Microstructures and Mechanical Properties of Al/Al2O3 Cermet Composites Reinforced by Al/Al2O3 Core-Shell Particles

Author(s):  
Hua Min Kou ◽  
Yu Bai Pan ◽  
Jing Kun Guo
2016 ◽  
Vol 8 (2) ◽  
pp. 1493-1500 ◽  
Author(s):  
Houwen Matthew Pan ◽  
Maximilian Seuss ◽  
Martin P. Neubauer ◽  
Dieter W. Trau ◽  
Andreas Fery

2015 ◽  
Vol 6 (29) ◽  
pp. 5273-5280 ◽  
Author(s):  
Benedict Sandmann ◽  
Bobby Happ ◽  
Igor Perevyazko ◽  
Tobias Rudolph ◽  
Felix H. Schacher ◽  
...  

Core–shell particles (soft PBA core and hard PMMA shell) were incorporated into methacrylate based composites. By the incorporation of the polymer lattices the fracture toughness and E-modulus values were improved.


2019 ◽  
Vol 35 (3) ◽  
pp. 117-137
Author(s):  
Yongjun Liu ◽  
Ming Zhong ◽  
Gang Liu ◽  
Shouzhi Pu

Recycled poly(ethylene terephthalate) (R-PET)/high-density polyethylene (HDPE)/glycidyl methacrylate grafted poly(ethylene-octene) (mPOE) blends, in which the binary (HDPE/mPOE) dispersed phase was of a HDPE core-mPOE shell structure, were prepared. For this purpose, HDPE-g-mPOE graft copolymers were prepared in HDPE/mPOE blends via reactive extrusion with the presence of the free radical initiator dicumyl peroxide (DCP). Then, R-PET was blended with the HDPE/mPOE blends by melt extrusion. The effect of the DCP and mPOE content in the HDPE/mPOE blends on the phase morphology and mechanical properties of the R-PET/HDPE/mPOE blends were studied systematically. It was found that the blends containing reactive compatibilizer exhibited the encapsulation of the HDPE by the mPOE, forming core–shell particles dispersed phase morphology. The graft chains of HDPE-g-mPOE-g-PET formed by the in situ reaction between R-PET and mPOE phases reduced the interfacial tension. Consequently, the dispersed phase morphology was observed to form smaller diameter core–shell particles. The resultant blends exhibited an effect on both the thermal and mechanical properties. Differential scanning calorimetric analysis showed the dispersed phase particles could act as a nucleating agent in the R-PET matrix to improve the crystallization temperature, while the graft copolymers formed in the compatibilized R-PET/HDPE/mPOE blend decreased the nucleation activity. Notched Charpy impact strength and elongation at break of the R-PET were improved by forming the core–shell particles dispersed phase morphology.


Polymers ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1040 ◽  
Author(s):  
Lien Zhu ◽  
Haoming Wang ◽  
Meihua Liu ◽  
Zheng Jin ◽  
Kai Zhao

In this paper, the high-density polyethylene/maleic anhydride grafted high-density polyethylene/polyamide 6 (HDPE/HDPE-g-MA/PA6) ternary blends were prepared by blend melting. The binary dispersed phase (HDPE-g-MA/PA6) is of a core-shell structure, which is confirmed by the SEM observation and theoretical calculation. The crystallization behavior and mechanical properties of PA6, HDPE-g-MA, HDPE, and their blends were investigated. The crystallization process, crystallization temperature, melting temperature, and crystallinity were studied by differential scanning calorimetry (DSC) testing. The results show that PA6 and HDPE-g-MA interact with each other during crystallizing, and their crystallization behaviors are different when the composition is different. At the same time, the addition of core-shell particles (HDPE-g-MA/PA6) can affect the crystallization behavior of the HDPE matrix. With the addition of the core-shell particles, the comprehensive mechanical properties of HDPE were enhanced, including tensile strength, elastic modulus, and the impact strength. Combined with previous studies, the toughening mechanism of core-shell structure is discussed in detail. The mechanism of the core-shell structure toughening is not only one, but the result of a variety of mechanisms together.


2007 ◽  
Vol 351 ◽  
pp. 109-113
Author(s):  
Zheng Yi Fu ◽  
Z. Fan ◽  
W.J. Tang ◽  
Jin Yong Zhang ◽  
Wei Min Wang ◽  
...  

Hybridization is a promising method for core/shell particles by a mechanical shock process involving dry blending and dry impact blending. In this paper, hybridization was used to prepare TiB2/Ni ceramics/metal and TiB2/Al2O3 ceramics/ceramics core/shell particles. The mechanism of the formation and the features of the core/shell particles were analyzed. The nano- Al2O3 particles can be coated on the surface of micron TiB2 particles directly by hybridization, The sub-micron Al2O3 particles can be coated on the surface of micron TiB2 particles, only with the introducing of PE-wax as transition layer. The mechanical properties of cermet sintered from TiB2/Ni core/shell ceramics/metal particles were compared with that from TiB2/Ni blended particles.


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