Many spectra have a polynomial-like baseline. Iterative polynomial fitting (IPF) is one of the most popular methods for baseline correction of these spectra. However, the baseline estimated by IPF may have substantially error when the spectrum contains significantly strong peaks or have strong peaks located at the endpoints. First, IPF uses temporary baseline estimated from the current spectrum to identify peak data points. If the current spectrum contains strong peaks, then the temporary baseline substantially deviates from the true baseline. Some good baseline data points of the spectrum might be mistakenly identified as peak data points and are artificially re-assigned with a low value. Second, if a strong peak is located at the endpoint of the spectrum, then the endpoint region of the estimated baseline might have significant error due to overfitting. This study proposes a search algorithm-based baseline correction method (SA) that aims to compress sample the raw spectrum to a dataset with small number of data points and then convert the peak removal process into solving a search problem in artificial intelligence (AI) to minimize an objective function by deleting peak data points. First, the raw spectrum is smoothened out by the moving average method to reduce noise and then divided into dozens of unequally spaced sections on the basis of Chebyshev nodes. Finally, the minimal points of each section are collected to form a dataset for peak removal through search algorithm. SA selects the mean absolute error (MAE) as the objective function because of its sensitivity to overfitting and rapid calculation. The baseline correction performance of SA is compared with those of three baseline correction methods: Lieber and MahadevanâJansen method, adaptive iteratively reweighted penalized least squares method, and improved asymmetric least squares method. Simulated and real FTIR and Raman spectra with polynomial-like baselines are employed in the experiments. Results show that for these spectra, the baseline estimated by SA has fewer error than those by the three other methods.
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