journals Recent advances in acid-free dissolution and separation of rare earth elements from the magnet waste

2021 ◽  
Vol 1 (2) ◽  
pp. 112-123
Author(s):  
Grace Inman ◽  
◽  
Denis Prodius ◽  
Ikenna C. Nlebedim

<abstract> <p>The availability of REEs is limiting the successful deployment of some environmentally friendly and energy-efficient technologies. In 2019, the U.S. generated more than 15.25 billion pounds of e-waste. Only ~15% of it was handled, leaving ~13 billion pounds of e-waste as potential pollutants. Of the 15% collected, the lack of robust technology limited REE recovery for re-use. Key factors that drive the recycling of permanent magnets based on rare earth elements (REEs) and the results of our research on magnet recycling will be discussed, with emphasis on neodymium and samarium-based rare earth permanent magnets.</p> </abstract>

2021 ◽  
Vol 7 (6) ◽  
pp. 89
Author(s):  
Valerio De Santis

Recent advances in computational electromagnetics (CEMs) have made the full characterization of complex magnetic materials possible, such as superconducting materials, composite or nanomaterials, rare-earth free permanent magnets, etc [...]


Author(s):  
A. Ya. Krasilʼnikov ◽  
A. A. Krasilʼnikov

The article considers the possibility of using a standard method for calculating the shear force of thin, high-coercivity neodymium–iron–boron type permanent magnets in magnetic clutches (couplings). The research results allowed to introduce a correction coefficients in the method of calculating the transmitting torque in magnetic clutches (couplings) with thin magnets. The possibility of 08H22N6T brand steel using for magnetic flux conductors manufacturing in a magnetic couplings.


2019 ◽  
Vol 6 (1) ◽  
pp. 91-102 ◽  
Author(s):  
Martina Orefice ◽  
Amy Van den Bulck ◽  
Bart Blanpain ◽  
Koen Binnemans

AbstractOxidative roasting of Nd–Fe‒B permanent magnets prior to leaching improves the selectivity in the recovery of rare-earth elements over iron. However, the dissolution rate of oxidatively roasted Nd–Fe‒B permanent magnets in acidic solutions is very slow, often longer than 24 h. Upon roasting in air at temperatures above 500 °C, the neodymium metal is not converted to Nd2O3, but rather to the ternary NdFeO3 phase. NdFeO3 is much more difficult to dissolve than Nd2O3. In this work, the formation of NdFeO3 was avoided by roasting Nd–Fe‒B permanent magnet production scrap in argon atmosphere, having an oxygen content of $$ p_{{{\text{O}}_{2} }} \, \le \,10^{ - 20} \;{\text{atm}}, $$pO2≤10-20atm, with the addition of 5 wt% of carbon as an iron reducing agent. For all the non-oxidizing iron roasting conditions investigated, the iron in the Nd–Fe‒B scrap formed a cobalt-containing metallic phase, clearly distinct from the rare-earth phase at microscopic level. The thermal treatment was optimized to obtain a clear phase separation of metallic iron and rare-earth phase also at the macroscopic level, to enable easy mechanical removal of iron prior to the leaching step. The sample roasted at the optimum conditions (i.e., 5 wt% carbon, no flux, no quenching step, roasting temperature of 1400 °C and roasting time of 2 h) was leached in the water-containing ionic liquid betainium bis(trifluoromethylsulfonyl)imide, [Hbet][Tf2N]. A leaching time of only 20 min was sufficient to completely dissolve the rare-earth elements. The rare-earth elements/iron ratio in the leachate was about 50 times higher than the initial rare-earth elements/iron ratio in the Nd–Fe‒B scrap. Therefore, roasting in argon with addition of a small amount of carbon is an efficient process step to avoid the formation of NdFeO3 and to separate the rare-earth elements from the iron, resulting in selective leaching for the recovery of rare-earth elements from Nd–Fe‒B permanent magnets.


Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4710
Author(s):  
Yunhu Hu ◽  
Mu You ◽  
Guijian Liu ◽  
Zhongbing Dong ◽  
Facun Jiao ◽  
...  

Strategically critical elements are becoming significant for the rising demand of emerging energy-efficient technologies and high-tech applications. These critical elements are mostly geologically dispersed, and mainly recovered from recycled materials. Coal with high concentrations of critical elements is supposed to stable alternative sources. The abundances of critical elements in coal varies widely among different deposits and regions. The high concentrations of critical elements are found in many Chinese and Russian coal ores. The global mining potential ratio (MPR) is applied and suggests scandium, hafnium, cesium, yttrium, germanium, gallium, thallium, strontium and rare-earth elements could be potential recovery from coal. A number of benefits are expected with the extraction of critical elements during coal utilization.


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