Effects of oxygen plasma treatments on the work function of indium tin oxide studied by in-situ photoelectron spectroscopy

2016 ◽  
Vol 68 (5) ◽  
pp. 692-696 ◽  
Author(s):  
Minjae Maeng ◽  
Ji-Hoon Kim ◽  
Jong-Am Hong ◽  
Yongsup Park
2002 ◽  
Vol 747 ◽  
Author(s):  
H. H. Fong ◽  
W. J. Song ◽  
S. K. So

ABSTRACTThe surface properties of indium-tin-oxide (ITO) thin films treated by UV ozone or plasma were analyzed by angular dependent X-ray photoelectron spectroscopy (ADXPS) and by ultraviolet photoemission (UPS). The chemical composition, chemical states and the work function of the ITO surfaces were deduced. Our analysis indicate that ITO surface is Sn-rich. Both UV ozone and O-plasma treatments are most effective in removing surface hydrocarbon. Among all treatments, O-plasma treated surface achieved the highest work function of 4.4eV, whereas argon ion sputtered surface had the lowest work function of 3.9eV. Both O-plasma and UV ozone treatments increase the surface oxygen concentration. It is proposed that O2-ions diffuse into ITO. The diffusion length is about 50Å as deduced from ADXPS. The stoichiometry of the surface is the major factor in controlling the surface work function of ITO. A surface band bending model is proposed to account for the change of work function due to “oxidized” ITO surface after UV-ozone or oxygen plasma treatments.


2009 ◽  
Vol 48 (2) ◽  
pp. 021601 ◽  
Author(s):  
Kang-Pil Kim ◽  
A. Mohammed Hussain ◽  
Dae-Kue Hwang ◽  
Sung-Ho Woo ◽  
Hong-Keun Lyu ◽  
...  

2015 ◽  
Vol 56 (9) ◽  
pp. 1445-1447 ◽  
Author(s):  
Daisuke Yamashita ◽  
Atsushi Ishizaki ◽  
Tomoyuki Yamamoto

2012 ◽  
Vol 13 (10) ◽  
pp. 2028-2034 ◽  
Author(s):  
Irfan Irfan ◽  
Sachiko Graber ◽  
Franky So ◽  
Yongli Gao

2013 ◽  
Vol 15 (8) ◽  
pp. 791-793 ◽  
Author(s):  
Huanzhong Gao ◽  
Long He ◽  
Zhijiang He ◽  
Zebin Li ◽  
Zhonghang Wu ◽  
...  

1996 ◽  
Vol 68 (19) ◽  
pp. 2699-2701 ◽  
Author(s):  
Y. Park ◽  
V. Choong ◽  
Y. Gao ◽  
B. R. Hsieh ◽  
C. W. Tang

2013 ◽  
Vol 06 (02) ◽  
pp. 1350020 ◽  
Author(s):  
LONG HE ◽  
ZHONGHANG WU ◽  
KONGDUO HE ◽  
XIAOXUAN FAN ◽  
ZEBIN LI ◽  
...  

Indium tin oxide (ITO) was modified by oxygen inductive coupled plasma (O-ICP) and oxygen plasma immersion ion implantation (O-PIII) respectively to compare the effects of both techniques on the surface properties. X-ray photoelectron spectroscopy (XPS) was applied to characterize the electronic state of ITO surface. The oxygen content enhancement and band bending at the surface of ITO were found after treatment by both O-ICP and O-PIII. The surface work function of ITO thin film depends on the oxygen composition at the surface. A surface work function increment of 0.8 eV by O-PIII was estimated from the shift of O1s core levels to low binding energy, which was the double of that by O-ICP. The conductivity increment of ITO films was less than 1% after O-ICP and O-PIII treatment. The transparency of ITO films increased by about 1% resulted from surface texture by O-PIII sputtering.


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