Isothermal Crystallization of Polyethylene/Montmorillonite Nanocomposites Prepared by In Situ Polymerization
2012 ◽
Vol 271-272
◽
pp. 42-45
Keyword(s):
Polyethylene/montmorillonite (PE/MMT) nanocomposites were prepared by in situ polymerization. The isothermal crystallization of PE/MMT nanocomposites at different MMT concentration (from 0.1 wt % to 1.2 wt %) was investigated by differential scanning calorimetry (DSC). The crystallization kinetics shows that the Avrami exponent of PE/MMT nanocomposites is decreased compared with pure PE, which indicates a decrease in the crystal growth dimension. This is attributed to the stems of PE crystals confined in the MMT layers. The crystallization rates of PE/MMT nanocomposites are faster than those of pure PE. However, when the content of MMT increases from 0.1 wt % to 1.2 wt %, the crystallization rate of PE/MMT nanocomposites is decreased.
2012 ◽
Vol 184-185
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pp. 932-935
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Vol 41
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pp. 3011-3017
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2002 ◽
Vol 57
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2013 ◽
Vol 54
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Vol 43
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