Fundamental Measurements of the Friction on an Atomically-Flat Terrace of Au(100) in Sulfuric Acid Solution under Potential Control Using Electrochemical Atomic Force Microscope

2006 ◽  
pp. 395-398
Author(s):  
Nobumitsu Hirai ◽  
Tatsuya Tooyama ◽  
Toshihiro Tanaka
Keyword(s):  
Sulfuric Acid ◽  
Acid Solution ◽  
Atomic Force Microscope ◽  
Sulfuric Acid Solution ◽  
Potential Control ◽  
Atomic Force ◽  
Atomically Flat

Fundamental Measurements of the Friction on an Atomically-Flat Terrace of Au(100) in Sulfuric Acid Solution under Potential Control Using Electrochemical Atomic Force Microscope

2006 ◽  
Vol 512 ◽  
pp. 395-398
Author(s):  
Nobumitsu Hirai ◽  
Tatsuya Tooyama ◽  
Toshihiro Tanaka
Keyword(s):  
Aqueous Solution ◽  
Sulfuric Acid ◽  
Silicon Nitride ◽  
Acid Solution ◽  
Atomic Force Microscope ◽  
Friction Force ◽  
Potential Range ◽  
Potential Control ◽  
Atomic Force ◽  
Atomically Flat

Potential dependence of the friction force between an atomically-flat terrace of Au(100) single crystal and a tip attached to a silicon nitride cantilever of electrochemical atomic force microscope (EC-AFM) have been investigated qualitatively in 0.05 M H2SO4 aqueous solution. It is found that the friction force gains when the potential increases in the potential range between −400 mV and 400 mV vs Hg/Hg2SO4 electrode.

scholarly journals Inhibitory Properties of Neomycin Thin Film Formed on Carbon Steel in Sulfuric Acid Solution. Electrochemical and AFM Investigation

2017 ◽  
Author(s):  
Adriana Samide ◽  
Gabriela Eugenia Iacobescu ◽  
Bogdan Tutunaru ◽  
Roxana Grecu ◽  
Cristian Tigae ◽  
...  
Keyword(s):  
Atomic Force Microscopy ◽  
Sulfuric Acid ◽  
Carbon Steel ◽  
Acid Solution ◽  
Sulfuric Acid Solution ◽  
Steel Surface ◽  
Protective Layer ◽  
Force Microscopy ◽  
Atomic Force ◽  
Neomycin Sulfate

Our study aims to implement a strategy to reduce the carbon steel corrosion rate in sulfuric acid solution, using an expired drug with adsorption affinity on the metal surface. To investigate the corrosion protection efficiency of an environmental friendly inhibitor, namely neomycin sulfate (NMS), the electrochemical measurements were applied on carbon steel immersed in 1.0 M H2SO4 solution with and without NMS. The protective layer formed on the steel surface was studied by atomic force microscopy (AFM). The potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) showed that the presence of the neomycin sulfate in acid solution leads to the decrease in corrosion current density (icorr) and the increase of polarization resistance (Rp). The mixed mechanism between physical and chemical adsorption of NMS molecules on the steel surface was proposed according to the Langmuir adsorption isotherm. The Atomic Force Microscopy (AFM) indicated that the NMS molecules contributed to a protective layer formation by their adsorption on the steel surface. The AFM parameters such as: root-mean-square roughness (Rq); average roughness (Ra) and maximum peak to valley height (Rp-v) revealed that in the presence of NMS a smoother surface of carbon steel was obtained, compared to the steel surface corroded in sulfuric acid blank solution.

scholarly journals Electropolishing of Niobium in a Sulfuric Acid Solution by Pulse Potential Control

2019 ◽  
Vol 68 (6) ◽  
pp. 148-151
Author(s):  
Ryo Shiratori ◽  
Shoma Kawamura ◽  
Hitoshi Yashiro ◽  
Keisuke Nii ◽  
Yoshiaki Ida ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Acid Solution ◽  
Sulfuric Acid Solution ◽  
Potential Control

scholarly journals Inhibitory Properties of Neomycin Thin Film Formed on Carbon Steel in Sulfuric Acid Solution. Electrochemical and AFM Investigation

2017 ◽  
Author(s):  
Adriana Samide ◽  
Gabriela Eugenia Iacobescu ◽  
Bogdan Tutunaru ◽  
Roxana Grecu ◽  
Cristian Tigae ◽  
...  
Keyword(s):  
Atomic Force Microscopy ◽  
Sulfuric Acid ◽  
Carbon Steel ◽  
Acid Solution ◽  
Sulfuric Acid Solution ◽  
Steel Surface ◽  
Protective Layer ◽  
Force Microscopy ◽  
Atomic Force ◽  
Neomycin Sulfate

Our study aims to implement a strategy to reduce the carbon steel corrosion rate in sulfuric acid solution, using an expired drug with adsorption affinity on the metal surface. To investigate the corrosion protection efficiency of an environmental friendly inhibitor, namely neomycin sulfate (NMS), the electrochemical measurements were applied on carbon steel immersed in 1.0 M H2SO4 solution with and without NMS. The protective layer formed on the steel surface was studied by atomic force microscopy (AFM). The potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) showed that the presence of the neomycin sulfate in acid solution leads to the decrease in corrosion current density (icorr) and the increase of polarization resistance (Rp). The mixed mechanism between physical and chemical adsorption of NMS molecules on the steel surface was proposed according to the Langmuir adsorption isotherm. The Atomic Force Microscopy (AFM) indicated that the NMS molecules contributed to a protective layer formation by their adsorption on the steel surface. The AFM parameters such as: root-mean-square roughness (Rq); average roughness (Ra) and maximum peak to valley height (Rp-v) revealed that in the presence of NMS a smoother surface of carbon steel was obtained, compared to the steel surface corroded in sulfuric acid blank solution.

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