The Function Study of TiO2 Catalysts on Zinc Air Battery

2011 ◽  
Vol 194-196 ◽  
pp. 882-885
Author(s):  
Chun Sen Zhou ◽  
Pei Xian Zhu ◽  
Jia Xin Guo

Adopt the titanium sour D ester water solution legal system have of the Na rice TiO2 does the zinc-air battery cathode catalyst. Shoot line Yan to cast light a table method(XRD) and scan an electronic microscope method(SEM) with the X, and deeply shoot an electronic microscope method(TEM) to carry on token to the TiO2 powder sample of making,[1] result enunciation titanium sour D ester water solution method legal system have of TiO2 catalysts is the Rui titanium mineral type structure, grain the path be not the biggest over 50 nms.Adopt cathode very in the meantime to turn curve, the Heng electric potential turn on electricity with the Heng electric current turn on electricity etc. electricity chemistry test means, result detection,The TiO2 has a better electricity catalyst an activity in the alkalescence lie the quality 6 mols/LNaOH, in keeping with do the zinc-air battery cathode catalyst.

2008 ◽  
Vol 59 (9) ◽  
Author(s):  
Daniel I. Hadaruga ◽  
Nicoleta G. Hadaruga ◽  
Anca Hermenean ◽  
Adrian Rivis ◽  
Vasile Paslaru ◽  
...  

This paper presents the thermal stability of the oleic acid encapsulated in a- and b - cyclodextrin. The complexation of the oleic acid was achieved by the ethanol-water solution method and the nanoparticles were analyzed by DSC. The free oleic acid and the encapsulated one were subjected to the thermal degradation in the range of 50-150�C and the degradation products were identified and quantified by GC-MS analysis of the fatty acid esters obtained by deriving with methanol/boron trifluoride, both for free compounds and for the encapsulated ones. The oleic acid complexes were very stable in this range of temperature.


2010 ◽  
Vol 10 (1) ◽  
pp. 26-31 ◽  
Author(s):  
Canggih Setya Budi ◽  
Indriana Kartini ◽  
Bambang Rusdiarso

Mesoporous titania powders with high-order crystalline building blocks had been synthesized through the sol-gel process using potato starch gel template. Internal spongelike pore structure of starch gel template was generated by heating the starch granules at 95 °C in water solution and freezing the starch gel at -15 °C. The synthesis routes were performed by immersing the starch gel template for 4 days into the white colloidal solution of TiO2 nanoparticles, which were prepared by hydrolyzing titanium (IV) tetraisopropoxide (TTIP) in ethanol at pH 1. Mesoporous TiO2 powders were obtained by two different ways of template removal, performed by calcination of the TiO2-starch composites at 600 °C for 4 h or combination of extraction with ethanol-HCl (2:1) at 80 °C and calcination at 500 °C for 4 h. Fourier Transform Infra Red (FT-IR) spectra shows both of template removal methods result in decreasing of characteristic vibrational band of the starch hydrocarbon on the resulted TiO2 powders. The X-Ray Diffraction (XRD) pattern imply that the concentrations of starch gel template influence the anatase crystallite peaks intensity of the synthesized TiO2 powders. TiO2 templated by 20% of starch sponges gel has highest intensity of anatase crystallite. Scherrer calculation inidicated that anatase particle size has nanoscale dimmension up to 12.96 nm. The nano-architecture feature of mesoporous TiO2 scaffolds was also evaluated by the Scanning Electron Microscope (SEM). It is shown that mesoporous TiO2 framework consist of nanocrystalline TiO2 particles as buiding blocks. The N2 adsorption-desorption isotherm curves assign that TiO2 powder resulted from extraction-calcination route has higher mesoporosity than that of only calcinated. The synthesized mesoporous TiO2 powder exhibits high Brunauer-Emmet-Teller (BET) specific surface area up to 65.65 m2/g.   Keywords: mesoporous TiO2, potato starch, template


2020 ◽  
Vol 471 ◽  
pp. 228373 ◽  
Author(s):  
Si-Han Peng ◽  
Tse-Hsi Chen ◽  
Chih-Hsun Lee ◽  
Hsin-Chun Lu ◽  
Shingjiang Jessie Lue

2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Seungwook Eom ◽  
Seyoung Ahn ◽  
Sanghwan Jeong

The optimum composition of cathode catalyst has been studied for rechargeable zinc air battery application. La0.9Ca0.1Co1−xFexO3  (x=0–0.4)perovskite powders were prepared using the citrate method. The substitution ratio of Co2+with Fe3+cations was controlled in the range of 0–0.4. The optimum substitution ratio of Fe3+cations was determined by electrochemical measurement of the air cathode composed of the catalyst, polytetrafluoroethylene (PTFE) binder, and Vulcan XC-72 carbon. The substitution by Fe enhanced the electrochemical performances of the catalysts. Considering oxygen reduction/evolution reactions and cyclability, we achieved optimum substitution level ofx=0.1in La0.9Ca0.1Co1−xFexO3.


2016 ◽  
Vol 500 ◽  
pp. 1-5 ◽  
Author(s):  
Liqiang Yan ◽  
Zhineng Kong ◽  
Wei Shen ◽  
Wenqi Du ◽  
Yan Zhou ◽  
...  

2011 ◽  
Vol 196 (7) ◽  
pp. 3673-3677 ◽  
Author(s):  
Zhu Chen ◽  
Ja-Yeon Choi ◽  
Haijiang Wang ◽  
Hui Li ◽  
Zhongwei Chen

2018 ◽  
Vol 36 (3) ◽  
pp. 359-363
Author(s):  
B. Ying ◽  
W.G. Sheng

AbstractA new hydrated rare earth borate K2O·CaO·4B2O3·12H2O:Eu was prepared by water solution method. The crystal structure, morphology, luminescence properties were investigated via XRD, IR, TG-DSC and SEM, respectively, and it was shown that one single crystal was obtained via spontaneous crystallization. The luminescent properties were also investigated by F-4600 spectrophotometer.


2019 ◽  
Vol 1 (6) ◽  
pp. 2392-2399 ◽  
Author(s):  
Shivaraju Guddehalli Chandrappa ◽  
Prabu Moni ◽  
Guruprakash Karkera ◽  
Annigere S. Prakash

MnCo2O4–GS nano composite by a one-pot sonochemical method and its high performance as an active cathode catalyst for a Zn–air battery.


2020 ◽  
Vol 472 ◽  
pp. 228451
Author(s):  
Wei Wang ◽  
Yajun Mi ◽  
Yumao Kang ◽  
Xianyi Liu ◽  
Sarah Imhanria ◽  
...  

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